Sampleite

NaCaCu5(PO4)4Cl · 5H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Smp
Discovered
1942
Also known as
  • Sampleiet

Where it forms, where it's found

Geological setting

Highly oxidized ore.

Oxidized zones of copper deposits in arid climates; in caves derived from copper sulfides in cave walls and phosphorus from bat guano; miarolytic cavities in granite; in pegmatites.

Type locality
Chuquicamata Mine
  1. Chuquicamata District
  2. Calama
  3. El Loa Province
  4. Antofagasta
  5. Chile

-22.2894°, -68.9011°

40recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Light blue · bluish green · blue in transmitted light.
Streak
Light blue
Tenacity
brittle
Cleavage
Perfect

On (010), perfect; on (100) and (001), good.

Density
3.2 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 5 – 23° · 2V calc = 22°
Refractive index
1.625 – 1.679
Surface relief
High
Principal indices
nα 1.625 – 1.629 · nβ 1.674 – 1.677 · nγ 1.674 – 1.679
Birefringence
0.049
Pleochroism
Visible

X = Deep blue, blue-green; Y = Light blue, turquoise-blue; Z = Turquoise-blue, colourless.

Dispersion
r > v
Extinction
Parallel. X = b, Y = a, Z = c.
UV response
Not fluorescent.
Notes

Absorption: X > Y > Z.

Michel-Lévy diagramhighlighted lineδ = 0.0490
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]490 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation490 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
C2/m 2/m 2/m
Cell parameters
a = 9.72 Å · b = 38.48 Å · c = 9.67 Å
Cell angles
β = 90.0 °
Ratio a:b:c
1 : 3.959 : 0.995
Z
8
Morphology

Thin lath-like, pseudo-orthorhombic plates, flattened on (010), elongated along [001]; rosettes; commonly aggregated into crusts.

Twinning

Common.

Type-locality form

Earthy crusts and crack fillings. Micaceous rosettes and aggregates of small platy crystals in small cracks.

Comment

Pseudo-orthorhombic metrics. Old literature gives "orthorhombic" cell with a = 9.7, b = 38.7, c = 9.45 A. The polymorph described by Giester et al. (2007) has space group P21/c, a = 9.695(2), b = 9.673(2), c = 19.739(4) Å, beta = 102.61(3)°, V = 1806.5(6) Å3, Z = 4; a P21/n modification is also known

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2115.999335.979
37.91%
29CuCopperCopper563.546317.730
35.85%
15PPhosphorusPhosphorus430.974123.896
13.98%
20CaCalciumCalcium140.07840.078
4.52%
17ClChlorineChlorine135.45035.450
4.00%
11NaSodiumSodium122.99022.990
2.60%
1HHydrogenHydrogen101.00810.080
1.14%
Total886.203100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Sampleiet

In other languages

German
Sampleit
Spanish
Sampleíta
Italian
Sampleite

Classification

Strunz
10th ed.

8.DG.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DGWith large and medium-sized cations, (OH, etc.):RO4< 0.5:1Group
  • 8.DG.05SampleiteSpecies
Dana
8th ed.

42.09.04.01

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.09(AB)7(XO4)4Zq·xH2OType
  • 42.09.04— unnamed intermediate level —Group
  • 42.09.04.01SampleiteSpecies
CIM

22.2.1

  • 22Phosphates, Arsenates or Vanadates with other AnionsClass
  • 22.2Phosphates, arsenates or vanadates with chlorideGroup
  • 22.2.1SampleiteSpecies

Group, growth & confusion

In the same group
2 members
Often grow together
1 mineral
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1942Hurlbut, C. S. (1942) Sampleite, a new mineral from Chuquicamata, Chile. American Mineralogist, 27 (8) 586-589
  2. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  3. 1956Guillemin, Claude (1956) Contribution à la minéralogie des arséniates, phosphates et vanadates de cuivre. II. — Phosphates et vanadates de cuivre. Bulletin de la Société française de Minéralogie et de Cristallographie, 79 (4). 219-275 doi:10.3406/bulmi.1956.5073DOI: 10.3406/bulmi.1956.5073
  4. 1989Fabrizi, Maria, Ganiaris, Helen, Tarling, Stephen, Scott, David A. (1989) The occurrence of sampleite, a complex copper phosphate, as a corrosion product on copper alloy objects from Memphis, Egypt. Studies in Conservation, 34 (1). 45-51 doi:10.1179/sic.1989.34.1.45DOI: 10.1179/sic.1989.34.1.45
  5. 2005(2005) Sampleite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Sampleite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/sampleite-3515},
  note      = {Accessed 2026-05-11}
}