Fluorapophyllite-(NH4)

(NH4)Ca4(Si8O20)F · 8H2O
IMA status
  • Approved
  • Pending publication
IMA symbol
Fapo-NH4
IMA approved
2019
Also known as
  • Fluorapophylliet-(NH4)
  • Fluorapophyllite-(NH₄)
  • IMA2019-083

Where it forms, where it's found

Geological setting

In cavities of quartz–illite–saponite–tobelite xenolith embedded in pyroxene andesite

Type locality
Vechec quarry
  1. Vechec
  2. Vranov nad Topľou District
  3. Prešov Region
  4. Slovakia

48.8525°, 21.6014°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104.5 – 5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colourless to light pink
Streak
White
Tenacity
brittle
Cleavage
Perfect

On (001)

Fracture
Irregular/Uneven
Density
2.325 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.5393 – 1.5414
Surface relief
Moderate
Principal indices
nω 1.5414 · nε 1.5393
Pleochroism
Non-pleochroic
UV response
Not fluorescent
Michel-Lévy diagramhighlighted lineδ = 0.0021
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]21 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation21 nm
Order1st order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
#182
Cell parameters
a = 8.99336(9) Å · c = 15.7910(3) Å
Unit cell volume
1277.18 ų
Z
2
Morphology

Forms (110), (101) and (001)

Type-locality form

Clusters, aggregates or crystalline crusts consisting of individual, well-developed crystals up to 4 mm in size

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2815.999447.972
50.55%
14SiSiliconSilicon828.085224.680
25.36%
20CaCalciumCalcium440.078160.312
18.09%
1HHydrogenHydrogen201.00820.160
2.28%
9FFluorineFluorine118.99818.998
2.14%
7NNitrogenNitrogen114.00714.007
1.58%
Total886.129100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Fluorapophylliet-(NH4)
  • Fluorapophyllite-(NH₄)
  • IMA2019-083

In other languages

German
Fluorapophyllit-(NH4) · IMA 2019-083
Italian
Fluorapofillite- · Fluorapofillite-(NH4)

Classification

Strunz
10th ed.

9.EA

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.EASingle nets of tetrahedra with 4-, 5-, (6-), and 8-membered ringsGroup
  • 9.EAFluorapophyllite-(NH4)Species

Group, growth & confusion

Literature, links & citation

Citations
  1. 2020Miyawaki, Ritsuro, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2020) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) – Newsletter 53. European Journal of Mineralogy, 32 (1) 209-213 doi:10.5194/ejm-32-209-2020 DOI: 10.5194/ejm-32-209-2020
  2. 2020Števko, Martin, Sejkora, Jiří, Plášil, Jakub, Dolníček, Zdeněk, Škoda, Radek (2020) Fluorapophyllite-(NH4), NH4Ca4(Si8O20)F⋅8H2O, a new member of the apophyllite group from the Vechec quarry, eastern Slovakia. Mineralogical Magazine, 84 (4) 533-539 doi:10.1180/mgm.2020.44DOI: 10.1180/mgm.2020.44
  3. 2022(2022) Fluorapophyllite-(NH₄). Handbook of Mineralogy. Mineralogical Society of America
  4. 2023Marincea, Ştefan; Dumitraş, Delia-Georgeta; Sava Ghineţ, Cristina; Filiuţă, Andra Elena; Dal Bo, Fabrice; Hatert, Frédéric; Costin, Gelu (2023) Ammonium-Bearing Fluorapophyllite-(K) in the Magnesian Skarns from Aleului Valley, Pietroasa, Romania. Minerals, 13 (11). 1362 doi:10.3390/min13111362DOI: 10.3390/min13111362
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Fluorapophyllite-(NH4) — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/fluorapophyllite-nh4-53993},
  note      = {Accessed 2026-05-11}
}