Smithsonite

Zn(CO3)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Smt
Discovered
1832
Also known as
  • Aztec Stone
  • Azurite (of ?)
  • Bonamite
  • +16 more

History

The name smithsonite honours James Smithson — the English chemist whose bequest founded the Smithsonian Institution in Washington, DC. The connection is direct: Smithson was the mineralogist who, in the early 1800s, first picked apart what calamine really was.

For centuries, calamine meant a confused mixture. Georgius Agricola used the Latin form lapis calaminaris in 1546. The Swedish chemist Johan Gottschalk Wallerius shortened it to calamine in 1747, applying it to the zinc carbonate. In 1780, his countryman Torbern Bergmann analysed several calamine ores and found they were not one mineral but a mix of zinc carbonates and silicates.

In 1803, Smithson took the work further. His systematic investigation showed that ores sold as calamine contained two distinct species — one a carbonate, the other a silicate. The silicate kept the old commercial name for a while; today it is called hemimorphite. The carbonate needed a new name.

François Sulpice Beudant supplied it. In 1832, the French mineralogist renamed the carbonate smithsonite in honour of Smithson, who had died three years earlier.

Through the nineteenth century, smithsonite was the principal ore of zinc. Smelters worked it directly, roasting the carbonate to drive off carbon dioxide and reduce the oxide that remained. From the 1880s onward, it was displaced by sphalerite — the zinc sulfide — once a new ore-dressing technique made sulfide minerals easier to concentrate.

Industrial & practical applications

Smithsonite is still classed as an ore of zinc, but it is no longer the chief source. The dominant zinc ore today is sphalerite — the sulfide. Smithsonite contributes only where oxide-type zinc deposits are worked directly, mostly through non-sulfide operations and the rare older mine that still produces.

Most modern demand for smithsonite is from collectors and museums. The mineral forms striking botryoidal masses — rounded, grape-like crusts — in a range of colours that few other species match. The apple-green variety, called cuprian smithsonite, takes its colour from copper held in the crystal. Pink crystals are cobaltoan smithsonite, coloured by trace cobalt. A bright yellow variety, known to miners as turkey fat ore, gets its tint from inclusions of greenockite — a cadmium sulfide — within the smithsonite. Notable specimen localities include the Kelly Mine in New Mexico, in the United States; Tsumeb in Namibia; the Ojuela Mine at Mapimí, in Durango, Mexico; and the Lavrion District in Greece.

Where it forms, where it's found

Geological setting

Oxidised zones of zinc ore deposits.

2,492recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789104 – 4.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous to Pearly
Transparency
Translucent
Colour
White · grey · yellow · green to apple-green · blue · pink · purple · bluish grey · and brown · colourless or faintly tinted in transmitted light.

Trace elements can be the direct cause of colour. Iron and manganese are enriched in orange-yellow smithsonites. The Cd2+ ion itself is not the cause of colour; only the presence of greenockite inclusions is related to “turkey fat” yellow in smithsonite. Manganese substitution of zinc is limited and changes the colour of smithsonite to pink. Only blue and cyan (blue-green) smithsonite samples contain weak Raman peaks at around 1200 cm−1 and Cu2+ concentrations higher than the detection limit of the test. The blue and cyan (blue-green) colours are both due to the (CO3)− radicals, nano-sized inclusions formed by Cu2+ ions, and aurichalcite inclusions (or aurichalcite–hemimorphite layers). As for the cyan smithsonite, the aurichalcite–hemimorphite layers are the major factor affecting colour. Ding et al (2023)

Streak
White
Tenacity
brittle
Cleavage
Very Good

On (1011).

Fracture
Irregular/Uneven · Sub-Conchoidal
Density
4.42 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.619 – 1.85
Surface relief
High
Principal indices
nω 1.842 – 1.85 · nε 1.619 – 1.623
UV response
May fluoresce pale green or pale blue.
Michel-Lévy diagramhighlighted lineδ = 0.2250
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]2250 nm5th order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation2250 nm
Order5th order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#98
Cell parameters
a = 4.6526(7) Å · c = 15.0257(22) Å
Morphology

Crystals rhombohedral (1011); less commonly (0221). Crystal faces usually curved and rough or composite; rarely scalenohedral. Botryoidal, reniform, or stalactic; incrustations; coarsely granular to compact massive; earthy, friable.

Twinning

None observed.

Translation gliding
Translation gliding with T(0001), t(1010).
Epitaxy

Smithsonite upon calcite with parallel axes. Oriented pseudomorphs of ZnO are formed by thermal dissociation. Otavite oriented growths on Smithsonite (Tsumeb).

Comment

Cell parameters are similar to those of magnesite.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
30ZnZincZinc165.38065.380
52.14%
8OOxygenOxygen315.99947.997
38.28%
6CCarbonCarbon112.01112.011
9.58%
Total125.388100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Co
  • Cu
  • Mn
  • Ca
  • Cd
  • Mg
  • In

Synonyms

  • Aztec Stone
  • Azurite (of ?)
  • Bonamite
  • Cadmium-bearing Smithsonite
  • Cadmiumzinkspat
  • Capnit
  • Carbonate of Zinc
  • Cobaltian Smithsonite
  • Cuprian Smithsonite
  • Kapnit
  • Kohlengalmei
  • Smithsonite (of Beudant)
  • Szaskaite
  • Zinc carbonaté
  • Zinc Spar
  • Zincspath
  • Zincum acido aëro mineralisatum
  • Zinkischer Carbonspat
  • Zinkspath

In other languages

French
14476-25-6 · 3486-35-9 · bonamite · cadmiosmithsonite · cobaltosmithsonite · cuprosmithsonite · herrerite · monheimite · smithsonite · zinc carbonaté · ZnCO3
German
Capnit · Edelgalmei · Edler Galmei · Galmei · Kapnit · Kohlengalmei · Smithsonit · Zinkspat
Spanish
esmitsonita · espato de cinc · espato de zinc · smithsonita
Italian
Smithsonite
Portuguese
smithsonita · Smithsonite
Japanese
スミソナイト · 菱亜鉛鉱
Chinese
菱锌矿
Simplified Chinese
菱锌矿
Traditional Chinese
菱鋅礦
Russian
Бонамит · Монхеймит · Смитсонит · Смифсонит · Херрерит · Цинковый шпат
Arabic
السميثونايت · سميثسونيت

Classification

Strunz
10th ed.

5.AB.05

  • 5CarbonatesClass
  • 5.ACarbonates without additional anions, without H2ODivision
  • 5.ABAlkali-earth (and other M2+) carbonatesGroup
  • 5.AB.05SmithsoniteSpecies
Dana
8th ed.

14.01.01.06

  • 14Anhydrous Normal CarbonatesClass
  • 14.01A(XO3)Type
  • 14.01.01Calcite Group (Trigonal: R-3c)Group
  • 14.01.01.06SmithsoniteSpecies
CIM

11.6.1

  • 11CarbonatesClass
  • 11.6Carbonates of Zn and CdGroup
  • 11.6.1SmithsoniteSpecies

Group, growth & confusion

In the same group
7 members

Literature, links & citation

Citations
  1. 1780Bergmann, T. (1780) Opuscula of Tobernus Bergmann: 209.
  2. 1783Bergman, Torbern (1783) Sciagraphia Regni Mineralis Secundum Principia Proxima Digesti [Sketch of the Mineral Kingdom According to the Proximate Principles of Digestion]. Apud Johannem Murray, Londini. 165pp.
  3. 1827Brongniart, A. (1827) 47 (as Zinc carbonaté).
  4. 1832Beudant, François-Sulpice (1832) Traité élémentaire de minéralogie. Deuxiéme Edition [Elementary Treatise on Mineralogy. Second Edition] (2nd ed.) Vol. 2 - Tome II [Volume II]. Chez Verdière.
  5. 1837Dana, James D. (1837) A System of Mineralogy (1st ed.)
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Smithsonite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/smithsonite-3688},
  note      = {Accessed 2026-05-11}
}