Chloritoid

Fe2+Al2O(SiO4)(OH)2
IMA status
  • Approved
  • Grandfathered
IMA symbol
Cld
Also known as
  • Barytophyllit
  • Barytophyllita
  • Barytophyllite
  • +16 more

Where it forms, where it's found

Type locality
Kosoi Brod deposit
  1. Kosoi Brod Village
  2. Polevskoy
  3. Sverdlovsk Oblast
  4. Russia

56.5042°, 60.3817°

346recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789106.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Dark green to green-gray or nearly black
Streak
White, grayish, or very slightly greenish
Cleavage
Perfect

(001) perfect, (110) good.

Density
3.4 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 36 – 89° · 2V calc = 78 – 80°
Refractive index
1.713 – 1.74
Surface relief
High
Principal indices
nα 1.713 – 1.73 · nβ 1.719 – 1.734 · nγ 1.723 – 1.74
Birefringence
0.01, may be anomalous blue
Pleochroism
Strong

X = olive-green to yellow; Y = grayish blue to blue; Z = colorless to pale greenish yellow. Orientation: X or Y = b (monoclinic) Z^c = 2-30 deg, Y ~= b (triclinic)

Dispersion
r > v
Michel-Lévy diagramhighlighted lineδ = 0.0100
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]100 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation100 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/c
Cell parameters
a = 9.50 Å · b = 5.50 Å · c = 18.22 Å
Cell angles
β = 101.9 °
Ratio a:b:c
1 : 0.579 : 1.918
Z
4
Morphology

Thin to thick foliated plates or prisms, or as massive aggregates. Seldom as pseudohexagonal tabular crystals. Also triclinic.

Twinning

Twin axes [100], [110], and [130] observed. Common on (001), polysynthetic.

Parting
On (010)
Type-locality form

Greenish-black crystals similar in appearance to chlorite.

Comment

For monoclinic polytype (space group C2/c). Triclinic polytype (C-1) has a = 9.46(1), b = 5.50(1), c = 9.15(1) A, α = 97.05(2), β = 101.56(2), γ = 90.10(2)°.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen715.999111.993
44.46%
26FeIronIron155.84555.845
22.17%
13AlAluminiumAluminium226.98253.964
21.42%
14SiSiliconSilicon128.08528.085
11.15%
1HHydrogenHydrogen21.0082.016
0.80%
Total251.903100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Barytophyllit
  • Barytophyllita
  • Barytophyllite
  • Bliabergit
  • Bliabergita
  • Bliabergite
  • Bliabergsit
  • Bliabergsita
  • Bliabergsite
  • Chlorite spar
  • Chloritoidit
  • Chloritoidite
  • Chloritspat
  • Sismondin
  • Sismondine
  • Sismondit
  • Sismondita
  • Sismondite
  • Strüverite (of Brezina)

In other languages

French
chloritoïde
German
Chloritoid · Chloritspath
Spanish
cloritoide
Italian
Cloritoide
Japanese
硬緑泥石
Chinese
硬綠泥石
Russian
хлоритовый шпат · хлоритоид
Arabic
كلوريتويد

Classification

Strunz
10th ed.

9.AF.85

  • 9SilicatesClass
  • 9.ANesosilicatesDivision
  • 9.AFNesosilicates with additional anions; cations in [4], [5] and/or only [6] coordinationGroup
  • 9.AF.85ChloritoidSpecies
Dana
8th ed.

52.03.03.01

  • 52Nesosilicates Insular Sio4 Groups and O, Oh, F, H2oClass
  • 52.03Insular SiO4 Groups and O, OH, F, and H2O with cations in [6] coordination onlyType
  • 52.03.03Chloritoid groupGroup
  • 52.03.03.01ChloritoidSpecies
CIM

16.19.6

  • 16Silicates Containing Aluminum and other MetalsClass
  • 16.19Aluminosilicates of Fe and MgGroup
  • 16.19.6ChloritoidSpecies

Group, growth & confusion

In the same group
3 members
Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1832Fiedler, Karl Gustav (1832) Lagerstätten des Diaspor, Chloritspath, Pyrophyllit und Monazit, aufgefunden im Ural. Annalen der Physik und Chemie, 101. 322-333 doi:10.1002/andp.18321010613DOI: 10.1002/andp.18321010613
  2. 1835Breithaupt, J.F.A. (1835) Neue specifische gewichte von mineralien. Journal für Praktische Chemie: 4: 272-278.
  3. 1837Rose, G. (1837) Der Chloritoid. in Mineralogisch-geognostische Reise nach dem Ural, dem Altai und dem Kapischen Meere, Sanderschen Buchbandlung (Berlin): 252-254.
  4. 1884Prost, E. (1884) Sur la salmite de Dumont, chloritoïde manganésifère. Annales de la Société géologique de Belgique, 11, 93.
  5. 1891Keller, H.F., Lane, A.C. (1891) XXVIII. Chloritoid von Champion, Michigan, USA. Zeitschrift für Kristallographie-Crystalline Materials: 19(1-6): 383-385.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Chloritoid — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/chloritoid-1017},
  note      = {Accessed 2026-05-11}
}