Vanarsite

NaCa12(As3+V5+8.5V4+3.5As5+6O51)2 · 78H2O
IMA status
  • Approved
IMA symbol
Vns
IMA approved
2014
Also known as
  • IMA2014-031
  • Vanarsiet

Where it forms, where it's found

Geological setting

On montroseite- and corvusite-bearing sandstone.

Type locality
Packrat Mine
  1. Beaver Mesa
  2. Gateway Mining District
  3. Mesa County
  4. Colorado
  5. USA

38.6476°, -109.0471°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Very dark blue
Streak
Grayish blue
Tenacity
brittle
Cleavage
Imperfect/Fair

(100)

Density
2.48 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 37°
Refractive index
1.645 – 1.681
Surface relief
High
Principal indices
nα 1.645 · nβ 1.677 · nγ 1.681
Pleochroism
Visible

X cornflower blue, Y dark blue, Z dark blue; X << Z~Y

Dispersion
Not observable
UV response
None
Michel-Lévy diagramhighlighted lineδ = 0.0360
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]360 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation360 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 25.8902(8) Å · b = 10.9468(3) Å · c = 28.2980(8) Å
Cell angles
β = 102.252(1) °
Ratio a:b:c
1 : 0.423 : 1.093
Unit cell volume
7828.9 ų
Z
2
Morphology

Blades flattened on (100) and elongated on [010].

Type-locality form

Sub-parallel intergrowths and fan-like or finger-like aggregates up to about 5 mm in length.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen18015.9992879.820
49.54%
23VVanadiumVanadium2450.9421222.608
21.03%
33AsArsenicArsenic1474.9221048.908
18.05%
20CaCalciumCalcium1240.078480.936
8.27%
1HHydrogenHydrogen1561.008157.248
2.71%
11NaSodiumSodium122.99022.990
0.40%
Total5812.510100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2014-031
  • Vanarsiet

In other languages

German
IMA 2014-031 · Vanarsit
Italian
vanarsite

Classification

Strunz
10th ed.

8.FD.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.FPolyphosphates, Polyarsenates, [4]-PolyvanadatesDivision
  • 8.FDPolyphosphates, etc., with OH and H2OGroup
  • 8.FD.10VanarsiteSpecies

Group, growth & confusion

In the same group
4 members

Literature, links & citation

Citations
  1. 2014Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2014) New minerals and nomenclature modifications approved in 2014, CNMNC Newsletter No 21. Mineralogical Magazine, 78 (4) 797-804 doi:10.1180/minmag.2014.078.4.03DOI: 10.1180/minmag.2014.078.4.03
  2. 2016Kampf, Anthony R., Hughes, John M., P. Nash, Barbara, Marty, Joe (2016) Vanarsite, packratite, morrisonite, and gatewayite: four new minerals containing the [As3+V4+,5+12As5+6O51] heteropolyanion, a novel polyoxometalate cluster. The Canadian Mineralogist, 54 (1) 145-162 doi:10.3749/canmin.1500062 DOI: 10.3749/canmin.1500062
  3. 2017(2017) Vanarsite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Vanarsite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/vanarsite-46169},
  note      = {Accessed 2026-05-11}
}