Brownmillerite

Ca2Fe3+AlO5
IMA status
  • Approved
IMA symbol
Bmlr
Discovered
1964
Also known as

Where it forms, where it's found

Geological setting

In thermally metamorphosed limestone blocks included in volcanic rocks

In thermally metamorphosed limestones

Type locality
Ettringer Feld
  1. Ettringen
  2. Vordereifel
  3. Mayen-Koblenz
  4. Rhineland-Palatinate
  5. Germany

50.3458°, 7.2222°

30recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Transparent · Translucent
Colour
Reddish-brown
Streak
White
Tenacity
brittle
Cleavage
None Observed
Fracture
Splintery
Density
3.76 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 75° · 2V calc = 72°
Refractive index
1.96 – 2.04
Surface relief
Very high
Principal indices
nα 1.96 · nβ 2.01 · nγ 2.04
Birefringence
0.08
Dispersion
strong
UV response
Not fluorescent in UV
Michel-Lévy diagramhighlighted lineδ = 0.0800
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]800 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation800 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 5.57 Å · b = 14.52 Å · c = 5.34 Å
Ratio a:b:c
1 : 2.607 : 0.959
Z
2
Comment

Space group Ibm2. Other cell parameters given: a = 5.584(5), b = 14.60(1), c = 5.374(5) A.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
20CaCalciumCalcium240.07880.156
32.99%
8OOxygenOxygen515.99979.995
32.92%
26FeIronIron155.84555.845
22.98%
13AlAluminiumAluminium126.98226.982
11.11%
Total242.978100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Celit
  • Celita
  • Celite
  • IMA1963-017

In other languages

French
brownmillerite · calcium aluminoferrite
German
Brownmillerit · IMA 1963-017
Spanish
Brownmillerita
Italian
brownmillerite · fase ferrica
Portuguese
Brownmillerita
Chinese
钙铁铝石

Classification

Strunz
10th ed.

4.AC.10

  • 4OxidesClass
  • 4.AMetal: Oxygen = 2:1 and 1:1Division
  • 4.ACM:O = 1:1 (and up to 1:1.25); with large cations (+- smaller ones)Group
  • 4.AC.10BrownmilleriteSpecies
Dana
8th ed.

07.11.02.01

  • 07Multiple OxidesClass
  • 07.11MiscellaneousType
  • 07.11.02— unnamed intermediate level —Group
  • 07.11.02.01BrownmilleriteSpecies
CIM

7.20.15

  • 7Oxides and HydroxidesClass
  • 7.20Oxides of FeGroup
  • 7.20.15BrownmilleriteSpecies

Group, growth & confusion

In the same group
4 members
Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1959Bertaut, E. F., Blum, P., Sagnières, A. (1959) Structure du ferrite bicalcique et de la brownmillerite. Acta Crystallographica, 12 (2) 149-159 doi:10.1107/s0365110x59000433DOI: 10.1107/s0365110x59000433
  2. 1962Smith, D. K. (1962) Crystallographic changes with the substitution of aluminum for iron in dicalcium ferrite. Acta Crystallographica, 15 (11) 1146-1152 doi:10.1107/s0365110x62003011DOI: 10.1107/s0365110x62003011
  3. 1964Hentschel, G. (1964): Mayenit, 12CaO.7Al2O3, und Brownmillerit, 2CaO.(Al,Fe)2O3, zwei neue Minerale in den Kalksteineinschlüssen der Lava des Ettringer Bellerberges: Neues Jahrbuch für Mineralogie, Monatshefte, 1964: 22-29.
  4. 1965American Mineralogist (1965): 50: 2106.
  5. 1971Colville, A. A., Geller, S. (1971) The crystal structure of brownmillerite, Ca2FeAlO5. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 27 (12) 2311-2315 doi:10.1107/s056774087100579xDOI: 10.1107/s056774087100579x
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Brownmillerite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/brownmillerite-790},
  note      = {Accessed 2026-05-11}
}