Gatewayite

Ca6(As3+V4+3V5+9As5+6O51) · 31H2O
IMA status
  • Approved
IMA symbol
Gwy
IMA approved
2015
Also known as
  • Gatewayiet
  • IMA2014-096

Where it forms, where it's found

Geological setting

On montroseite- and corvusite-bearing sandstone. Oxidation of montroseite-corvusite assemblage in a moist environment.

Type locality
Packrat Mine
  1. Beaver Mesa
  2. Gateway Mining District
  3. Mesa County
  4. Colorado
  5. USA

38.6476°, -109.0471°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Very dark greenish blue
Streak
Grayish blue
Tenacity
brittle
Cleavage
Imperfect/Fair

(010) and (101) fair

Density
2.34 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 65.9° · 2V calc = 65.0°
Refractive index
1.621 – 1.668
Surface relief
Moderate
Principal indices
nα 1.621 · nβ 1.654 · nγ 1.668
Pleochroism

X pale olive green, Y medium greenish blue, Z dark greenish blue; X < < Y < Z

Dispersion
Extreme
UV response
None
Notes

Y = b, X^a ≈ 30° in obtuse β

Michel-Lévy diagramhighlighted lineδ = 0.0470
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]470 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation470 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21
Cell parameters
a = 11.1850(4) Å · b = 16.8528(4) Å · c = 20.7146(15) Å
Cell angles
β = 91.166(6) °
Ratio a:b:c
1 : 1.507 : 1.852
Unit cell volume
3903.9 ų
Z
2
Morphology

Blades, more or less flattened on (101) and elongated on [010].

Type-locality form

Blades up to 0.5 mm long in divergent inter-growths. Also as crude prisms, up to 1 mm long, with rounded faces and as composite crystals consisting of subparallel inter-growths of narrow prisms up to 2 mm long.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen8215.9991311.918
47.70%
23VVanadiumVanadium1250.942611.304
22.22%
33AsArsenicArsenic774.922524.454
19.07%
20CaCalciumCalcium640.078240.468
8.74%
1HHydrogenHydrogen621.00862.496
2.27%
Total2750.640100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Gatewayiet
  • IMA2014-096

In other languages

German
Gatewayit · IMA 2014-096
Italian
gatewayite

Classification

Strunz
10th ed.

8.FD.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.FPolyphosphates, Polyarsenates, [4]-PolyvanadatesDivision
  • 8.FDPolyphosphates, etc., with OH and H2OGroup
  • 8.FD.10GatewayiteSpecies

Group, growth & confusion

In the same group
4 members

Literature, links & citation

Citations
  1. 2015Hålenius, U., Hatert, F., Pasero, M., Mills, S. J. (2015) New minerals and nomenclature modifications approved in 2015, CNMNC Newsletter No 24. Mineralogical Magazine, 79 (2) 247-251 doi:10.1180/minmag.2015.079.2.03DOI: 10.1180/minmag.2015.079.2.03
  2. 2016Kampf, Anthony R., Hughes, John M., P. Nash, Barbara, Marty, Joe (2016) Vanarsite, packratite, morrisonite, and gatewayite: four new minerals containing the [As3+V4+,5+12As5+6O51] heteropolyanion, a novel polyoxometalate cluster. The Canadian Mineralogist, 54 (1) 145-162 doi:10.3749/canmin.1500062 DOI: 10.3749/canmin.1500062
  3. 2017(2017) Gatewayite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Gatewayite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/gatewayite-46572},
  note      = {Accessed 2026-05-11}
}