Dimorphite

As4S3
IMA status
  • Approved
  • Grandfathered
IMA symbol
Dim
Also known as
  • Dimorphiet
  • Dimorphine
  • Dimorphit
  • +1 more

Where it forms, where it's found

Geological setting

Fumarolic vent

Secondary zone of ore deposits.

Type locality
Solfatara di Pozzuoli
  1. Pozzuoli
  2. Metropolitan City of Naples
  3. Campania
  4. Italy

40.8281°, 14.1417°

5recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789101.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Orange-yellow
Streak
Yellow
Tenacity
brittle
Cleavage
None Observed
Density
3.58 g/cm³

Optical

Optical type
Biaxial (+)
Refractive index
1.6654
Surface relief
High
Principal indices
nβ 1.6654
Dispersion
strong

Crystallography

Crystal system
Orthorhombic
Space group
Pnma
Cell parameters
a = 11.24 Å · b = 9.90 Å · c = 6.56 Å
Ratio a:b:c
1 : 0.881 : 0.584
Z
4
Morphology

Dipyramidal crystals.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
33AsArsenicArsenic474.922299.688
75.70%
16SSulfurSulfur332.06096.180
24.30%
Total395.868100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Dimorphiet
  • Dimorphine
  • Dimorphit
  • Dimorphita

In other languages

German
Dimorphin
Spanish
Dimorfita
Italian
Dimorfite
Japanese
ジモルファイト
Chinese
三硫化四砷

Classification

Strunz
10th ed.

2.FA.10

  • 2Sulfides and SulfosaltsClass
  • 2.FSulfides of arsenic, alkalies; sulfides with halide, oxide, hydroxide, H2ODivision
  • 2.FAWith As, (Sb), SGroup
  • 2.FA.10DimorphiteSpecies
Dana
8th ed.

02.06.01.01

  • 02SulfidesClass
  • 02.06AmBnXp, with (m+n):p = 4:3Type
  • 02.06.01— unnamed intermediate level —Group
  • 02.06.01.01DimorphiteSpecies
CIM

3.7.3

  • 3Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)Class
  • 3.7Sulphides etc. of V, As, Sb and BiGroup
  • 3.7.3DimorphiteSpecies

Group, growth & confusion

Often grow together
3 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1849Scacchi, A. (1849) Memoria IIIa. Esame delle sostanze che si formano presso i fumaroli della Regione Flegrea. Memorie Geologiche sulla Campania 3a, (Napoli), 83-131.
  2. 1944Palache, Charles, Berman, Harry, Frondel, Clifford (1944) The System of Mineralogy (7th ed.) Vol. 1 - Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, New York.
  3. 1970Whitfield, H.J. (1970) The crystal structure of tetra-arsenic trisulfide. Journal of the Chemical Society A: Inorganic, Physical, Theoretical, 1970, 1800-1803.
  4. 1972Clark, Alan H. (1972) Mineralogy of the Alacrán deposit, Pampa Larga, Chile V. Dimorphite of supergene origin. Neues Jahrbuch für Mineralogie - Monatshefte, 1972 (9). 423-429 doi:10.1127/njmm/1972/1972/423DOI: 10.1127/njmm/1972/1972/423
  5. 1973Whitfield, H.J. (1973) Crystal structure of the β-form of tetra-arsenic trisulphide. Journal of the Chemical Society, Dalton Transactions, Inorganic Chemistry, 1973, 1737-1738.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Dimorphite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/dimorphite-1292},
  note      = {Accessed 2026-05-11}
}