Kainite

KMg(SO4)Cl · 2.75H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Kai
Discovered
1865
Also known as

Where it forms, where it's found

Geological setting

Potash deposit of oceanic origin.

Type locality
Friedrichshall potash mine
  1. Staßfurt
  2. Salzlandkreis
  3. Saxony-Anhalt
  4. Germany

51.8406°, 11.6069°

57recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colourless · yellow · brownish · greyish-green · red · violet · blue · colourless in transmitted light.

Tints due to included matter. Violet-coloured material is decolourized at 150°C. H2S identified in blue material (Leonhardt and Kühn).

Streak
White
Tenacity
brittle
Cleavage
Perfect

(001), perfect.

Fracture
Splintery
Density
2.15 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 90° · 2V calc = 88°
Refractive index
1.494 – 1.516
Surface relief
Moderate
Principal indices
nα 1.494 · nβ 1.505 · nγ 1.516
Pleochroism
Visible

X = Violet Y = Blue Z = Yellowish Observed on blue or violet material only.

Dispersion
weak
Extinction
X = a; Y = b; Z ∧ c = 13°.
Michel-Lévy diagramhighlighted lineδ = 0.0220
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]220 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation220 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 19.6742(2) Å · b = 16.18240(10) Å · c = 9.49140(10) Å
Cell angles
β = 94.8840(10) °
Ratio a:b:c
1 : 0.823 : 0.482
Unit cell volume
3010.86 ų
Z
16
Morphology

Crystals thick tabular (100) to equidimensional; often exhibiting numerous forms. Occurs as crystalline coatings and clusters in cavities or fissures in which single crystals may reach several centimeters; granular massive.

Comment

Borisov et al. (2022).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen6.7515.999107.993
44.18%
19KPotassiumPotassium139.09839.098
15.99%
17ClChlorineChlorine135.45035.450
14.50%
16SSulfurSulfur132.06032.060
13.12%
12MgMagnesiumMagnesium124.30524.305
9.94%
1HHydrogenHydrogen5.51.0085.544
2.27%
Total244.450100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Caenit
  • Caenita
  • Caenite
  • Cainit
  • Cainite
  • Cenit
  • Cenita
  • Cenite

In other languages

French
kaïnite
German
Kainit
Spanish
Kainita
Italian
Kainite
Portuguese
cainita · Cainite · Kainita · Kainite
Japanese
カイナイト · カリナイト
Chinese
鉀瀉鹽 · 鉀鎂礬 · 钾盐镁矾
Russian
каинит
Arabic
كاينيت

Classification

Strunz
10th ed.

7.DF.10

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DFWith large and medium-sized cationsGroup
  • 7.DF.10KainiteSpecies
Dana
8th ed.

31.07.01.01

  • 31Hydrated Sulfates Containing Hydroxyl or HalogenClass
  • 31.07(AB)2(XO4)Zq·xH2OType
  • 31.07.01— unnamed intermediate level —Group
  • 31.07.01.01KainiteSpecies
CIM

26.14

  • 26Sulphates with HalideClass
  • 26.14— unnamed intermediate level —Group
  • 26.14KainiteSpecies

Group, growth & confusion

Often grow together
6 minerals

Literature, links & citation

Citations
  1. 1865Zincken, C. (1865): Mittheilung an Prof. H.B. Geinitz vom 18.März 1865 [Über ein neues Mineral, Kainit].- Neues Jahrbuch für Mineralogie, Geologie und Paläontologie, 310.
  2. 1865Zincken, C. (1865): Ueber die Zusammensetzung des Kainits von Leopoldshall bei Stassfurth.- Berg- und hüttenmännische Zeitung 24, 288.
  3. 1869Groth, P. (1869) Ueber den krystallisirten Kainit von Stassfurth. Annalen der Physik, Halle, Leipzig: 213(7): 442-447.
  4. 1882Zepharovich, V. von (1882) Ueber Kainit, Rutil und Anatas. Zeitschrift für Krystallographie, Mineralogie und Petrographie, 6 (1-6). 234-243 doi:10.1524/zkri.1882.6.1.234DOI: 10.1524/zkri.1882.6.1.234
  5. 1889Bücking, H. (1889) Mittheilungen aus dem mineralogischen Institut der Universität Strassburg. 13.: Glaserit, Blödit, Kainit und Boracit von Donglashall bei Westeregeln. Zeitschrift für Kristallographie - Crystalline Materials, 15(1-6), 561-575 (569).
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Kainite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/kainite-2132},
  note      = {Accessed 2026-05-11}
}