Massicot

PbO
IMA status
  • Approved
  • Grandfathered
IMA symbol
Msi
Discovered
1841
Also known as
  • Bleiglätte
  • Bleioxyd
  • Chrysitin
  • +15 more

Where it forms, where it's found

Geological setting

As an alteration product of lead minerals.

Type locality
Binsfeldhammer lead smelter slag locality
  1. Stolberg
  2. Aachen
  3. Cologne
  4. North Rhine-Westphalia
  5. Germany

50.7575°, 6.2431°

190recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent · Opaque
Colour
Sulphur- to orpiment-yellow · sometimes with a reddish tint · grey-yellow. Nearly colourless to pale yellow in transmitted light.
Streak
Yellow
Density
9.56 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 90° · 2V calc = 86°
Refractive index
2.51 – 2.71
Surface relief
Very high
Principal indices
nα 2.51 · nβ 2.61 · nγ 2.71
Pleochroism
Visible

Y = light sulfur-yellow Z = deep yellow

Dispersion
Strong
Michel-Lévy diagramhighlighted lineδ = 0.2000
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]2000 nm4th order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation2000 nm
Order4th order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#52
Cell parameters
a = 5.4903(1) Å · b = 5.892 Å · c = 4.752 Å
Ratio a:b:c
1 : 1.073 : 0.866
Z
4
Morphology

Massive, earthy to scaly. Artificial crystals are tabular (100).

Twinning

Observed on artificial crystals.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead1207.200207.200
92.83%
8OOxygenOxygen115.99915.999
7.17%
Total223.199100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Bleiglätte
  • Bleioxyd
  • Chrysitin
  • Lead monoxide
  • Lead ocher
  • Litarjirio nativo
  • Masicotit
  • Masicotite
  • Massicolit
  • Massicolita
  • Massicolite
  • Massicottit
  • Massicottita
  • Massicottite
  • Masticot
  • Piombo ossidato
  • Plomb oxidé jaune
  • Silberglätte

In other languages

French
massico · massicot
German
Bleiglätte · Litharge · Massicot · Massicotit · Massikot
Spanish
masicote · masicotita
Italian
Massicot
Chinese
黄丹 · 黄丹 (矿物)
Russian
Массикот
Arabic
ماسيكُوت

Classification

Strunz
10th ed.

4.AC.25

  • 4OxidesClass
  • 4.AMetal: Oxygen = 2:1 and 1:1Division
  • 4.ACM:O = 1:1 (and up to 1:1.25); with large cations (+- smaller ones)Group
  • 4.AC.25MassicotSpecies
Dana
8th ed.

04.02.07.01

  • 04Simple OxidesClass
  • 04.02AXType
  • 04.02.07— unnamed intermediate level —Group
  • 04.02.07.01MassicotSpecies
CIM

7.11.20

  • 7Oxides and HydroxidesClass
  • 7.11Oxides of Sn and PbGroup
  • 7.11.20MassicotSpecies

Group, growth & confusion

Often grow together
2 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1841Huot (1841): 346.
  2. 1875Weisbach (1875): 54.
  3. 1883D'Achiardi (1883): 1: 221.
  4. 1917Larsen, Esper S. (1917) Massicot and litharge, the two modifications of lead monoxide. American Mineralogist, 2 (2) 18-19
  5. 1944Palache, Charles, Berman, Harry, Frondel, Clifford (1944) The System of Mineralogy (7th ed.) Vol. 1 - Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, New York.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Massicot — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/massicot-2587},
  note      = {Accessed 2026-05-11}
}