Where it forms, where it's found
- Geological setting
Granite pegmatite.
Granite pegmatites, especially the "complex" type containing lithium and phosphate species.
- Type locality
- Fillow Quarry
- Branchville
- Redding
- Fairfield County
- Connecticut
- USA
41.2678°, -73.4392°
Physical
- Hardness
- 1Talc
- 2Gypsum
- 3Calcite
- 4Fluorite
- 5Apatite
- 6Orthoclase
- 7Quartz
- 8Topaz
- 9Corundum
- 10Diamond
- Lustre
- Resinous
- Transparency
- Transparent · Translucent
- Colour
- Reddish-brown · yellowish brown · golden-yellow · salmon-orange · pale grey-green (when Fe-rich) · colourless to light yellow · pink in transmitted light.
Low-Fe material is pale pinkish brown to orange.
- Streak
- Colorless to Grayish White
- Cleavage
- Very Good
On (001) nearly perfect; on (010) imperfect; on (011) interrupted.
- Fracture
- Irregular/Uneven · Sub-Conchoidal
- Density
- 3.29 g/cm³
Optical
- Optical type
- Biaxial (+) · 2V measured = 30 – 70° · 2V calc = 68°
- Refractive index
- 1.663 – 1.691
- Surface relief
- High
- Principal indices
- nα 1.663 – 1.685 · nβ 1.663 – 1.685 · nγ 1.673 – 1.691
- Birefringence
- 0.008
- Pleochroism
- Weak
X= deep pink Y= pale greenish yellow Z= pale pink
- Dispersion
- strong r < v
- Extinction
- Parallel
- UV response
- Not fluorescent.
- Notes
May be black due to oxidation and staining; Mg reduces RI (Am Min 28:90 (1943)) measured 2V° ranges from near 70° for near end-member lithiophilite, down to near 30° for Lhp50Trp50.
Crystallography
- Space group
- Pmna
- Cell parameters
- a = 6.094(5) Å · b = 10.427(5) Å · c = 4.743(1) Å
- Ratio a:b:c
- 1 : 1.711 : 0.778
- Z
- 4
- Morphology
Crystals rare; commonly coarse with uneven surfaces; stout prismatic [001]. Usually massive, rarely granular.
- Twinning
Rare contact twins on (130)
- Type-locality form
Irregular rounded masses to 7.5 cm in diameter.
- Comment
Pmnb AC (1960) 13: 325; Isotypic with olivine
Chemical composition
- Impurities
- Mg
- Ca
- Fe
Synonyms
- Lithio-Mangano-Triphylite
- Lithiolit
- Lithiolita
- Lithiolite
- Lithiophiliet
- Lithiophilita
In other languages
- French
- lithiophilite
- German
- Lithiophilit · Lithiophylit
- Spanish
- Litiofilita
- Italian
- litiofilite
- Portuguese
- litiofilite
- Japanese
- リチオフィライト
- Russian
- литиофилит
Classification
8.AB.10
- 8Phosphates, Arsenates, VanadatesClass
- 8.APhosphates, etc. without additional anions, without H2ODivision
- 8.ABWith medium-sized cationsGroup
- 8.AB.10LithiophiliteSpecies
38.01.01.02
- 38Anhydrous Normal Phosphates, Arsenates, and VanadatesClass
- 38.01ABXO4Type
- 38.01.01Triphylite GroupGroup
- 38.01.01.02LithiophiliteSpecies
19.1.10
- 19PhosphatesClass
- 19.1Phosphates of the alkali metalsGroup
- 19.1.10LithiophiliteSpecies
Group, growth & confusion
AmblygoniteLiAl(PO4)FMineral—
BermaniteMn2+Mn3+2(PO4)2(OH)2 · 4H2OMineral—
BobierriteMg3(PO4)2 · 8H2OMineral—
Dickinsonite-(KMnNa)K(NaMn)CaNa3AlMn13(PO4)12(OH)2Mineral—
HureauliteMn2+5(PO3OH)2(PO4)2 · 4H2OMineral—
MontebrasiteLiAl(PO4)(OH)Mineral—
TripliteMn2+2(PO4)FMineral—
TriploiditeMn2+2(PO4)(OH)Mineral—
Literature, links & citation
- 1878Brush, G.J., Dana, E.S. (1878) On a new and remarkable mineral locality in Fairfield County, Connecticut; with a description of several new species occurring there. First Paper.. American Journal of Science and Arts, 116, 33-46; 114-123 (118).
- 1879Brush, G.J., Dana, E.S. (1879) On the mineral locality in Fairfield County, Connecticut. American Journal of Science: 18: 45-50.
- 1883Penfield, S.L. (1883) Analyses of two varieties of Lithiophilite (Manganese Triphilite). American Journal of Science, 26(153), 176-176.
- 1895Penfield, S.L., Pratt, J.H. (1895) Effect of the Mutual Replacement of Manganese and Iron on the Optical Properties of Lithiophilite and Triphylite. American Journal of Science, 50(299), 387-390.
- 1923(1923) Atlas Der Krystallformen Vol. 9 - Text - Band IX - Trechmannit-Zoisit und Nachträge. Carl Winters Universitätsbuchhandlung, Heidelberg.
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Lithiophilite — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/lithiophilite-2418},
note = {Accessed 2026-05-11}
}


