Titanite

CaTi(SiO4)O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Ttn
Discovered
1795
Also known as
  • Aspidelit
  • Aspidelita
  • Aspidelite
  • +13 more

History

Titanite is the modern, internationally agreed name for a mineral the world knew for nearly two centuries as sphene.

The first sighting belongs to the Swiss naturalist Marc-Auguste Pictet, who in 1787 noted a "nouveau substance minérale" without giving it a full description or a name. The story then waits eight years for the Berlin chemist Martin Heinrich Klaproth. In 1795 Klaproth confirmed a new element in the ore rutile and named it titanium, after the Titans of Greek mythology. Recognising that Pictet's mystery mineral was rich in the same element, he named it titanite for its titanium content.

A second name arrived in 1801. The French crystallographer René Just Haüy proposed sphene, from the Greek sphenos — wedge — for the mineral's characteristic wedge-shaped crystals. Both names then coexisted in the literature for almost two centuries, with sphene dominating in gemmology and titanite in formal mineralogy.

The International Mineralogical Association settled the matter in 1982: it adopted titanite as the official species name and discredited sphene. Sphene survives in the gem trade as an informal name for transparent, fire-bright cut stones, but every modern technical publication now uses titanite.

Industrial & practical applications

Titanite has almost no bulk-industrial life. It contains roughly 40 % titanium dioxide by weight, but the world's titanium supply is drawn overwhelmingly from ilmenite and rutile. Ilmenite alone covers about 91 % of demand, so titanite is rarely mined as a titanium ore in its own right.

The mineral's real value is scientific. Titanite is one of the workhorse minerals of U–Pb geochronology, the technique that dates rocks by measuring how much radioactive uranium has decayed into lead inside a crystal. Titanite traps uranium when it grows and holds the resulting lead up to about 700 °C. It is also widespread as an accessory mineral, a minor but reliable component of many igneous and metamorphic rocks.
That high closure temperature is the point. Most mineral clocks only register cooling; titanite can record the formation event itself, letting geologists date deep-crustal metamorphism, magmatism, and ore-forming fluids.

In gemmology the older name survives. Cut sphene — transparent titanite, usually a vivid yellow-green to brown — is prized for a dispersion of 0.051. That figure exceeds the dispersion of diamond, the optical property that splits white light into spectral colours. The trade is small. Gem-quality crystals are uncommon, and at a hardness of 5.5 the stone is too soft for daily wear. Faceted sphene mostly ends up in collector pieces and pendants.

Where it forms, where it's found

Geological setting

Common accessory mineral in intermediate and felsic plutonic rocks, pegmatites, alpine veins. Also in some gneisses, schists, and skarns.

Type locality
Titanite occurrence
  1. Hauzenberg
  2. Passau District
  3. Lower Bavaria
  4. Bavaria
  5. Germany
5,835recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789105 – 5.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Adamantine to resinous
Transparency
Transparent · Translucent
Colour
Brown · green · yellow · orange · rose-red · black · beige · grey · colourless · grey-blue · bluish
Streak
White
Tenacity
brittle
Cleavage
Distinct/Good

Good on (110)

Density
3.48 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 17 – 40° · 2V calc = 68 – 82°
Refractive index
1.843 – 2.11
Surface relief
Very high
Principal indices
nα 1.843 – 1.95 · nβ 1.87 – 2.034 · nγ 1.943 – 2.11
Pleochroism
Visible

X= nearly colorless Y= yellow to green Z= red to yellow orange

Dispersion
r > v extreme
Extinction
Z ∧ c = 51°.
Tropism
Anisotropic
Reflectance R%
(10.7,12.6,1.5,2.47) 400, (10.4,12.4,1.46,2.33) 420, (10.1,12.1,1.43,2.27) 440, (9.98,11.9,1.39,2.18) 460, (9.90,11.8,1.37,2.15) 470, (9.84,11.7,1.36,2.11) 480, (9.71,11.5,1.34,2.06) 500, (9.61,11.3,1.32,2.01) 520, (9.50,11.2,1.30,1.97) 540, (9.48,11.1,1.29,1.96) 546, (9.46,11.1,1.29,1.94) 560, (9.45,11.0,1.28,1.92) 580, (9.43,11.0,1.28,1.91) 589, (9.44,11.0,1.28,1.91) 600, (9.44,11.0,1.28,1.91) 620, (9.44,11.0,1.29,1.91) 640, (9.43,10.9,1.29,1.89) 650, (9.44,11.0,1.29,1.89) 660, (9.44,10.9,1.29,1.88) 680, (9.44,10.9,1.29,1.87) 700
Michel-Lévy diagramhighlighted lineδ = 0.1300
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1300 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1300 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/a
Cell parameters
a = 7.057 Å · b = 8.707 Å · c = 6.555 Å
Cell angles
β = 113.81 °
Ratio a:b:c
1 : 1.234 : 0.929
Z
4
Morphology

Common forms are (111), (110), (102), (100), (001) and (112). Crystals equant to wedge-shaped, or flattened with large (001) or (102), or prismatic by extension along [001], to 65 x 17 x 17 cm, compact, massive. NOTE: The morphological data is based on a choice of unit-cell parameters that differs from the one that is given in Mindat. This 'old' unit cell has a = 6.56, b = 8.72, c = 7.44 Å and β = 119.54° (see the introduction in http://rruff.info/rruff_1.0/uploads/AM61_238.pdf). The 3D drawings of titanite are also based on this old cell.

Twinning

On (100), contact and penetration, less commonly lamellar on (221).

Parting
Due to twinning on (221)
Comment

May be metamict. Titanite close to end-member composition has space-group symmetry <i>P</i>21/<i>a</i>, whereas titanite with significant additional constituents has <i>A</i>2/<i>a</i> symmetry. Smaller unit cells indicate an Al- and F-rich composition.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen515.99979.995
40.81%
22TiTitaniumTitanium147.86747.867
24.42%
20CaCalciumCalcium140.07840.078
20.44%
14SiSiliconSilicon128.08528.085
14.33%
Total196.025100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Y
  • Mn
  • Al
  • Ce
  • Sr
  • Na
  • Nb
  • Ta
  • Al
  • Mg
  • V
  • F
  • Zr
  • Sn

Synonyms

  • Aspidelit
  • Aspidelita
  • Aspidelite
  • Braunmenakerz
  • Castellit
  • Castellite
  • Gelbmenakerz
  • Ligurit
  • Ligurita
  • Ligurite
  • Menakerz
  • Semelin
  • Sphen
  • Sphene
  • Spinellin
  • Titanite (of Klaproth)

In other languages

French
sphène · Titanite
German
Sphen · Titanit
Spanish
esfena · titanita
Italian
ligurite · titanite
Portuguese
Esfena · Esfeno · titanita · Titanite
Japanese
くさび石 · スフェーン · チタナイト · チタン石
Chinese
榍石
Russian
Сфен · Титанит
Arabic
التيتانيت · تيتانيت

Classification

Strunz
10th ed.

9.AG.15

  • 9SilicatesClass
  • 9.ANesosilicatesDivision
  • 9.AGNesosilicates with additional anions; cations in > [6] +- [6] coordinationGroup
  • 9.AG.15TitaniteSpecies
Dana
8th ed.

52.04.03.01

  • 52Nesosilicates Insular Sio4 Groups and O, Oh, F, H2oClass
  • 52.04Insular SiO4 Groups and O, OH, F, and H2O with cations in [6] and/or >[6] coordinationType
  • 52.04.03Titanite groupGroup
  • 52.04.03.01TitaniteSpecies
CIM

14.9.6

  • 14Silicates not Containing AluminumClass
  • 14.9Silicates of TiGroup
  • 14.9.6TitaniteSpecies

Group, growth & confusion

In the same group
4 members
Commonly confused with
3 minerals

Literature, links & citation

Citations
  1. Szełęg, E. (2003): The crystal chemistry of tin in titanite. Mineralogical Society of Poland - Special Papers, 22, 218-220.
  2. 1795Klaproth, M. H. (1795) XV. Untersuchung eines neuen Fossils as dem Passauischen. In Beiträge zur chemischen Kenntniss der Mineralkörper Vol. 1. Rottmann. p.245-252.
  3. 1937Strunz, Hugo (1937) Titanit und Tilasit. Über die Verwandtschaft der Silikate mit den Phosphaten und Arsenaten. Zeitschrift für Kristallographie, Mineralogie und Petrographie, 96 (1). 7-14 doi:10.1524/zkri.1937.96.1.7DOI: 10.1524/zkri.1937.96.1.7
  4. 1947Jaffe, Howard W. (1947) Reexamination of sphene (titanite) American Mineralogist, 32 (11-12) 637-642
  5. 1972Černý, P.; Povondra, P. (1972) An Al,F-rich metamict titanite from Czechoslovakia. Neues Jahrbuch für Mineralogie - Monatshefte, 1972 (9). 400-406 doi:10.1127/njmm/1972/1972/400DOI: 10.1127/njmm/1972/1972/400
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Titanite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/titanite-3977},
  note      = {Accessed 2026-05-11}
}