Metanatroautunite

Na(UO2)(PO4) · 3H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Mnaut
Discovered
1957
Also known as
  • Metanatroautuniet
  • Natriumautunit
  • Sodium Autunite
  • +1 more

Where it forms, where it's found

Geological setting

Oxidation zone of a uranium deposit.

9recorded occurrences
Source · OpenStreetMap

Radioactivity

Physical

Hardness
123456789102 – 2.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Lemon-yellow
Streak
White
Tenacity
brittle
Cleavage
Perfect

(001)

Fracture
Micaceous
Density
3.62 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.559 – 1.578
Surface relief
Moderate
Principal indices
nω 1.578 · nε 1.559
Birefringence
0.019
Pleochroism
Visible

O = light yellow, E = pale yellow

UV response
Fluoresces yellow green in SW and LW UV
Michel-Lévy diagramhighlighted lineδ = 0.0190
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]190 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation190 nm
Order1st order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
#184
Cell parameters
a = 6.9935(7) Å · c = 17.5101(12) Å
Unit cell volume
856.4 ų
Z
4
Type-locality form

Pale yellow platy crystals, sometimes in foliated or radiating aggregates.

Comment

Mills et al. (2012)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
92UUraniumUranium1238.029238.029
53.85%
8OOxygenOxygen915.999143.991
32.57%
15PPhosphorusPhosphorus130.97430.974
7.01%
11NaSodiumSodium122.99022.990
5.20%
1HHydrogenHydrogen61.0086.048
1.37%
Total442.032100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Metanatroautuniet
  • Natriumautunit
  • Sodium Autunite
  • Sodium Meta-autunite

In other languages

German
Metanatroautunit
Italian
metanatroautunite · Sodio meta-autunite · Sodio-autunite

Classification

Strunz
10th ed.

8.EB.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.EUranyl phosphates and arsenatesDivision
  • 8.EBUO2:RO4 = 1:1Group
  • 8.EB.10MetanatroautuniteSpecies
Dana
8th ed.

40.2a.05.01

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.2aAB2(XO4)2·xH2O, containing (UO2)2+Type
  • 40.2a.05— unnamed intermediate level —Group
  • 40.2a.05.01MetanatroautuniteSpecies
CIM

19.11.6

  • 19PhosphatesClass
  • 19.11Phosphates of UGroup
  • 19.11.6MetanatroautuniteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1957Chernikov, A.A., Krutetskaya, O.V. and Organova, N.I. (1957) Natroautunite. Soviet Journal of Atomic Energy, 3, 901–5.
  2. 1981Butt, C. R. M., Graham, J. (1981) Sodian potassian hydroxonian meta-autunite: first natural occurrence of an intermediate member of a predicted solid solution series. American Mineralogist, 66 (9-10) 1068-1072
  3. 1981Chernikov, A.A. (1981) Behaviour of Uranium in the Hypergene Zone. Nedra, Moscow, Russia, 24p (In Russ.).
  4. 1994Chernikov, A.A. and Organova, N.I. (1994) Natroautunite and metanatroautunite. Transactions of the Russian Academy of Sciences, 341A, 109–113.
  5. 2004Mills, S.J. (2004) Metanatroautunite (‘sodium autunite’) from the Lake Boga Granite, Victoria. Australian Journal of Mineralogy, 10(1), 29–31.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Metanatroautunite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/metanatroautunite-3705},
  note      = {Accessed 2026-05-11}
}