Where it forms, where it's found
- Geological setting
Highly oxidized ore.
Oxidized zones of copper deposits in arid climates; in caves derived from copper sulfides in cave walls and phosphorus from bat guano; miarolytic cavities in granite; in pegmatites.
- Type locality
- Chuquicamata Mine
- Chuquicamata District
- Calama
- El Loa Province
- Antofagasta
- Chile
-22.2894°, -68.9011°
Physical
Optical
- Optical type
- Biaxial (-) · 2V measured = 5 – 23° · 2V calc = 22°
- Refractive index
- 1.625 – 1.679
- Surface relief
- High
- Principal indices
- nα 1.625 – 1.629 · nβ 1.674 – 1.677 · nγ 1.674 – 1.679
- Birefringence
- 0.049
- Pleochroism
- Visible
X = Deep blue, blue-green; Y = Light blue, turquoise-blue; Z = Turquoise-blue, colourless.
- Dispersion
- r > v
- Extinction
- Parallel. X = b, Y = a, Z = c.
- UV response
- Not fluorescent.
- Notes
Absorption: X > Y > Z.
Crystallography
- Space group
- C2/m 2/m 2/m
- Cell parameters
- a = 9.72 Å · b = 38.48 Å · c = 9.67 Å
- Cell angles
- β = 90.0 °
- Ratio a:b:c
- 1 : 3.959 : 0.995
- Z
- 8
- Morphology
Thin lath-like, pseudo-orthorhombic plates, flattened on (010), elongated along [001]; rosettes; commonly aggregated into crusts.
- Twinning
Common.
- Type-locality form
Earthy crusts and crack fillings. Micaceous rosettes and aggregates of small platy crystals in small cracks.
- Comment
Pseudo-orthorhombic metrics. Old literature gives "orthorhombic" cell with a = 9.7, b = 38.7, c = 9.45 A. The polymorph described by Giester et al. (2007) has space group P21/c, a = 9.695(2), b = 9.673(2), c = 19.739(4) Å, beta = 102.61(3)°, V = 1806.5(6) Å3, Z = 4; a P21/n modification is also known
Chemical composition
Synonyms
- Sampleiet
In other languages
- German
- Sampleit
- Spanish
- Sampleíta
- Italian
- Sampleite
Classification
8.DG.05
- 8Phosphates, Arsenates, VanadatesClass
- 8.DPhosphates, etc. with additional anions, with H2ODivision
- 8.DGWith large and medium-sized cations, (OH, etc.):RO4< 0.5:1Group
- 8.DG.05SampleiteSpecies
42.09.04.01
- 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
- 42.09(AB)7(XO4)4Zq·xH2OType
- 42.09.04— unnamed intermediate level —Group
- 42.09.04.01SampleiteSpecies
22.2.1
- 22Phosphates, Arsenates or Vanadates with other AnionsClass
- 22.2Phosphates, arsenates or vanadates with chlorideGroup
- 22.2.1SampleiteSpecies
Group, growth & confusion
Literature, links & citation
- 1942Hurlbut, C. S. (1942) Sampleite, a new mineral from Chuquicamata, Chile. American Mineralogist, 27 (8) 586-589
- 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
- 1956Guillemin, Claude (1956) Contribution à la minéralogie des arséniates, phosphates et vanadates de cuivre. II. — Phosphates et vanadates de cuivre. Bulletin de la Société française de Minéralogie et de Cristallographie, 79 (4). 219-275 doi:10.3406/bulmi.1956.5073DOI: 10.3406/bulmi.1956.5073
- 1989Fabrizi, Maria, Ganiaris, Helen, Tarling, Stephen, Scott, David A. (1989) The occurrence of sampleite, a complex copper phosphate, as a corrosion product on copper alloy objects from Memphis, Egypt. Studies in Conservation, 34 (1). 45-51 doi:10.1179/sic.1989.34.1.45DOI: 10.1179/sic.1989.34.1.45
- 2005(2005) Sampleite. Handbook of Mineralogy. Mineralogical Society of America
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Sampleite — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/sampleite-3515},
note = {Accessed 2026-05-11}
}

