Legrandite

Zn2(AsO4)(OH) · H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Leg
Discovered
1932

Where it forms, where it's found

Geological setting

Oxidized zone of an arsenic-bearing zinc deposit.

Rare secondary mineral in Zn-As bearing deposits, granite pegmatites (rare).

Type locality
Flor de Peña Mine
  1. Lampazos de Naranjo (Lampazos)
  2. Lampazos de Naranjo Municipality
  3. Nuevo León
  4. Mexico
15recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent · Translucent
Colour
Yellow to colourless · pale yellow to colourless in transmitted light.
Streak
White
Tenacity
brittle
Cleavage
Imperfect/Fair

Fair to poor on (100)

Fracture
Irregular/Uneven
Density
3.98 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 50° · 2V calc = 52 – 62°
Refractive index
1.675 – 1.74
Surface relief
High
Principal indices
nα 1.675 – 1.702 · nβ 1.69 – 1.709 · nγ 1.735 – 1.74
Birefringence
0.66
Pleochroism
Visible

X = Y = Colourless to yellow Z = Yellow

Dispersion
r < v strong
Extinction
X = b; Z ^ c = 40°
UV response
No fluorescent in UV
Michel-Lévy diagramhighlighted lineδ = 0.6600
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]6600 nmhigh order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation6600 nm
Orderhigh order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 12.805(2) Å · b = 7.933(1) Å · c = 10.215(2) Å
Cell angles
β = 104.23 °
Ratio a:b:c
1 : 0.620 : 0.798
Z
8
Morphology

Crystals prismatic elongated [001], exhibiting dominant (110), striated parallel to (001) and (111), (100), and (001). Commonly in sprays or sheaflike aggregates.

Type-locality form

Massive radiating-prismatic and rare freely developed crystals.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
30ZnZincZinc265.380130.760
42.91%
8OOxygenOxygen615.99995.994
31.51%
33AsArsenicArsenic174.92274.922
24.59%
1HHydrogenHydrogen31.0083.024
0.99%
Total304.700100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

In other languages

French
Legrandite
German
Legrandit
Spanish
Legrandita
Italian
Legrandite
Japanese
レグランド · レグランド石

Classification

Strunz
10th ed.

8.DC.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DCWith only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1Group
  • 8.DC.10LegranditeSpecies
Dana
8th ed.

42.06.04.01

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.06A2(XO4)Zq·xH2OType
  • 42.06.04Strashimirite GroupGroup
  • 42.06.04.01LegranditeSpecies
CIM

20.3.4

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.3Arsenates of Zn, Cd or HgGroup
  • 20.3.4LegranditeSpecies

Group, growth & confusion

Often grow together
4 minerals

Literature, links & citation

Citations
  1. 1932Drugman, Julien, Hey, Max H. (1932) Legrandite, a new zinc arsenate. Mineralogical Magazine and Journal of the Mineralogical Society, 23 (138) 175-178 doi:10.1180/minmag.1932.023.138.03 DOI: 10.1180/minmag.1932.023.138.03
  2. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  3. 1963Finney, J. J. (1963) The composition and space group of legrandite. American Mineralogist, 48 (11-12) 1255-1257
  4. 1963Desautels, Paul E., Clarke, Roy S. (1963) Re-examination of legrandite. American Mineralogist, 48 (11-12) 1258-1265
  5. 1971McLean, W. John, Anthony, John W., Finney, Joseph J., Laughon, and Robert B. (1971) The crystal structure of legrandite. American Mineralogist, 56 (5-6) 1147-1154
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Legrandite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/legrandite-2365},
  note      = {Accessed 2026-05-11}
}