Fluorapophyllite-(Na)

NaCa4Si8O20F · 8H2O
IMA status
  • Approved
IMA symbol
Fapo-Na
Discovered
1976
IMA approved
1976
Also known as
  • Apophyllite-Na
  • Fluorapophylliet-(Na)
  • IMA1976-032
  • +3 more

Where it forms, where it's found

Type locality
Sampo mine
  1. Shitouyouze
  2. Bitchū
  3. Takahashi City
  4. Okayama Prefecture
  5. Japan
8recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104 – 5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous · Pearly
Colour
Brownish-yellow · yellowish-brown · colourless
Streak
light gray
Cleavage
Perfect

perfect on (001) and poor on (110)

Density
2.50 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 32° · 2V calc = 62°
Refractive index
1.536 – 1.544
Surface relief
Moderate
Principal indices
nα 1.536 · nβ 1.538 · nγ 1.544
Dispersion
r < v strong
Michel-Lévy diagramhighlighted lineδ = 0.0080
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]80 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation80 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 8.875(4) Å · b = 8.881(6) Å · c = 15.79(1) Å
Ratio a:b:c
1 : 1.001 : 1.779
Z
2
Comment

space group : Pnnm or Pnn2

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2815.999447.972
50.27%
14SiSiliconSilicon828.085224.680
25.22%
20CaCalciumCalcium440.078160.312
17.99%
11NaSodiumSodium122.99022.990
2.58%
9FFluorineFluorine118.99818.998
2.13%
1HHydrogenHydrogen161.00816.128
1.81%
Total891.080100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • K

Synonyms

  • Apophyllite-Na
  • Fluorapophylliet-(Na)
  • IMA1976-032
  • Natroapofilita
  • Natroapophyllit
  • Natroapophyllite

In other languages

German
Apophyllit-(NaF) · Fluorapophyllit- · Fluorapophyllit-(Na) · IMA 1976-032 · Natroapophyllit
Italian
Apophyllite-(NaF) · Fluorapofillite- · Natroapofillite · Natroapophyllite

Classification

Strunz
10th ed.

9.EA.15

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.EASingle nets of tetrahedra with 4-, 5-, (6-), and 8-membered ringsGroup
  • 9.EA.15Fluorapophyllite-(Na)Species
Dana
8th ed.

72.03.01.03

  • 72Phyllosilicates Two-dimensional Infinite Sheets with Other Than Six-membered RingsClass
  • 72.03Two-Dimensional Infinite Sheets with Other Than Six-Membered Rings with 3-, 4-, or 5-membered rings and 8-membered ringsType
  • 72.03.01Apophyllite group (4- & 8-membered rings)Group
  • 72.03.01.03Fluorapophyllite-(Na)Species
CIM

17.1.4

  • 17Silicates Containing other AnionsClass
  • 17.1Silicates with fluoride (not containing Al)Group
  • 17.1.4Fluorapophyllite-(Na)Species

Group, growth & confusion

Literature, links & citation

Citations
  1. 1981Matsueda, Hiroharu; Miura, Yasunori; Rucklidge, John (1981) Natroapophyllite, a new orthorhombic sodium analog of apophyllite. I. Description, occurrence, and nomenclature. American Mineralogist, 66 (3-4). 410-415
  2. 2001(2001) Fluorapophyllite-(Na). Handbook of Mineralogy. Mineralogical Society of America
  3. 2013Hatert, Frédéric, Mills, Stuart J., Pasero, Marco, Williams, Peter A. (2013) CNMNC guidelines for the use of suffixes and prefixes in mineral nomenclature, and for the preservation of historical names. European Journal of Mineralogy, 25 (1) 113-115 doi:10.1127/0935-1221/2013/0025-2267DOI: 10.1127/0935-1221/2013/0025-2267
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Fluorapophyllite-(Na) — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/fluorapophyllite-na-2851},
  note      = {Accessed 2026-05-11}
}