Liraite

NaCa2Mn2+2[Fe3+Fe2+]Mn2+2(PO4)6(H2O)2
IMA status
  • Approved
IMA symbol
Lir
IMA approved
2019
Also known as
  • IMA2019-085
  • Liraiet

Where it forms, where it's found

Geological setting

In the intermediate zone of a muscovite-rare element class pegmatite.

Type locality
Ceferino Namuncurá pegmatite
  1. Parroquia District
  2. Pocho Department
  3. Córdoba Province
  4. Argentina

-31.6292°, -65.2508°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Dark brown with greenish hues (nearly black) · dark olive green in slices
Streak
Dark brownish green
Tenacity
brittle
Cleavage
Very Good

One very good cleavage, and orthogonal to that one good cleavage.

Fracture
Irregular/Uneven
Density
3.52 g/cm³

Optical

Optical type
· 2V calc = 69.2°
Refractive index
1.732 – 1.754
Surface relief
High
Principal indices
nα 1.732 · nβ 1.739 · nγ 1.754
Pleochroism

X = Y = olive, Z = yellowish brown

Extinction
Transmission: X = Y > Z
Michel-Lévy diagramhighlighted lineδ = 0.0220
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]220 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation220 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 12.608(6) Å · b = 12.918(6) Å · c = 11.737(4) Å
Ratio a:b:c
1 : 1.025 : 0.931
Unit cell volume
1911.6 ų
Z
4
Type-locality form

Ellipsoidal nodules up to 20 cm in diameter

Comment

Spacegroup: Pcab (CNMNC Newsletter 53)

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2615.999415.974
39.98%
25MnManganeseManganese454.938219.752
21.12%
15PPhosphorusPhosphorus630.974185.844
17.86%
26FeIronIron255.845111.690
10.74%
20CaCalciumCalcium240.07880.156
7.70%
11NaSodiumSodium122.99022.990
2.21%
1HHydrogenHydrogen41.0084.032
0.39%
Total1040.438100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2019-085
  • Liraiet

In other languages

German
IMA 2019-085 · Lirait
Spanish
Liraíta

Classification

Strunz
10th ed.

8.CF

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CFWith large and medium-sized cations, RO4:H2O > 1:1Group
  • 8.CFLiraiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 2020Miyawaki, Ritsuro, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2020) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) – Newsletter 53. European Journal of Mineralogy, 32 (1) 209-213 doi:10.5194/ejm-32-209-2020 DOI: 10.5194/ejm-32-209-2020
  2. 2021Biglia, Marco E., Cooper, Mark A., Grew, Edward S., Yates, Martin G., Sfragulla, Jorge A., Guereschi, Alina B., Márquez-Zavalía, María F., Galliski, Miguel A. (2021) Liraite, ideally NaCa2Mn2[Fe3+Fe2+]Mn2(PO4)6(H2O)2, a new phosphate mineral of the wicksite group from the Ceferino Namuncurá pegmatite, Córdoba, Argentina. The Canadian Mineralogist, 59 (4) 751-761 doi:10.3749/canmin.2000110DOI: 10.3749/canmin.2000110
  3. 2022(2022) Liraite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Liraite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/liraite-54244},
  note      = {Accessed 2026-05-11}
}