Bobierrite

Mg3(PO4)2 · 8H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Bob
Discovered
1868
Also known as
  • Bobierriet
  • Hautefeuillite
  • Hautefueillite
  • +1 more

Where it forms, where it's found

Geological setting

Guano deposit.

Guano deposits. Phosphatic fossils. Late stage phosphate mineralization in granite pegmatite.

Type locality
Mejillones peninsula
  1. Mejillones
  2. Antofagasta Province
  3. Antofagasta
  4. Chile
16recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102 – 2.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colorless to gray-white · colorless in transmitted light.
Streak
White
Tenacity
sectile
Cleavage
Perfect

On (010), perfect.

Density
2.195 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 53 – 71° · 2V calc = 52 – 73°
Refractive index
1.51 – 1.582
Surface relief
Moderate
Principal indices
nα 1.51 – 1.5468 · nβ 1.52 – 1.5533 · nγ 1.543 – 1.582
Birefringence
0.032
Pleochroism
Non-pleochroic
Dispersion
r<v weak
Extinction
Y = b, Z ∧ c = 27°-29°.
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0320
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]320 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation320 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/c
Cell parameters
a = 4.667 Å · b = 27.926 Å · c = 10.067 Å
Cell angles
β = 105.01 °
Ratio a:b:c
1 : 5.984 : 2.157
Z
4
Morphology

Crystals acicular or fibrous, minute, elongated [001] and flattened (010). Also forms rosette-like flattened aggregates; lamellar; crystalline agglomerations; masive.

Type-locality form

Six-sided minute prismatic crystals forming aggregates, embedded in guano.

Comment

Takagi, S., Mathew, M., and Brown, W. E. (1986) Crystal Structures of Bobierrite and Synthetic Mg<f>3</f>(PO<f>4</f>)2.8H<f>2</f>O. American Mineralogist: 71: 1229-1233.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1615.999255.984
62.90%
12MgMagnesiumMagnesium324.30572.915
17.92%
15PPhosphorusPhosphorus230.97461.948
15.22%
1HHydrogenHydrogen161.00816.128
3.96%
Total406.975100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Bobierriet
  • Hautefeuillite
  • Hautefueillite
  • Phosphate de Magnésie tribasique et Hydraté

In other languages

German
Bobierrit
Italian
Bobierrite
Chinese
白磷镁矿

Classification

Strunz
10th ed.

8.CE.35

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CEWith only medium-sized cations, RO4:H2O about 1:2.5Group
  • 8.CE.35BobierriteSpecies
Dana
8th ed.

40.03.07.01

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.03A3(XO4)2·xH2OType
  • 40.03.07— unnamed intermediate level —Group
  • 40.03.07.01BobierriteSpecies
CIM

19.3.19

  • 19PhosphatesClass
  • 19.3Phosphates of Be and MgGroup
  • 19.3.19BobierriteSpecies

Group, growth & confusion

Often grow together
3 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1868Dana, James D., Brush, George Jarvis (1868) A System of Mineralogy (5th ed.). p.882
  2. 1868Bobierre (1868) Les Mondes, April 1868: 691 (as Phosphate de Magnésie tribasique et Hydraté).
  3. 1888Lacroix, A. (1888) Sur la bobiereite. Comptes rendus de l’Académie des sciences de Paris: 106: 631-633.
  4. 1903de Schulten, A. (1903) Recherches sur le phosphate et l'arséniate trimagnésiens. Reproduction artificielle de la bobierrite et de la hœrnésite. Bulletin de la Société française de Minéralogie: 26: 81-86.
  5. 1921Larsen, Esper S. (1921) The microscopic determination of the nonopaque minerals. Bulletin 679. US Geological Survey doi:10.3133/b679 DOI: 10.3133/b679
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Bobierrite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/bobierrite-701},
  note      = {Accessed 2026-05-11}
}