Lithiophilite

LiMn2+(PO4)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Lhp
Discovered
1878
Also known as
  • Lithio-Mangano-Triphylite
  • Lithiolit
  • Lithiolita
  • +3 more

Where it forms, where it's found

Geological setting

Granite pegmatite.

Granite pegmatites, especially the "complex" type containing lithium and phosphate species.

Type locality
Fillow Quarry
  1. Branchville
  2. Redding
  3. Fairfield County
  4. Connecticut
  5. USA

41.2678°, -73.4392°

176recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Resinous
Transparency
Transparent · Translucent
Colour
Reddish-brown · yellowish brown · golden-yellow · salmon-orange · pale grey-green (when Fe-rich) · colourless to light yellow · pink in transmitted light.

Low-Fe material is pale pinkish brown to orange.

Streak
Colorless to Grayish White
Cleavage
Very Good

On (001) nearly perfect; on (010) imperfect; on (011) interrupted.

Fracture
Irregular/Uneven · Sub-Conchoidal
Density
3.29 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 30 – 70° · 2V calc = 68°
Refractive index
1.663 – 1.691
Surface relief
High
Principal indices
nα 1.663 – 1.685 · nβ 1.663 – 1.685 · nγ 1.673 – 1.691
Birefringence
0.008
Pleochroism
Weak

X= deep pink Y= pale greenish yellow Z= pale pink

Dispersion
strong r < v
Extinction
Parallel
UV response
Not fluorescent.
Notes

May be black due to oxidation and staining; Mg reduces RI (Am Min 28:90 (1943)) measured 2V° ranges from near 70° for near end-member lithiophilite, down to near 30° for Lhp50Trp50.

Michel-Lévy diagramhighlighted lineδ = 0.0080
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]80 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation80 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
Pmna
Cell parameters
a = 6.094(5) Å · b = 10.427(5) Å · c = 4.743(1) Å
Ratio a:b:c
1 : 1.711 : 0.778
Z
4
Morphology

Crystals rare; commonly coarse with uneven surfaces; stout prismatic [001]. Usually massive, rarely granular.

Twinning

Rare contact twins on (130)

Type-locality form

Irregular rounded masses to 7.5 cm in diameter.

Comment

Pmnb AC (1960) 13: 325; Isotypic with olivine

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen415.99963.996
40.80%
25MnManganeseManganese154.93854.938
35.03%
15PPhosphorusPhosphorus130.97430.974
19.75%
3LiLithiumLithium16.9406.940
4.42%
Total156.848100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Mg
  • Ca
  • Fe

Synonyms

  • Lithio-Mangano-Triphylite
  • Lithiolit
  • Lithiolita
  • Lithiolite
  • Lithiophiliet
  • Lithiophilita

In other languages

French
lithiophilite
German
Lithiophilit · Lithiophylit
Spanish
Litiofilita
Italian
litiofilite
Portuguese
litiofilite
Japanese
リチオフィライト
Russian
литиофилит

Classification

Strunz
10th ed.

8.AB.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.APhosphates, etc. without additional anions, without H2ODivision
  • 8.ABWith medium-sized cationsGroup
  • 8.AB.10LithiophiliteSpecies
Dana
8th ed.

38.01.01.02

  • 38Anhydrous Normal Phosphates, Arsenates, and VanadatesClass
  • 38.01ABXO4Type
  • 38.01.01Triphylite GroupGroup
  • 38.01.01.02LithiophiliteSpecies
CIM

19.1.10

  • 19PhosphatesClass
  • 19.1Phosphates of the alkali metalsGroup
  • 19.1.10LithiophiliteSpecies

Group, growth & confusion

In the same group
6 members
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1878Brush, G.J., Dana, E.S. (1878) On a new and remarkable mineral locality in Fairfield County, Connecticut; with a description of several new species occurring there. First Paper.. American Journal of Science and Arts, 116, 33-46; 114-123 (118).
  2. 1879Brush, G.J., Dana, E.S. (1879) On the mineral locality in Fairfield County, Connecticut. American Journal of Science: 18: 45-50.
  3. 1883Penfield, S.L. (1883) Analyses of two varieties of Lithiophilite (Manganese Triphilite). American Journal of Science, 26(153), 176-176.
  4. 1895Penfield, S.L., Pratt, J.H. (1895) Effect of the Mutual Replacement of Manganese and Iron on the Optical Properties of Lithiophilite and Triphylite. American Journal of Science, 50(299), 387-390.
  5. 1923(1923) Atlas Der Krystallformen Vol. 9 - Text - Band IX - Trechmannit-Zoisit und Nachträge. Carl Winters Universitätsbuchhandlung, Heidelberg.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Lithiophilite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/lithiophilite-2418},
  note      = {Accessed 2026-05-11}
}