Holdenite

Mn2+6Zn3(AsO4)2(SiO4)(OH)8
IMA status
  • Approved
  • Grandfathered
IMA symbol
Hde
Discovered
1921
Also known as
  • Holdeniet

Where it forms, where it's found

Geological setting

In a veinlet coursing through massive zinc ore in a metamorphosed sedimentary Pre-cambrian Zn-Fe-Mn ore body.

Pre-Cambrian marble-hosted zinc deposit

Type locality
Franklin
  1. Sussex County
  2. New Jersey
  3. USA

41.1219°, -74.5808°

3recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Pink · yellowish red · deep red · pink in transmitted light
Streak
White
Cleavage
Poor/Indistinct

On (010), poor.

Fracture
Sub-Conchoidal
Density
4.11 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 30° · 2V calc = 30°
Refractive index
1.769 – 1.785
Surface relief
High
Principal indices
nα 1.769 · nβ 1.770 · nγ 1.785
Birefringence
0.016
Pleochroism
Non-pleochroic
Dispersion
r > v distinct
Extinction
Parallel. XYZ = cba
UV response
Not fluorescent in UV. Fluorescent material may be fluorite which can superficially resemble holdenite.
Michel-Lévy diagramhighlighted lineδ = 0.0160
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]160 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation160 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#47
Cell parameters
a = 11.99 Å · b = 31.46 Å · c = 8.69 Å
Ratio a:b:c
1 : 2.624 : 0.725
Z
8
Morphology

Crystals equant to thick tabular (100), with α and u relatively large.

Type-locality form

Small crystals and small masses.

Comment

Cell chosen is Abma

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
25MnManganeseManganese654.938329.628
31.95%
8OOxygenOxygen2015.999319.980
31.02%
30ZnZincZinc365.380196.140
19.01%
33AsArsenicArsenic274.922149.844
14.52%
14SiSiliconSilicon128.08528.085
2.72%
1HHydrogenHydrogen81.0088.064
0.78%
Total1031.741100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Holdeniet

In other languages

German
Holdenit
Italian
Holdenite
Chinese
红砷锌锰矿

Classification

Strunz
10th ed.

8.BE.55

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BEWith only medium-sized cations, (OH, etc.):RO4 > 2:1Group
  • 8.BE.55HoldeniteSpecies
Dana
8th ed.

43.04.07.01

  • 43Compound Phosphates, Etc.Class
  • 43.04Anhydrous Compound Phosphates, etc·, Containing Hydroxyl or HalogenType
  • 43.04.07— unnamed intermediate level —Group
  • 43.04.07.01HoldeniteSpecies
CIM

20.3.15

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.3Arsenates of Zn, Cd or HgGroup
  • 20.3.15HoldeniteSpecies

Group, growth & confusion

Often grow together
5 minerals

Literature, links & citation

Citations
  1. 1921(1921) First annual meeting of the Mineralogical Society of America. American Mineralogist, 6 (2) 35-45
  2. 1927Palache, Charles, Shannon, E. V. (1927) Holdenite, a new arsenate of manganese and zinc, from Franklin, New Jersey. American Mineralogist, 12 (4) 144-148
  3. 1949Prewitt-Hopkins, Joan (1949) X-ray study of holdenite, mooreite and torreyite. American Mineralogist, 34 (7-8) 589-595
  4. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  5. 1977Moore, Paul B., Araki, Takaharu (1977) Holdenite, a novel cubic close-packed structure. American Mineralogist, 62 (5-6) 513-521
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Holdenite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/holdenite-1920},
  note      = {Accessed 2026-05-11}
}