Adamite

Zn2(AsO4)(OH)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Ad
Discovered
1866
Also known as
  • Adamine
  • Adamite (of Friedel)
  • Adamitt

History

Adamite carries the name of a man who never described a mineral himself. Gilbert-Joseph Adam was a wealthy French collector and Inspector of Finance for the French government. He supplied the first specimens of a new zinc arsenate to the chemist Charles Friedel. Friedel did the analysis and, in 1866, named the mineral after him.

The specimens came from Chañarcillo, in the Copiapó Province of Chile's Atacama region. Chañarcillo remains the type locality of the species.

Adam was not a one-mineral patron. Specimens from his cabinet led to the formal description of aerugite, chenevixite, corkite, cuprotungstite, scacchite, and xanthiosite. His collection was catalogued in Annales des Mines in 1869. At his death in 1881 it was acquired by the École des Mines in Paris. He was made Commandeur de la Légion d'Honneur and was a member of the Société géologique de France.

Industrial & practical applications

Adamite has no industrial use. The world's zinc comes from sphalerite and a handful of other sulfides. Adamite forms only in the oxidised, weathered top layer of those deposits, never in enough quantity to mine. Its arsenic content would disqualify it as ore in any case. Its demand is entirely from collectors and museums.

What collectors pay for is colour and fluorescence. Most adamite is pale yellow to honey-yellow. Copper substitution produces vivid green to turquoise crystals — the cuprian variety. The manganese-bearing variety from the Ojuela mine at Mapimí, Durango, glows lemon-yellow under short-wave and long-wave ultraviolet light. The Ojuela material is the reference for the species: "Ojuela adamite and legrandite have set the standard for these species".

Mineralogically, adamite remains useful as a study mineral. It forms a continuous series with olivenite — the copper analogue, Cu₂(AsO₄)(OH) — through an intermediate called cuproadamite. The series is a textbook example of one metal swapping in for another inside the same crystal framework: zinc and copper exchange freely in the structure. The manganese end-member of the same group is the rare mineral eveite, Mn₂(AsO₄)(OH).

Where it forms, where it's found

Geological setting

A secondary mineral in the oxidised zone of zinc- and arsenic-bearing hydrothermal mineral deposits.

Type locality
Chañarcillo Mining District
  1. Copiapó
  2. Copiapó Province
  3. Atacama
  4. Chile
258recorded occurrences
Source · OpenStreetMap

Varieties

Safety & handling

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent · Translucent
Colour
Ideally white · colourless · frequently pale yellow · honey-yellow · brownish yellow · rose red · blue · pale green to green · may be zoned · bright green (Cu-bearing) · bright pink · purple (Co-bearing)

Colourless or faintly tinted in transmitted light.

Streak
white
Tenacity
very brittle
Cleavage
Distinct/Good

on (101), good; on (010), poor.

Fracture
Irregular/Uneven · Conchoidal
Density
4.32 g/cm³

Optical

Optical type
Biaxial (+/-) · 2V measured = 78 – 90° · 2V calc = 74 – 84°
Refractive index
1.708 – 1.773
Surface relief
High
Principal indices
nα 1.708 – 1.722 · nβ 1.742 – 1.744 · nγ 1.763 – 1.773
Birefringence
0.05
Pleochroism
Weak

In pale colours if cuprian or cobaltian.

Dispersion
strong r > v or r < v
Extinction
X = a; Y = c; Z = b.
Luminescence
None?
UV response
May fluoresce or phosphoresce lemon-yellow under SW and LW UV.
Michel-Lévy diagramhighlighted lineδ = 0.0500
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]500 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation500 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
Pnnm
Cell parameters
a = 8.304 Å · b = 8.524 Å · c = 6.036 Å
Ratio a:b:c
1 : 1.026 : 0.727
Z
4
Morphology

Crystals of variable morphology. Often elongated [010], also elongated [001], rarely elongated [100]. Tabular at times (101) or equant. Commonly forms radial aggregates, fanlike rosettes or crystalline crusts.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
30ZnZincZinc265.380130.760
45.61%
8OOxygenOxygen515.99979.995
27.90%
33AsArsenicArsenic174.92274.922
26.14%
1HHydrogenHydrogen11.0081.008
0.35%
Total286.685100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Cu
  • Fe
  • Co

Synonyms

  • Adamine
  • Adamite (of Friedel)
  • Adamitt

In other languages

French
adamite · Cobaltoadamite · Cuproadamite · Manganoadamite
German
Adamin · Adamit · Cuproadamin
Spanish
adamina · adamita
Italian
Adamina · adamite
Portuguese
adamite
Japanese
アダマイト · アダム石 · アダム鉱 · 水砒亜鉛鉱
Chinese
水砷锌矿 · 羟砷锌石 · 羥砷鋅石
Simplified Chinese
水砷锌矿
Traditional Chinese
水砷鋅礦
Russian
Адамин
Arabic
أداميت

Classification

Strunz
10th ed.

8.BB.30

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BBWith only medium-sized cations, (OH, etc.):RO4 about 1:1Group
  • 8.BB.30AdamiteSpecies
Dana
8th ed.

41.06.06.03

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.06A2(XO4)ZqType
  • 41.06.06Olivenite GroupGroup
  • 41.06.06.03AdamiteSpecies
CIM

20.3.1

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.3Arsenates of Zn, Cd or HgGroup
  • 20.3.1AdamiteSpecies

Group, growth & confusion

In the same group
6 members
Commonly confused with
3 minerals

Literature, links & citation

Citations
  1. 1866Friedel, C., Daubrée, G.A. (1866) Sur l‘adamine, nouvelle espèce minérale. Comptes Rendus Hebdomadaires des Séances de l’Académie des Sciences 62, 692-695. [as Adamine]
  2. 1868Dana, James D., Brush, George Jarvis (1868) A System of Mineralogy (5th ed.). p.882
  3. 1868Damour (1868) Comptes rendus de l’Académie des sciences de Paris: 67: 1124.
  4. 1870Pisani, F. (1870) Sur les minéraux trouvés dans la mine de cuivre du Cap Garonne (Var). Comptes rendus hebdomadaires des séances de l'Académie des sciences, 70, 1001-1005.
  5. 1878Des Cloizeaux, A. (1878) Présentation de minéraux : Nouémite [nouméite], Adamine, Vietinghofite [samarskite]. Bulletin de la Société française de Minéralogie: 1: 28-32.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Adamite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/adamite-21},
  note      = {Accessed 2026-05-11}
}