Alluaivite

Na19(Ca,Mn2+)6(Ti,Nb)3Si26O74Cl · 2H2O
IMA status
  • Approved
IMA symbol
Aav
Discovered
1990
Also known as
  • Alluaiviet
  • Alluaivitt
  • IMA1988-052

Where it forms, where it's found

Geological setting

In ultra-agpaitic pegmatites in a differentiated alkalic massif.

Type locality
Alluaiv Mountain
  1. Lovozersky District
  2. Murmansk Oblast
  3. Russia

67.8645°, 34.5124°

5recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105 – 6/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent
Colour
Colorless to weak brownish pink
Tenacity
brittle
Fracture
Conchoidal
Density
2.76 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.618 – 1.626
Surface relief
Moderate
Principal indices
nω 1.618 · nε 1.626
UV response
Vivid orange-red.
Michel-Lévy diagramhighlighted lineδ = 0.0080
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]80 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation80 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
R-3m
Cell parameters
a = 14.04 Å · c = 60.6 Å
Morphology

Irregular accumulations, to 1 mm.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen7615.9991215.924
35.61%
14SiSiliconSilicon2628.085730.210
21.38%
11NaSodiumSodium1922.990436.810
12.79%
25MnManganeseManganese654.938329.628
9.65%
41NbNiobiumNiobium392.906278.718
8.16%
20CaCalciumCalcium640.078240.468
7.04%
22TiTitaniumTitanium347.867143.601
4.21%
17ClChlorineChlorine135.45035.450
1.04%
1HHydrogenHydrogen41.0084.032
0.12%
Total3414.841100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Zr
  • La
  • Ce
  • TR
  • Sr
  • Ba
  • K

Synonyms

  • Alluaiviet
  • Alluaivitt
  • IMA1988-052

In other languages

French
alluaivite
German
Alluaivit · IMA 1988-052
Italian
alluaivite
Russian
Аллуайвит

Classification

Strunz
10th ed.

9.CO.10

  • 9SilicatesClass
  • 9.CCyclosilicatesDivision
  • 9.CO[Si9O27]18- 9-membered ringsGroup
  • 9.CO.10AlluaiviteSpecies
Dana
8th ed.

64.1b.01.01

  • 64Cyclosilicates Rings with Other Anions and Insular Silicate GroupsClass
  • 64.1b— unnamed intermediate level —Type
  • 64.1b.01— unnamed intermediate level —Group
  • 64.1b.01.01AlluaiviteSpecies
CIM

17.3.7

  • 17Silicates Containing other AnionsClass
  • 17.3Silicates with chloride (including aluminosilicates)Group
  • 17.3.7AlluaiviteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1990Khomyakov, A.P., Netschelyustov, G.N., Rastsvetaeva, R.K. (1990) Alluaivite Na19(Ca,Mn)6(Ti,Nb)3Si26O74Cl·2H2O–a new titanosilicate of of eudialyte–like structure. Zapiski Vsesoyuznogo Mineralogicheskogo Obshchestva: 119(1): 117-120.
  2. 1990Rastsvetaeva, R.K., Khomyakov, A.P., Andrianov, V.I., Gusev, A.I. (1990) Crystal structure of alluaivite. Doklady Akademii Nauk SSSR: 312: 1379-1383.
  3. 1991Jambor, John L., Puziewicz, Jacek (1991) New Mineral Names. American Mineralogist, 76 (9-10) 1728-1735
  4. 1997Mandarino, Joseph A. (1997) New Minerals 1990-1994. The Mineralogical Record Inc., Tuscon, Arizona. 220pp.
  5. 2001(2001) Alluaivite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Alluaivite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/alluaivite-141},
  note      = {Accessed 2026-05-11}
}