Hydroxyapophyllite-(K)

KCa4Si8O20(OH,F) · 8H2O
IMA status
  • Approved
IMA symbol
Hapo-K
Discovered
1978
Also known as
  • Apophyllite-(KOH)
  • Hydroksypofyllitt-(K)
  • Hydroxyapophylliet-(K)
  • +2 more

Where it forms, where it's found

Type locality
Ore Knob Mine
  1. Ore Knob
  2. Ashe County
  3. North Carolina
  4. USA

36.4087°, -81.3239°

82recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104 – 5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent · Opaque
Colour
Colorless to white · may be pink · light green · or light yellow.
Streak
white
Tenacity
brittle
Cleavage
Perfect

(001)

Fracture
Irregular/Uneven
Density
2.37 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.536 – 1.543
Surface relief
Moderate
Principal indices
nω 1.536 – 1.542 · nε 1.537 – 1.543
Michel-Lévy diagramhighlighted lineδ = 0.0010
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]10 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation10 nm
Order1st order
XPL colour

Crystallography

Crystal system
Tetragonal
Cell parameters
a = 8.978(3) Å · c = 15.83(1) Å
Z
2
Comment

Space Group: P4/mnc

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2915.999463.971
50.20%
14SiSiliconSilicon828.085224.680
24.31%
20CaCalciumCalcium440.078160.312
17.35%
19KPotassiumPotassium139.09839.098
4.23%
9FFluorineFluorine118.99818.998
2.06%
1HHydrogenHydrogen171.00817.136
1.85%
Total924.195100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Al
  • Na

Synonyms

  • Apophyllite-(KOH)
  • Hydroksypofyllitt-(K)
  • Hydroxyapophylliet-(K)
  • Hydroxyapophyllit
  • Hydroxyapophyllite

In other languages

German
Hydroxyapophyllit- · Hydroxyapophyllit-(K)
Spanish
Hidroxiapofilita- · Hidroxiapofilita-(K)
Italian
apophyllite-(KOH) · hydroxyapophyllite · idrossiapofillite · Idrossiapofillite- · idrossiapofillite-(K)

Classification

Strunz
10th ed.

9.EA.15

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.EASingle nets of tetrahedra with 4-, 5-, (6-), and 8-membered ringsGroup
  • 9.EA.15Hydroxyapophyllite-(K)Species
CIM

17.1.6

  • 17Silicates Containing other AnionsClass
  • 17.1Silicates with fluoride (not containing Al)Group
  • 17.1.6Hydroxyapophyllite-(K)Species

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. Chalokwu, C.I., Yau, Y.C. (1985) Hydroxyapophyllite in hornfels beneath the Duluth Complex, northeastern Minnesota. The Canadian Mineralogist 23, 489-490.
  2. 1978Dunn, Pete J.; Rouse, Roland C.; Norberg, Julie A. (1978) Hydroxyapophyllite, a new mineral, and a redefinition of the apophyllite group. I. Description, occurrences, and nomenclature. American Mineralogist, 63 (1-2). 196-198
  3. 1978Rouse, Roland C., Peacor, Donald R., Dunn, Pete J. (1978) Hydroxyapophyllite, a new mineral, and a redefinition of the apophyllite group. II. Crystal structure. American Mineralogist, 63 (1-2). 196-202
  4. 1978Wilson, Wendell E., Dunn, Pete J. (1978) Nomenclature revisions in the apophyllite group: hydroxyapophyllite, apophyllite, fluorapophyllite. The Mineralogical Record, 9 (2) 95-98
  5. 1987Acta Crystallographica: (1987): B43: 517.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hydroxyapophyllite-(K) — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hydroxyapophyllite-k-1989},
  note      = {Accessed 2026-05-11}
}