Liebigite

Ca2(UO2)(CO3)3 · 11H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Lbi
Discovered
1848
Also known as
  • Flutherit
  • Flutherita
  • Flutherite
  • +9 more

Where it forms, where it's found

Geological setting

Secondary mineral formed by alkteration of uraninite in alkaline carbonate solutions.

Type locality
Edirne
  1. Edirne Province
  2. Turkey

41.6667°, 26.5667°

80recorded occurrences
Source · OpenStreetMap

Radioactivity

Physical

Hardness
123456789102.5 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent · Translucent
Colour
Apple-green · siskin-green · yellowish green
Cleavage
Imperfect/Fair

On (100).

Density
2.41 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 37 – 42°
Refractive index
1.494 – 1.542
Surface relief
Moderate
Principal indices
nα 1.494 – 1.501 · nβ 1.498 – 1.505 · nγ 1.535 – 1.542
Pleochroism
Visible

X = Nearly colourless Y = Light yellowish green Z = Light yellowish green

Dispersion
moderate r > v
UV response
Green to blue green fluorescence (LW & SWUV).
Michel-Lévy diagramhighlighted lineδ = 0.0410
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]410 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation410 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 16.699(3) Å · b = 17.557(3) Å · c = 13.697(2) Å
Ratio a:b:c
1 : 1.051 : 0.820
Z
8
Morphology

Crystals equant or short prismatic [001], normally indistinct with rounded edges and convex or vicinal faces. Commonly granular or scaly aggregates and thin crusts; botryoidal.

Type-locality form

Mammillary concretion.

Comment

Space Group: Bba2.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2215.999351.978
48.32%
92UUraniumUranium1238.029238.029
32.68%
20CaCalciumCalcium240.07880.156
11.01%
6CCarbonCarbon312.01136.033
4.95%
1HHydrogenHydrogen221.00822.176
3.04%
Total728.372100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Flutherit
  • Flutherita
  • Flutherite
  • Hebergit
  • Hebergita
  • Hebergite
  • Kalk-Uran-carbonate
  • Liebigiet
  • Medjidite
  • Uranotalita
  • Uranothallit
  • Uranothallite

In other languages

French
Liebigite
German
Flutherit · Hebergit · Kalkurancarbonat · Liebigit · Uranothallit
Spanish
Liebigita
Italian
liebigite

Classification

Strunz
10th ed.

5.ED.20

  • 5CarbonatesClass
  • 5.EUranyl CarbonatesDivision
  • 5.EDUO2:CO3 = 1:3Group
  • 5.ED.20LiebigiteSpecies
Dana
8th ed.

15.03.02.01

  • 15Hydrated Normal CarbonatesClass
  • 15.03AmBn(XO3)p·xH2O, with (m+n):p = 1:1Type
  • 15.03.02— unnamed intermediate level —Group
  • 15.03.02.01LiebigiteSpecies

Group, growth & confusion

Often grow together
5 minerals

Literature, links & citation

Citations
  1. 1848Smith, J.L. (1848) Two new minerals, - medjidite (sulphate of uranium and lime) - liebigite (carbonate of uranium and lime). American Journal of Science and Arts: 5: 336-338.
  2. 1851Smith, J.L. (1851) American Journal of Science: 11: 259.
  3. 1853Vogl (1853) Jahrbuch Geol. Reichsanst., Vienna: 4: 221 (as Kalk-Uran-carbonate).
  4. 1856Lindacker analysis in: Vogl (1856) Gangverh. Mineralreich. Joachimsthal, Teplitz.
  5. 1875Weisbach, Albin (1875) Synopsis mineralogical, systematische Übersicht des Mineralreiches. 78 pp., Freiberg: 48 (as Flutherite).
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Liebigite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/liebigite-2398},
  note      = {Accessed 2026-05-11}
}