Haycockite

Cu4Fe5S8
IMA status
  • Approved
IMA symbol
Hyc
Discovered
1971
IMA approved
1971
Also known as
  • Haycockiet
  • IMA1971-028

Where it forms, where it's found

Geological setting

Sulfide-poor hortonolite dunite

Type locality
Mooihoek Farm 255 KT
  1. Fetakgomo Tubatse Local Municipality
  2. Sekhukhune District Municipality
  3. Limpopo
  4. South Africa

-24.5579°, 30.1440°

16recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Brass yellow

Does not easily tarnish

Streak
Black
Density
4.33 g/cm³

Optical

Optical colour
Brass-yellow, Similar to chalcopyrite
Anisotropism
Weak to moderate
Tropism
Anisotropic
Reflectance R%
(13.9,13.5) 400, (18.3,19.4) 440, (25.1,26.8) 480, (31.0,32.5) 520, (35.1,36.1) 560, (37.8,38.3) 600, (39.2,39.4) 640, (39.8,39.7) 680, (40.0,39.8) 700
Reflected-light panel
31.1 %anisotropic · dual curve
Specimen sRGB 223, 144, 52
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Weak to moderate
Reflected colour
Brass-yellow, Similar to chalcopyrite

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 10.705(5) Å · b = 10.734(5) Å · c = 31.630(15) Å
Ratio a:b:c
1 : 1.003 : 2.955
Z
12
Morphology

Grains to 500 microns

Twinning

On (103) polysynthetic

Type-locality form

Massive, to 0.5 mm.

Comment

Space Group: P222, P2221, P21212, or P212121.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
26FeIronIron555.845279.225
35.35%
16SSulfurSulfur832.060256.480
32.47%
29CuCopperCopper463.546254.184
32.18%
Total789.889100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ni

Synonyms

  • Haycockiet
  • IMA1971-028

In other languages

German
Haycockit
Italian
Haycockite

Classification

Strunz
10th ed.

2.CB.10b

  • 2Sulfides and SulfosaltsClass
  • 2.CMetal Sulfides, M: S = 1: 1 (and similar)Division
  • 2.CBWith Zn, Fe, Cu, Ag, etc.Group
  • 2.CB.10bHaycockiteSpecies
Dana
8th ed.

02.09.08.02

  • 02SulfidesClass
  • 02.09AmBnXp, with (m+n):p = 1:1Type
  • 02.09.08Talnakhite GroupGroup
  • 02.09.08.02HaycockiteSpecies
CIM

3.1.27

  • 3Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)Class
  • 3.1Sulphides etc. of CuGroup
  • 3.1.27HaycockiteSpecies

Group, growth & confusion

In the same group
3 members
Often grow together
6 minerals

Literature, links & citation

Citations
  1. 1972Cabri, Louis J., Hall, Sydney R. (1972) Mooihoekite and haycockite, two new copper-iron sulfides, and their relationship to chalcopyrite and talnakhite. American Mineralogist, 57 (5-6) 689-708
  2. 1973Rowland, J.F., Hall, S.R. (1973) The crystal structure of haycockite, Cu4Fe5S8. American Mineralogist: 58, 1110 abst.
  3. 1975Rowland, J. F., Hall, S. R. (1975) Haycockite, Cu4Fe5S8: a superstructure in the chalcopyrite series. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 31 (8) 2105-2112 doi:10.1107/s0567740875006929DOI: 10.1107/s0567740875006929
  4. 1995Vaughan, D. J., England, K. E. R., Kelsall, G. H., Yin, Q. (1995) Electrochemical oxidation of chalcopyrite (CuFeS2) and the related metal-enriched derivatives Cu4Fe5S8, Cu9Fe9S16, and Cu9Fe8S16. American Mineralogist, 80 (7-8). 725-731 doi:10.2138/am-1995-7-809 DOI: 10.2138/am-1995-7-809
  5. 1997Daltry, V. D. C. (1997) Mineralogy of South Africa: Type-Mineral Species and Type-Mineral Names. Handbook 15. Geological Survey of South Africa
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Haycockite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/haycockite-1837},
  note      = {Accessed 2026-05-11}
}