Marialite

Na4Al3Si9O24Cl
IMA status
  • Approved
  • Grandfathered
IMA symbol
Mar
Discovered
1866
Also known as
  • Marialiet
  • Marialite (of von Roth)
  • Mizzonite

Where it forms, where it's found

Geological setting

Regionally and contact metamorphic rocks, skarns, pegmatites, altered mafic igneous rocks, volcanic ejecta.

Type locality
Pianura
  1. Naples
  2. Metropolitan City of Naples
  3. Campania
  4. Italy

40.8556°, 14.1850°

132recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105.5 – 6/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Colourless · white · bluish · brownish · yellowish · violet · greenish
Streak
White
Tenacity
very brittle
Cleavage
Distinct/Good

Distinct on the (100) and the (110)

Fracture
Irregular/Uneven · Conchoidal
Density
2.5 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.532 – 1.55
Surface relief
Moderate
Principal indices
nω 1.539 – 1.55 · nε 1.532 – 1.541
UV response
Commonly orange to bright yellow or red in SW or LW. Photochromic scapolite has been found in Baffin Island and Afghanistan.
Michel-Lévy diagramhighlighted lineδ = 0.0080
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]80 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation80 nm
Order1st order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
#135
Cell parameters
a = 12.060(3) Å · c = 7.572(3) Å
Z
2
Morphology

Prismatic, granular, massive.

Comment

Teertstra & Sherriff (1996) give a = 12.06(1) and c = 7.551(5) Å for end-member marialite.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2415.999383.976
45.44%
14SiSiliconSilicon928.085252.765
29.91%
11NaSodiumSodium422.99091.960
10.88%
13AlAluminiumAluminium326.98280.946
9.58%
17ClChlorineChlorine135.45035.450
4.19%
Total845.097100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Ca
  • K
  • S

Synonyms

  • Marialiet
  • Marialite (of von Roth)
  • Mizzonite

In other languages

French
Marialite
German
Marialith
Spanish
Marialita
Italian
Marialite
Japanese
マリアライト · マリアル石 · 曹柱石
Chinese
鈉柱石 · 钠柱石

Classification

Strunz
10th ed.

9.FB.15

  • 9SilicatesClass
  • 9.FTektosilicates without zeolitic H2ODivision
  • 9.FBTektosilicates with additional anionsGroup
  • 9.FB.15MarialiteSpecies
Dana
8th ed.

76.03.01.01

  • 76Tectosilicates Al-si FrameworkClass
  • 76.03Al-Si Framework with other Be/Al/Si frameworksType
  • 76.03.01Scapolite groupGroup
  • 76.03.01.01MarialiteSpecies
CIM

17.3.4

  • 17Silicates Containing other AnionsClass
  • 17.3Silicates with chloride (including aluminosilicates)Group
  • 17.3.4MarialiteSpecies

Group, growth & confusion

In the same group
2 members
Often grow together
2 minerals

Literature, links & citation

Citations
  1. Haberlandt, H. and Köhler, A. (1934/1935): Fluoreszenzanalyse von Skapolithen. Chemie der Erde 9, 139-144.
  2. Haberlandt, H. (1949): Neue Luminiszenzuntersuchungen an Fluoriten und anderen Mineralien IV. Sitz.-Ber. österr. Akad. Wiss., math.-naturwiss. Kl. I, 158, 609-646.
  3. 1866vom Rath, G. (1866) Mineralogisch-geognostische Fragmente aus Italien. Zeitschrift der deutschen geologischen Gesellschaft: 18: 634-637.
  4. 1965Papike, J. J., Zoltai, Tibor (1965) The crystal structure of a marialite scapolite. American Mineralogist, 50 (5-6) 641-655
  5. 1973Ulbrich, Horst H. (1973) Crystallographic data and refractive indices of scapolites. American Mineralogist, 58 (1-2) 81-92
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Marialite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/marialite-2575},
  note      = {Accessed 2026-05-11}
}