Ferri-fluoro-leakeite

NaNa2(Mg2Fe3+2Li)Si8O22F2
IMA status
  • Approved
IMA symbol
Ffllk
IMA approved
2009
Also known as
  • Ferri-fluoro-leakeiet
  • IMA2009-085

Where it forms, where it's found

Geological setting

Alkaline granite.

Type locality
Verkhnee Espe Massif (Verkhnee Espe deposit)
  1. Akzhaylyautas Mts (Akzhailyautas Mts
  2. Akjaylautas Mts
  3. Akzhalautas Mts)
  4. Tarbagatai Range
  5. Abai Region
  6. Kazakhstan

48.1000°, 81.4500°

5recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789106/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
Black · mustard yellow to brownish yellow
Streak
Very pale grey to white
Tenacity
brittle
Cleavage
Perfect

Perfect (110), intersecting at ~56º, characteristic of monoclinic amphiboles.

Fracture
Splintery
Density
3.245 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 80.9° · 2V calc = 79.4°
Refractive index
1.663 – 1.68
Surface relief
High
Principal indices
nα 1.663 · nβ 1.673 · nγ 1.680
Pleochroism
Visible

X = pale grey-green, Y = medium grey, Z = grey-brown.

Extinction
X ∧ a = 14.1º (in β obtuse); Y = b; Z ∧ c = 75.9º (in β acute).
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0170
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]170 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation170 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 9.8297(3) Å · b = 17.9257(6) Å · c = 5.2969(2) Å
Cell angles
β = 103.990(1) °
Ratio a:b:c
1 : 1.824 : 0.539
Z
2
Morphology

Elongated striated crystals. Prismatic parallel to [001] with (100) and (110) faces and cleavage faces, and the prism direction is terminated by irregular fractures.

Type-locality form

Prismatic grains to 3 mm long, occurring as isolated crystals, as small aggregates, and as inclusions in cámaraite.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2215.999351.978
41.37%
14SiSiliconSilicon828.085224.680
26.41%
26FeIronIron255.845111.690
13.13%
11NaSodiumSodium322.99068.970
8.11%
12MgMagnesiumMagnesium224.30548.610
5.71%
9FFluorineFluorine218.99837.996
4.46%
3LiLithiumLithium16.9406.940
0.81%
Total850.864100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Ferri-fluoro-leakeiet
  • IMA2009-085

In other languages

German
Ferri-Fluoro-Leakeit · IMA 2009-085
Italian
ferri-fluoro-leakeite

Classification

Strunz
10th ed.

9.DE.05

  • 9SilicatesClass
  • 9.DInosilicatesDivision
  • 9.DEInosilicates with 2-periodic double chains, Si4O11; ClinoamphibolesGroup
  • 9.DE.05Ferri-fluoro-leakeiteSpecies
Dana
8th ed.

66.04.16.03

  • 66Inosilicates Double-width, Unbranched Chains, (w=2)Class
  • 66.04Amphiboles - Na subgroupType
  • 66.04.16— unnamed intermediate level —Group
  • 66.04.16.03Ferri-fluoro-leakeiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 2010Cámara, F., Hawthorne, F. C., Ball, N. A., Bekenova, G., Stepanov, A. V., Kotel'nikov, P. E. (2010) Fluoroleakeite, NaNa2(Mg2Fe3+2Li)Si8O22F2, a new mineral of the amphibole group from the Verkhnee Espe deposit, Akjailyautas Mountains, Eastern Kazakhstan District, Kazakhstan: description and crystal structure. Mineralogical Magazine, 74 (3) 521-528 doi:10.1180/minmag.2010.074.3.521 DOI: 10.1180/minmag.2010.074.3.521
  2. 2012Hawthorne, F. C., Oberti, R., Harlow, G. E., Maresch, W. V., Martin, R. F., Schumacher, J. C., Welch, M. D. (2012) Nomenclature of the amphibole supergroup. American Mineralogist, 97 (11) 2031-2048 doi:10.2138/am.2012.4276 DOI: 10.2138/am.2012.4276
  3. 2014Oberti, R., Boiocchi, M., Hawthorne, F. C., Kristiansen, R. (2014) Ferri-fluoro-leakeite: a second occurrence at Bratthagen (Norway), with new data on Zn partitioning and the oxo component in Na amphiboles. Mineralogical Magazine, 78 (4) 861-869 doi:10.1180/minmag.2014.078.4.07DOI: 10.1180/minmag.2014.078.4.07
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Ferri-fluoro-leakeite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/ferri-fluoro-leakeite-39878},
  note      = {Accessed 2026-05-11}
}