Morrisonite

Ca11(As3+V4+2V5+10As5+6O51)2 · 78H2O
IMA status
  • Approved
IMA symbol
Mris
IMA approved
2014
Also known as
  • IMA2014-088
  • Morrisoniet

Where it forms, where it's found

Geological setting

On montroseite- and corvusite-bearing sandstone. Oxidation of montroseite-corvusite assemblage in a moist environment.

Type locality
Packrat Mine
  1. Beaver Mesa
  2. Gateway Mining District
  3. Mesa County
  4. Colorado
  5. USA

38.6476°, -109.0471°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Very dark blue
Streak
Grayish blue
Tenacity
brittle
Cleavage
Perfect

(010) perfect, (100) good

Density
2.29 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 58°
Refractive index
1.611 – 1.637
Surface relief
Moderate
Principal indices
nα 1.611 · nβ 1.631 · nγ 1.637
Pleochroism

X blue, Y dark blue, Z dark blue; X < < Y ≈ Z

Dispersion
not observable
UV response
None
Michel-Lévy diagramhighlighted lineδ = 0.0260
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]260 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation260 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 14.957(2) Å · b = 48.208(6) Å · c = 23.836(3) Å
Cell angles
β = 90.034(6) °
Ratio a:b:c
1 : 3.223 : 1.594
Unit cell volume
17187 ų
Z
4
Morphology

Blades, flattened on (010) and elongated on [100]

Type-locality form

Blades up to about 1 mm long, striated lengthwise, growing in sub-parallel and divergent intergrowths.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen18015.9992879.820
50.09%
23VVanadiumVanadium2450.9421222.608
21.26%
33AsArsenicArsenic1474.9221048.908
18.24%
20CaCalciumCalcium1140.078440.858
7.67%
1HHydrogenHydrogen1561.008157.248
2.74%
Total5749.442100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2014-088
  • Morrisoniet

In other languages

German
IMA 2014-088 · Morrisonit
Italian
morrisonite

Classification

Strunz
10th ed.

8.FD.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.FPolyphosphates, Polyarsenates, [4]-PolyvanadatesDivision
  • 8.FDPolyphosphates, etc., with OH and H2OGroup
  • 8.FD.10MorrisoniteSpecies

Group, growth & confusion

In the same group
4 members

Literature, links & citation

Citations
  1. 2015Hålenius, U., Hatert, F., Pasero, M., Mills, S. J. (2015) New minerals and nomenclature modifications approved in 2015, CNMNC Newsletter No 24. Mineralogical Magazine, 79 (2) 247-251 doi:10.1180/minmag.2015.079.2.03DOI: 10.1180/minmag.2015.079.2.03
  2. 2016Kampf, Anthony R., Hughes, John M., P. Nash, Barbara, Marty, Joe (2016) Vanarsite, packratite, morrisonite, and gatewayite: four new minerals containing the [As3+V4+,5+12As5+6O51] heteropolyanion, a novel polyoxometalate cluster. The Canadian Mineralogist, 54 (1) 145-162 doi:10.3749/canmin.1500062 DOI: 10.3749/canmin.1500062
  3. 2017(2017) Morrisonite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Morrisonite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/morrisonite-46557},
  note      = {Accessed 2026-05-11}
}