Groutite

Mn3+O(OH)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Gro
Discovered
1945
Also known as
  • Groutiet

Where it forms, where it's found

Geological setting

Late stage mineralization in vugs in Banded Iron Formation (BIF)

Type locality
Sagamore Mangan No. 2 pit
  1. Riverton
  2. Cuyuna North Range
  3. Crow Wing County
  4. Minnesota
  5. USA

46.4536°, -94.0506°

71recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Black · may be iridescent
Streak
dark brown
Tenacity
brittle
Cleavage
Perfect

Perfect on (010) Less perfect (100)

Fracture
Irregular/Uneven · Splintery
Density
4.144 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 40 – 50°
Refractive index
2.1 – 2.2
Surface relief
Very high
Principal indices
nα 2.1 – 2.2 · nγ 2.1 – 2.2
Birefringence
0.100
Pleochroism
Strong

X = very dark brown to black; Y = yellowish brown.

Extinction
Parallel
Reflectance R%
(13.7 ,22.0) 400, (13.4 ,21.3) 420, (13.3 ,20.7) 440, (13.1, 20.2) 460, (13.0, 19.7) 480, (13.0, 19.4) 500, (12.9, 19.1) 520, (12.9, 19.0) 540, (12.8, 19.0) 560, (12.7, 18.7) 580, (12.7, 18.6) 600, (12.7, 18.5) 620, (12.6, 18.3) 640, (12.5, 18.2) 660, (12.4, 18.0) 680, (12.4, 17.9) 700
UV response
Not fluorescent in ultraviolet
Notes

Strong pleochroism distinguishes groutite from manganite.

Reflected-light panel
12.9 %anisotropic · dual curve
Specimen sRGB 134, 93, 50
White reference100 % reflector under same lamp
R₁ R₂
Mode

Crystallography

Crystal system
Orthorhombic
Space group
#71
Cell parameters
a = 4.560 Å · b = 10.700 Å · c = 2.870 Å
Ratio a:b:c
1 : 2.346 : 0.629
Z
4
Morphology

Wedge- or lens-shaped crystals. Type material showed: (110), (120), (130), (010), (100), (111), (021), (134)

Twinning

Reported. [Compare twinning in isostructural diaspore.]

Comment

Non-standard space-group setting Pbnm.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
25MnManganeseManganese154.93854.938
62.47%
8OOxygenOxygen215.99931.998
36.38%
1HHydrogenHydrogen11.0081.008
1.15%
Total87.944100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Groutiet

In other languages

French
Groutite
German
Groutit
Spanish
Groutita
Italian
Groutite
Chinese
斜方水锰矿

Classification

Strunz
10th ed.

4.FD.10

  • 4OxidesClass
  • 4.FHydroxides (without V or U)Division
  • 4.FDHydroxides with OH, without H2O; chains of edge-sharing octahedraGroup
  • 4.FD.10GroutiteSpecies
Dana
8th ed.

06.01.01.03

  • 06Hydroxides and Oxides Containing HydroxylClass
  • 06.01XO(OH)Type
  • 06.01.01Diaspore group (Orthorhombic, Pnma or Pnmd)Group
  • 06.01.01.03GroutiteSpecies
CIM

7.18.8

  • 7Oxides and HydroxidesClass
  • 7.18Oxides of MnGroup
  • 7.18.8GroutiteSpecies

Group, growth & confusion

In the same group
5 members
Commonly confused with
4 minerals

Literature, links & citation

Citations
  1. 1947Gruner, John W. (1947) Groutite, HMnO2, a new mineral of the diaspore-goethite group. American Mineralogist, 32 (11-12) 654-659
  2. 1948Fleischer, M. (1948) New mineral names. American Mineralogist, 33 (5-6). 384-386
  3. 1949Collin, R. L., Lipscomb, W. N. (1949) The crystal structure of groutite, HMnO2. Acta Crystallographica, 2 (2) 104-106 doi:10.1107/s0365110x49000230DOI: 10.1107/s0365110x49000230
  4. 1959Klingsberg, C., Roy, R. (1959) Stability and interconvertibility of phases in the system Mn-O-OH. American Mineralogist, 44 (7-8) 819-838
  5. 1959Segeler, Curt G. (1959) Notes on a second occurrence of groutite. American Mineralogist, 44 (7-8) 877-878
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Groutite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/groutite-1756},
  note      = {Accessed 2026-05-11}
}