Autunite

Ca(UO2)2(PO4)2 · 10-12H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Aut
Discovered
1852
Also known as
  • Calcium-Autunite
  • Calciumphosphoruranit
  • Calcouranit
  • +7 more

History

Berzelius had glimpsed the mineral in 1819. He listed it tentatively under the uranite entry of his system. The description called it a "salt of calcium in which uranium oxide plays the role of acid".

Autunite got its own name in 1852, when Henry James Brooke and William Hallowes Miller described it. The type locality is at Saint Symphorien, near Autun in Saône-et-Loire, France. The town gave the mineral its name.

Industrial & practical applications

At 48 percent uranium by mass, autunite is a viable but minor ore of the metal — mined commercially where deposits are rich enough. At Mount Kit Carson in Washington State, nine properties together yielded about 90,000 pounds of uranium oxide. Other workable deposits lie in Cornwall, Katanga in the Democratic Republic of the Congo, and the northwestern United States.

Beyond uranium extraction, autunite has a small ornamental market. Its crystals fluoresce bright green to lime green under ultraviolet light, which makes them a collector favourite.

Where it forms, where it's found

Geological setting

Granite pegmatite

In the oxidation zone of uranium-bearing rocks, including sandstones, hydrothermal veins, and granitic pegmatites.

Type locality
Saint-Symphorien-de-Marmagne uranium deposit
  1. Saint-Symphorien-de-Marmagne
  2. Autun
  3. Saône-et-Loire
  4. Bourgogne-Franche-Comté
  5. France

46.8287°, 4.2965°

1,095recorded occurrences
Source · OpenStreetMap

Radioactivity

Physical

Hardness
123456789102 – 2.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Yellow · greenish-yellow · pale green · dark green · greenish black.

Color may become yellower and less greenish with even slight dehydration

Streak
Pale yellow
Tenacity
sectile
Cleavage
Perfect

Perfect on (001), indistinct on (100)

Autunite is fragile and may easily split with low pressure. On cutting, the mineral may appear sectile, waxy, or slightly elastic.

Fracture
Micaceous
Density
3.05 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 10 – 53°
Refractive index
1.553 – 1.578
Surface relief
Moderate
Principal indices
nα 1.553 – 1.555 · nβ 1.575 · nγ 1.577 – 1.578 · nω 1.575 · nε 1.572
Birefringence
0.024 (if biaxial)
Pleochroism
Visible

X = Colourless to pale yellow Y = Z = Yellow to dark yellow

Dispersion
r > v strong
Extinction
Z=c, Y={110}
UV response
Strong yellow-green (LW & SW UV).
Notes

Uniaxial - but commonly anomalously biaxial - dependent on the H2O content of the crystals. 2V decreases with decreasing water content.

Michel-Lévy diagramhighlighted lineδ = 0.0240
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]240 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation240 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#71
Cell parameters
a = 14.0135(6) Å · b = 20.7121(8) Å · c = 6.9959(3) Å
Ratio a:b:c
1 : 1.478 : 0.499
Z
4
Morphology

Crystals thin to thick tabular (001), and with a rectangular or octagonal outline. Subparallel growths common; foliated or scaly aggregates, crusts.

Twinning

Rare interpenetrant twinning on (110).

Epitaxy

Oriented growths on prism. Crystals look concentrically zoned.

Comment

For synthetic material. Pseudotetragonal metrics. Often shown to be holosymmetrical tetragonal. Natural samples may show space-group symmetry I4/mmm, with a = 6.989, c = 20.63 Å.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
92UUraniumUranium2238.029476.058
50.10%
8OOxygenOxygen2215.999351.978
37.04%
15PPhosphorusPhosphorus230.97461.948
6.52%
20CaCalciumCalcium140.07840.078
4.22%
1HHydrogenHydrogen201.00820.160
2.12%
Total950.222100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ba
  • Mg

Synonyms

  • Calcium-Autunite
  • Calciumphosphoruranit
  • Calcouranit
  • Calcouranita
  • Calcouranite
  • Kalk-Uranglimmer
  • Kalk-Uranit
  • Lime-Uranite
  • Ótainít
  • Sel à base de chaux, où l'oxide d'urane joue le rôle d'acide

In other languages

French
autunite · Calcium-Autunite · Calcouranite · Lime-Uranite
German
Autunit · Kalkuranglimmer
Spanish
autunita
Italian
autunite
Portuguese
Autunita · autunite
Japanese
燐灰ウラン石
Chinese
钙铀云母
Russian
отенит
Arabic
أوتونايت · أوتونيت

Classification

Strunz
10th ed.

8.EB.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.EUranyl phosphates and arsenatesDivision
  • 8.EBUO2:RO4 = 1:1Group
  • 8.EB.05AutuniteSpecies
Dana
8th ed.

40.2a.01.01

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.2aAB2(XO4)2·xH2O, containing (UO2)2+Type
  • 40.2a.01— unnamed intermediate level —Group
  • 40.2a.01.01AutuniteSpecies
CIM

19.11.15

  • 19PhosphatesClass
  • 19.11Phosphates of UGroup
  • 19.11.15AutuniteSpecies

Group, growth & confusion

Commonly confused with
3 minerals

Literature, links & citation

Citations
  1. 1819Berzelius, J. J. (1819) Nouveau Système de minéralogie. Méquignon-Marvis.
  2. 1844Berzelius (1844) Annalen der Physik, Halle, Leipzig: 1: 379.
  3. 1852Brooke, Henry J., Phillips, William (1852) An Elementary Introduction to Mineralogy (6th ed.)
  4. 1865Breithaupt (1865) Berg.- und hüttenmännisches Zeitung, Freiberg, Leipzig (merged into Glückauf): 24: 302 (as Calcouranit).
  5. 1875Church, A.H. (1875) On the composition of autunite. Journal of the Chemical Society, London: 28: 109-112.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Autunite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/autunite-433},
  note      = {Accessed 2026-05-11}
}