Manganite

Mn3+O(OH)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Mnn
Discovered
1827
Also known as
  • Acerdèse
  • Braunmanganerz
  • Glanzmanganerz
  • +12 more

History

Long before anyone gave it a name, manganite was already useful. Powder of the black mineral turns up at Neanderthal sites, where it served two purposes. It worked as a pigment, and it helped start fires: ground manganite lowers the temperature at which wood ignites, from about 350 °C down to 250 °C.

The mineral was described under several other names as early as 1772, before mineralogists settled on a single one. That came in 1827, when the Austrian mineralogist Wilhelm Karl von Haidinger published the name manganite, chosen for the mineral's manganese content.

The finest crystals come from Ilfeld, in the Harz mountains of Germany. There manganite grows in veins alongside calcite and barite, in dark steel-grey prisms striated along their length. These specimens made the locality famous among collectors and supplied the material that mineralogists first studied closely.

Industrial & practical applications

Manganite carries manganese — the metal that hardens steel and fills dry-cell batteries — but the world rarely turns to manganite to get it. As an ore it is much less abundant than pyrolusite or psilomelane, the two oxides that supply most of the manganese industry uses. Where manganite gathers in quantity it can be worked as a local source, yet the metal that reaches steel mills and battery plants comes overwhelmingly from those richer ores, not from this one.

Its larger value today is to collectors. The bundled steel-grey crystals from Ilfeld, in the Harz mountains of Germany, are prized specimens and the reason the mineral is so well known.

Where it forms, where it's found

Geological setting

Hydrothermal veins

Low temperature hydrothermal or hot spring manganese deposits. Sedimentary deposits.

Type locality
Manganese deposit
  1. Ilfeld
  2. Harztor
  3. Nordhausen District
  4. Thuringia
  5. Germany

51.5917°, 10.7511°

706recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Gray-black · black
Streak
Reddish brown to black
Tenacity
brittle
Cleavage
Perfect

(010) perfect; (110) and (001) good.

Fracture
Splintery
Density
4.29 g/cm³

Optical

Optical type
Biaxial (+)
Refractive index
2.25 – 2.53
Surface relief
Very high
Principal indices
nα 2.25 · nβ 2.25 · nγ 2.53
Birefringence
0.028
Pleochroism
Weak

X = reddish brown; Z = red brown.

Dispersion
r > v extreme
Extinction
X = a; Y = b; Z ∧ c = 0°–4°.
Optical colour
Gray-white with brown tint
Anisotropism
Weak
Bireflectance
Distinct in grays
Internal reflections
Blood-red
Tropism
Anisotropic
Reflectance R%
(18.0,25.1) 400, (18.0,24.8) 420, (18.0,24.5) 440, (17.9,24.1) 460, (17.8,23.7) 480, (17.6,23.2) 500, (17.3,22.7) 520, (17.0,22.2) 540, (16.8,21.6) 560, (16.5,21.2) 580, (16.3,20.8) 600, (16.1,20.6) 620, (16.0,20.3) 640, (15.8,20.1) 660, (15.7,19.9) 680, (15.7,19.7) 700
UV response
Not fluorescent in ultraviolet.
Notes

Weak pleochroism distinguishes manganite from groutite. Absorption: Z > X = Y.

Reflected-light panel
16.9 %anisotropic · dual curve
Specimen sRGB 149, 106, 59
White reference100 % reflector under same lamp
R₁ R₂
Mode
Bireflectance
Distinct in grays
Anisotropism
Weak
Reflected colour
Gray-white with brown tint
Internal reflections
Blood-red

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 8.94 Å · b = 5.28 Å · c = 5.74 Å
Cell angles
β = 90 °
Ratio a:b:c
1 : 0.591 : 0.642
Z
8
Morphology

Crystals striated and short to long prismatic [001]. Often terminated by (001) alone, by (001) with macrodomes, or by a series of macropyramids; highly modified at times. Prismatic faces deeply striated [001], and terminal {h0l} or {hkl} faces striated parallel to their mutual intersections. Crystals often grouped or markedly composite subparallel [001]. Stalactitic; granular (rare).

Twinning

1. On (011), both as contact and penetration twins. Twinning often repeated with composition face either parallel or inclined. 2. Twin plane (100) lamellar, assuming a monoclinic symmetry for the species.

Type-locality form

Coarse rectangular prism, often with multiple parallel growth.

Comment

Space group B21/d (non-standard setting); pseudo-orthorhombic.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
25MnManganeseManganese154.93854.938
62.47%
8OOxygenOxygen215.99931.998
36.38%
1HHydrogenHydrogen11.0081.008
1.15%
Total87.944100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Ba
  • Pb
  • Cu
  • Al
  • Ca

Synonyms

  • Acerdèse
  • Braunmanganerz
  • Glanzmanganerz
  • Grau-Braunsteinerz
  • Graumanganerz
  • Gray Oxide of Manganese
  • Manganaise cristallisé
  • Manganèse oxydé metalloïde
  • Newkirkit
  • Newkirkita
  • Newkirkite
  • Prismatoidisches Mangan-Erz
  • Sphenomanganit
  • Sphenomanganita
  • Sphenomanganite

In other languages

French
Acerdèse · Magnésie noire · Manganaise cristallisée · Manganèse satinée · manganite · Newkirkite · Pierre de Périgueux · Savon des verriers · Sphénomanganite
German
Braunstein · Manganit
Spanish
manganita
Italian
Manganite
Portuguese
manganite
Japanese
水マンガン鉱
Chinese
水錳礦 · 水锰矿
Russian
Манганит
Arabic
منغنيت

Classification

Strunz
10th ed.

4.FD.15

  • 4OxidesClass
  • 4.FHydroxides (without V or U)Division
  • 4.FDHydroxides with OH, without H2O; chains of edge-sharing octahedraGroup
  • 4.FD.15ManganiteSpecies
Dana
8th ed.

06.01.03.01

  • 06Hydroxides and Oxides Containing HydroxylClass
  • 06.01XO(OH)Type
  • 06.01.03— unnamed intermediate level —Group
  • 06.01.03.01ManganiteSpecies
CIM

7.18.7

  • 7Oxides and HydroxidesClass
  • 7.18Oxides of MnGroup
  • 7.18.7ManganiteSpecies

Group, growth & confusion

Often grow together
5 minerals
Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1826von Haidinger, W.K. (1826) On the crystalline forms and properties of the manganese ores. The Edinburgh Journal of Science: 4: 41-50.
  2. 1828Haidinger, W. (1828) Mineralogical Account of the Ores of Manganese. Transactions of the Royal Society of Edinburgh, 11 (1). p.119-142. doi:10.1017/s0080456800021876DOI: 10.1017/s0080456800021876
  3. 1828Turner, E. (1828) Chemical examination of the oxides of manganese. Part II. On the composition of the ores of manganese described by Mr. Haidinger. The Philosophical Magazine: 4: 96-104.
  4. 1866How, H. (1866) Contributions to the Mineralogy of Nova Scotia, Pt. I, Manganite, Pyrolusite, Wad. Philosophical Magazine, Series 4: 31(208): 165-170.
  5. 1892Rutley, Frank (1892) Note on Crystals of Manganite from Harzgerode. Mineralogical Magazine and Journal of the Mineralogical Society, 10 (45) 20-21 doi:10.1180/minmag.1892.010.45.05 DOI: 10.1180/minmag.1892.010.45.05
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Manganite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/manganite-2519},
  note      = {Accessed 2026-05-11}
}