Where it forms, where it's found
- Geological setting
Late stage mineralization in vugs in Banded Iron Formation (BIF)
- Type locality
- Sagamore Mangan No. 2 pit
- Riverton
- Cuyuna North Range
- Crow Wing County
- Minnesota
- USA
46.4536°, -94.0506°
Physical
Optical
- Optical type
- Biaxial (+) · 2V measured = 40 – 50°
- Refractive index
- 2.1 – 2.2
- Surface relief
- Very high
- Principal indices
- nα 2.1 – 2.2 · nγ 2.1 – 2.2
- Birefringence
- 0.100
- Pleochroism
- Strong
X = very dark brown to black; Y = yellowish brown.
- Extinction
- Parallel
- Reflectance R%
- (13.7 ,22.0) 400, (13.4 ,21.3) 420, (13.3 ,20.7) 440, (13.1, 20.2) 460, (13.0, 19.7) 480, (13.0, 19.4) 500, (12.9, 19.1) 520, (12.9, 19.0) 540, (12.8, 19.0) 560, (12.7, 18.7) 580, (12.7, 18.6) 600, (12.7, 18.5) 620, (12.6, 18.3) 640, (12.5, 18.2) 660, (12.4, 18.0) 680, (12.4, 17.9) 700
- UV response
- Not fluorescent in ultraviolet
- Notes
Strong pleochroism distinguishes groutite from manganite.
Crystallography
- Space group
- #71
- Cell parameters
- a = 4.560 Å · b = 10.700 Å · c = 2.870 Å
- Ratio a:b:c
- 1 : 2.346 : 0.629
- Z
- 4
- Morphology
Wedge- or lens-shaped crystals. Type material showed: (110), (120), (130), (010), (100), (111), (021), (134)
- Twinning
Reported. [Compare twinning in isostructural diaspore.]
- Comment
Non-standard space-group setting Pbnm.
Chemical composition
Synonyms
- Groutiet
In other languages
- French
- Groutite
- German
- Groutit
- Spanish
- Groutita
- Italian
- Groutite
- Chinese
- 斜方水锰矿
Classification
4.FD.10
- 4OxidesClass
- 4.FHydroxides (without V or U)Division
- 4.FDHydroxides with OH, without H2O; chains of edge-sharing octahedraGroup
- 4.FD.10GroutiteSpecies
06.01.01.03
- 06Hydroxides and Oxides Containing HydroxylClass
- 06.01XO(OH)Type
- 06.01.01Diaspore group (Orthorhombic, Pnma or Pnmd)Group
- 06.01.01.03GroutiteSpecies
7.18.8
- 7Oxides and HydroxidesClass
- 7.18Oxides of MnGroup
- 7.18.8GroutiteSpecies
Group, growth & confusion
Literature, links & citation
- 1947Gruner, John W. (1947) Groutite, HMnO2, a new mineral of the diaspore-goethite group. American Mineralogist, 32 (11-12) 654-659
- 1948Fleischer, M. (1948) New mineral names. American Mineralogist, 33 (5-6). 384-386
- 1949Collin, R. L., Lipscomb, W. N. (1949) The crystal structure of groutite, HMnO2. Acta Crystallographica, 2 (2) 104-106 doi:10.1107/s0365110x49000230DOI: 10.1107/s0365110x49000230
- 1959Klingsberg, C., Roy, R. (1959) Stability and interconvertibility of phases in the system Mn-O-OH. American Mineralogist, 44 (7-8) 819-838
- 1959Segeler, Curt G. (1959) Notes on a second occurrence of groutite. American Mineralogist, 44 (7-8) 877-878
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Groutite — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/groutite-1756},
note = {Accessed 2026-05-11}
}



