Sylvite

KCl
IMA status
  • Approved
  • Grandfathered
IMA symbol
Syl
Discovered
1832
Also known as
  • Chloride of Potassium
  • Chlorkalium
  • Hoevelit
  • +17 more

Where it forms, where it's found

Geological setting

Evaporite deposit

Evaporites in sedimentary basins, sublimate in volcanic fumaroles, burning coal.

Type locality
Mount Vesuvius
  1. Metropolitan City of Naples
  2. Campania
  3. Italy
281recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101.5 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent · Translucent
Colour
Colourless · grey · white · yellowish to reddish · seldom blue or violet
Streak
White
Tenacity
brittle
Cleavage
Perfect

On (001)

Fracture
Irregular/Uneven
Density
1.993 g/cm³

Optical

Optical type
Isotropic
Surface relief
Low
Principal indices
n 1.4903
Pleochroism
Visible

Distinct pleochroism observed in colored crystals with weak anomalous birefringence (especially noted in mechanically deformed crystals).

Tropism
Isotropic
Notes

Anomalously anisotropic when strained.

Isotropy testPPL ↔ XPL diagnostic
PPL intrinsic colour; no change on stage rotation
XPL extinct at every orientation
Single index
n = 1.490

Crystallography

Crystal system
Isometric
Space group
#224
Cell parameters
a = 6.2931 Å
Z
4
Morphology

Crystals cubic; cubooctahedral or octahedral habits less common. Massive, coarsely granular to compact. Columnar structure rare; as crusts.

Twinning

On (111) (artificial crystals only).

Epitaxy

Hematite inclusions with (0001) of hematite parallel to (001), (111), or (011) of halite. Minute halite inclusions oriented in parallel position to the sylvite.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
19KPotassiumPotassium139.09839.098
52.45%
17ClChlorineChlorine135.45035.450
47.55%
Total74.548100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Br
  • CO2=C
  • O

Synonyms

  • Chloride of Potassium
  • Chlorkalium
  • Hoevelit
  • Hoevelita
  • Hoevelite
  • Hövelita
  • Hövelite
  • Hövellit
  • Leopoldit
  • Leopoldita
  • Leopoldite
  • Muriate of Potash
  • Potassium Chloride
  • Sal digestivus sylvii
  • Schätzelit
  • Schätzelita
  • Schätzelite
  • Sylviit
  • Sylvita
  • Sylvyne

In other languages

French
Hoevelite · Léopoldite · Sylvine · Sylvite
German
Syl · Sylvin
Spanish
silvina
Italian
Silvite · Sylvite
Portuguese
Silvina · silvita · Silvite
Japanese
カリ岩塩
Chinese
钾石盐
Traditional Chinese
鉀石鹽
Russian
сильвин
Arabic
سيلفيت

Classification

Strunz
10th ed.

3.AA.20

  • 3HalidesClass
  • 3.ASimple halides, without H2ODivision
  • 3.AAM:X = 1:1, 2:3, 3:5, etc.Group
  • 3.AA.20SylviteSpecies
Dana
8th ed.

09.01.01.02

  • 09Normal HalidesClass
  • 09.01AXType
  • 09.01.01Halite GroupGroup
  • 09.01.01.02SylviteSpecies
CIM

8.1.6

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.1Halides of the alkali metals and ammoniumGroup
  • 8.1.6SylviteSpecies

Group, growth & confusion

In the same group
4 members

Literature, links & citation

Citations
  1. 1823Smithson, J. (1823) A discovery of chloride of potassium in the Earth. The Annals of Philosophy: 6: 258-259.
  2. 1830Beudant, François-Sulpice (1830) Traité élémentaire de minéralogie. Deuxiéme Edition [Elementary Treatise on Mineralogy. Second Edition] (2nd ed.) Vol. 1 - Tome Premier [Volume One]. Chez Verdière.
  3. 1865Bischoff (1865) Berg.- und hüttenmännisches Zeitung, Freiberg, Leipzig: 24: 276.
  4. 1865Bischoff (1865) Ann. Chem. Phys.: 5: 318.
  5. 1865Zinken (1865) Berg.- und hüttenmännisches Zeitung, Freiberg, Leipzig: 24: 79.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Sylvite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/sylvite-3850},
  note      = {Accessed 2026-05-11}
}