Grischunite

NaCa2Mn2+5Fe3+(AsO4)6 · 2H2O
IMA status
  • Approved
IMA symbol
Gcn
Discovered
1981
IMA approved
1981
Also known as
  • Grischuniet
  • IMA1981-028

Where it forms, where it's found

Geological setting

Alpine metamorphism of manganese ores, with abundant arsenic in surrounding rock.

Type locality
Falotta
  1. Tinizong (Tinzen)
  2. Surses
  3. Albula Region
  4. Grisons
  5. Switzerland

46.5533°, 9.6469°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789105/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Translucent
Colour
Dark red-brown.
Streak
Yellow red to yellow brown
Cleavage
Perfect

Perfect along (010)

Density
3.8 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 40 – 50° · 2V calc = 50°
Refractive index
1.784 – 1.79
Surface relief
High
Principal indices
nα 1.784 · nβ 1.785 · nγ 1.790
Pleochroism
Visible

X = yellow green (X||b), Y = yellow brown (Y||a), and Z = dark red brown (Z||c)

Dispersion
extreme, r << v
Notes

absorption Z ≃ Y » X

Michel-Lévy diagramhighlighted lineδ = 0.0060
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]60 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation60 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 12.855(2) Å · b = 13.487(2) Å · c = 12.047(1) Å
Ratio a:b:c
1 : 1.049 : 0.937
Z
4
Morphology

Lathlike crystals, elongated along b.

Type-locality form

Anhedral grains and lathlike crystals

Comment

Space Group: P cab.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
33AsArsenicArsenic674.922449.532
34.49%
8OOxygenOxygen2615.999415.974
31.92%
25MnManganeseManganese554.938274.690
21.08%
20CaCalciumCalcium240.07880.156
6.15%
26FeIronIron155.84555.845
4.29%
11NaSodiumSodium122.99022.990
1.76%
1HHydrogenHydrogen41.0084.032
0.31%
Total1303.219100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Grischuniet
  • IMA1981-028

In other languages

German
Grischunit · IMA 1981-028
Italian
Grischunite

Classification

Strunz
10th ed.

8.CF.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CFWith large and medium-sized cations, RO4:H2O > 1:1Group
  • 8.CF.05GrischuniteSpecies
Dana
8th ed.

40.02.11.01

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.02AB2(XO4)2·xH2OType
  • 40.02.11— unnamed intermediate level —Group
  • 40.02.11.01GrischuniteSpecies
CIM

20.8.22

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.8Arsenates of MnGroup
  • 20.8.22GrischuniteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1984Graeser, S.; Schwander, H.; Suhner, B. (1984) Grischunit (CaMn₂(AsO₄)₂), eine neue Mineralart aus den Schweizer Alpen. Zur Mn-As-Mineralisation des Oberhalbstein-Gebietes (I) [Grischunite (CaMn₂(AsO₄)₂), a new mineral species from the Swiss Alps. On the Mn-As mineralization of the Oberhalbstein area (I)]. Schweizerische mineralogische und petrographische Mitteilungen, 64 (1-2). 1-10
  2. 1986Dunn, Pete J., Chao, George Y., Fitzpatrick, Joan J., Langley, Richard H., Fleischer, Michael, Zilczer, Janet A. (1986) New Mineral Names. American Mineralogist, 71 (1-2). 227-232
  3. 1987Bianchi, R., Pilati, T., Mannucci, G. (1987) Crystal structure of grischunite. American Mineralogist: 72: 1225-1229.
  4. 2005(2005) Grischunite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Grischunite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/grischunite-1753},
  note      = {Accessed 2026-05-11}
}