Ferro-ferri-fluoro-leakeite

NaNa2(Fe2+2Fe3+2Li)Si8O22F2
IMA status
  • Approved
IMA symbol
Fffllk
Also known as
  • Ferro-ferri-fluoro-leakeiet
  • IMA1993-026

Where it forms, where it's found

Geological setting

Mildly peralkaline porphyry.

Type locality
Canada Pinabete pluton
  1. Taos County
  2. New Mexico
  3. USA

36.7744°, -105.5656°

4recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789106/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Colour
Bluish black to black. · dark mauve-red (?)
Streak
Bluish gray, very pale pink (?)
Tenacity
brittle
Cleavage
Perfect

Characteristic perfect (110) cleavage of monoclinic amphiboles, intersecting at ~56°.

Density
3.37 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 87° · 2V calc = 82°
Refractive index
1.675 – 1.694
Surface relief
High
Principal indices
nα 1.675 · nβ 1.683 · nγ 1.694
Pleochroism
Strong

X = very dark indigo blue; Y = gray blue; Z = yellow green.

Dispersion
Dispersion is not visible because of the strong absorption.
Extinction
X ∧ c = 10° (in β obtuse); Y = b; Z ∧ a = 4° (in β obtuse).
Luminescence
Nonfluorescent
UV response
Not fluorescent.
Notes

Absorption: X > Y > Z.

Michel-Lévy diagramhighlighted lineδ = 0.0190
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]190 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation190 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 9.792 Å · b = 17.938 Å · c = 5.313 Å
Cell angles
β = 103.87 °
Ratio a:b:c
1 : 1.832 : 0.543
Type-locality form

Anhedral bluish black crystals elongated along c and up to 1 mm long.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2215.999351.978
38.51%
14SiSiliconSilicon828.085224.680
24.58%
26FeIronIron455.845223.380
24.44%
11NaSodiumSodium322.99068.970
7.55%
9FFluorineFluorine218.99837.996
4.16%
3LiLithiumLithium16.9406.940
0.76%
Total913.944100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Ferro-ferri-fluoro-leakeiet
  • IMA1993-026

In other languages

German
Ferro-Ferri-Fluoro-Leakeit · IMA 1993-026
Italian
ferro-ferri-fluoro-leakeite · fluor-ferro-leakeite · fluoro-ferroleakeite

Classification

Strunz
10th ed.

9.DE.25

  • 9SilicatesClass
  • 9.DInosilicatesDivision
  • 9.DEInosilicates with 2-periodic double chains, Si4O11; ClinoamphibolesGroup
  • 9.DE.25Ferro-ferri-fluoro-leakeiteSpecies
Dana
8th ed.

66.01.3c.15

  • 66Inosilicates Double-width, Unbranched Chains, (w=2)Class
  • 66.01Amphiboles - Mg-Fe-Mn-Li subgroupType
  • 66.01.3c— unnamed intermediate level —Group
  • 66.01.3c.15Ferro-ferri-fluoro-leakeiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1996Mandarino, Joseph A. (1996) Abstracts of New Mineral Descriptions. The Mineralogical Record, 27 (5) 393-395
  2. 1996Hawthorne, Frank C., Oberti, Roberta, Ungaretti, Luciano, Ottolini, Luisa, Grice, Joel D., Czamanske, Gerald K. (1996) Fluor-ferro-leakeite, NaNa2(Fe2+2Fe3+2Li)Si8O22F2, a new alkali amphibole from the Canada Pinabete Pluton, Questa, New Mexico, U.S.A. American Mineralogist, 81 (1) 226-228 doi:10.2138/am-1996-1-227 DOI: 10.2138/am-1996-1-227
  3. 1998Mandarino, Joseph A. (1998) The Second List of Additions and Corrections to the Glossary of Mineral Species (1995) - The Amphibole Group. The Mineralogical Record, 29 (3) 169-174
  4. 2006Hawthorne, F. C., Oberti, R. (2006) On the classification of amphiboles. The Canadian Mineralogist, 44 (1) 1-21 doi:10.2113/gscanmin.44.1.1DOI: 10.2113/gscanmin.44.1.1
  5. 2012Hawthorne, F. C., Oberti, R., Harlow, G. E., Maresch, W. V., Martin, R. F., Schumacher, J. C., Welch, M. D. (2012) Nomenclature of the amphibole supergroup. American Mineralogist, 97 (11) 2031-2048 doi:10.2138/am.2012.4276 DOI: 10.2138/am.2012.4276
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Ferro-ferri-fluoro-leakeite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/ferro-ferri-fluoro-leakeite-6951},
  note      = {Accessed 2026-05-11}
}