Goethite

FeO(OH)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Gth
Discovered
1806
Also known as

History

Long before it had a name, goethite was on the walls of caves. The mineral turns up in paint samples from the caves of Lascaux in France. It is one of the brown ochres — earth pigments built around iron oxides. Paleolithic painters also heat-treated it to produce a red pigment. Warmed enough, goethite — a hydrated iron oxide — loses its water and becomes hematite, a deep red iron oxide.

The mineral kept its place in the ochre trade long after the Paleolithic. One striking example comes from Phrygia in Asia Minor. The burial shroud of King Gordias was coloured with a dye containing goethite. In its un-faded state, the shroud would have looked as though it were woven from gold.

The formal mineralogical naming came much later. The mineral was first described in 1806, from samples at the Hollertszug Mine in Herdorf, Germany. It was named that year by the German mineralogist Johann Georg Lenz, in honour of Johann Wolfgang von Goethe. Goethe is remembered as a poet and novelist, but he was also a philosopher and a politician. He served as Chief Minister of State of Weimar. He was also a geoscientist with a working interest in minerals — and the dedication acknowledged that side of him.

Industrial & practical applications

The main modern use of goethite is as an iron ore. Mined in bulk, it is often called brown iron ore in the trade. It is the primary iron mineral in some important deposits — the Alsace-Lorraine basin in France being a long-standing example. Further major sources are spread across Brazil, South Africa, Russia, Australia and the southern Appalachians. Iron-rich lateritic soils — the deep red weathering layers that form in tropical climates — also yield goethite-bound iron and other metals when mined.

The mineral also remains in use as a pigment. It is the source of the artists' colour known as yellow ochre — an earth pigment built around hydrated iron oxide.

Goethite also has a small place in jewellery. Banded or iridescent varieties are cut and polished into cabochons — domed, unfaceted gems with a smooth top — and set for decorative use.

Where it forms, where it's found

Geological setting

Common weathering product, primary hydrothermal mineral, bog and marine environments.

Type locality
Hollertszug Mine (Hollerter Zug Mine)
  1. Dermbach
  2. Herdorf
  3. Daaden-Herdorf
  4. Altenkirchen
  5. Rhineland-Palatinate
  6. Germany

50.7794°, 7.9300°

7,898recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789105 – 5.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Brownish black · yellow-brown · reddish brown
Streak
Yellowish brown, orange-yellow, ocher-yellow
Tenacity
brittle
Cleavage
Perfect

(010); (100) less perfect.

Fracture
Irregular/Uneven
Density
4.27 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 27° · 2V calc = 20°
Refractive index
2.26 – 2.409
Surface relief
Very high
Principal indices
nα 2.260 – 2.275 · nβ 2.393 – 2.409 · nγ 2.393 – 2.409
Pleochroism
Strong

X = red b/yellow b = clear yellow Y = red a/yellow c = brown-yellow Z = red c/yellow a = orange-yellow

Dispersion
relatively strong r>v
Extinction
X = b; Y = c; Z = a.
Optical colour
Gray with bluish tint
Anisotropism
Distinct; in bluish grays
Internal reflections
Yellow, red, brown
Tropism
Anisotropic
Reflectance R%
(17.5,19.2) 400, (16.7,18.3) 420, (15.9,17.4) 440, (15.2,16.7) 460, (14.6,16.0) 480, (14.1,15.5) 500, (13.7,15.0) 520, (13.3,14.6) 540, (13.0,14.3) 560, (12.8,14.0) 580, (12.5,13.7) 600, (12.4,13.5) 620, (12.2,13.4) 640, (12.0,13.2) 660, (12.0,13.1) 680, (11.9,13.0) 700
Notes

Absorption: Z > Y > X.

Reflected-light panel
13.7 %anisotropic · dual curve
Specimen sRGB 132, 94, 56
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Distinct; in bluish grays
Reflected colour
Gray with bluish tint
Internal reflections
Yellow, red, brown

Crystallography

Crystal system
Orthorhombic
Space group
#71
Cell parameters
a = 4.608 Å · b = 9.956 Å · c = 3.0215 Å
Ratio a:b:c
1 : 2.161 : 0.656
Z
4
Morphology

Prismatic [001] and striated [001]; also flattened into tablets or scales on (010). Velvety aggregates of capillary crystals to acicular [001] and long prismatic forms often radially grouped. Massive, reniform, botryoidal, stalactitic. Bladed or columnar. Compact or fibrous concretionary nodules. Oolitic.

Twinning

Apparently none reported, but see https://www.mindat.org/mesg-631125.html and compare twinning in isostructural <m>diaspore</m>.

Comment

Non-standard space-group setting Pbnm.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
26FeIronIron155.84555.845
62.85%
8OOxygenOxygen215.99931.998
36.01%
1HHydrogenHydrogen11.0081.008
1.14%
Total88.851100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Mn

Synonyms

  • Aëtit
  • Allcharit
  • Allcharita
  • Allcharite
  • Chileit (of Breithaupt)
  • Ehrenwerthite (of Cornu)
  • Fullonit
  • Fullonita
  • Fullonite
  • Geothite
  • Goetite
  • Götheit
  • Götheita
  • Götheite
  • Göthit
  • Göthita
  • Göthite
  • Haarförminge Brauneisenstein
  • Haarförminger Brauneisenstein
  • Hierro pardo
  • Hydrohämatit
  • Mesabit
  • Mesabita
  • Mesabite
  • Nadeleisenerz
  • Prismatisches Eisenerz
  • Prismatisches Nadeleisenerz
  • Przibramite (of Glocker)
  • Samteisenerz
  • Schwarzer Glaskopf
  • Yanthosiderit
  • Yanthosiderita
  • Yanthosiderite
  • α-Goethit
  • α-Goethita
  • α-Goethite

In other languages

French
20344-49-4 · allcharite · alumogoethite · chiléite · ehrenwerthite · fer hydroxylé oolitique · fullonite · goethite · hydrohématite · mésabite · onégite · yanthosiderite
German
Brauner Glaskopf · Goethit · Nadeleisenerz · Samtblende
Spanish
goethita · goetita
Italian
Goethite
Portuguese
goethita · Goethite
Japanese
ゲーサイト · ゲータイト · 針鉄鉱
Chinese
针铁矿
Simplified Chinese
针铁矿
Traditional Chinese
針鐵礦
Russian
гётит
Arabic
غوتيت
Hindi
गोएथाइट

Classification

Strunz
10th ed.

4.00

  • 4OxidesClass
  • 4.0— unnamed intermediate level —Division
  • 4.00— unnamed intermediate level —Group
  • 4.00GoethiteSpecies
Dana
8th ed.

06.01.01.02

  • 06Hydroxides and Oxides Containing HydroxylClass
  • 06.01XO(OH)Type
  • 06.01.01Diaspore group (Orthorhombic, Pnma or Pnmd)Group
  • 06.01.01.02GoethiteSpecies
CIM

7.20.5

  • 7Oxides and HydroxidesClass
  • 7.20Oxides of FeGroup
  • 7.20.5GoethiteSpecies

Group, growth & confusion

In the same group
5 members
Commonly confused with
3 minerals

Literature, links & citation

Citations
  1. 1806Lenz, J.G. (1806) Göthit. In: Tabellen über das gesammte Mineralreich. Göpferdts, Jena, 46-46.
  2. 1903Cesàro, G., Abraham, A. (1903) La goethite. Bulletin de l'Académie royale de Belgique, Classe des Sciences, 2, 179.
  3. 1919Posnjak, E., Merwin, H.E. (1919) The hydrated ferric oxides. American Journal of Science: 47: 311-348.
  4. 1919Spencer, L. J. (1919) Mineralogical characters of Turite ( = turgite) and some other iron-ores from Nova Scotia. Mineralogical Magazine and Journal of the Mineralogical Society, 18 (86) 339-348 doi:10.1180/minmag.1919.018.86.05 DOI: 10.1180/minmag.1919.018.86.05
  5. 1935Goldzstaub (1935) Bulletin soc. min., 58, 6.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Goethite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/goethite-1719},
  note      = {Accessed 2026-05-11}
}