Millerite

NiS
IMA status
  • Approved
  • Grandfathered
IMA symbol
Mlr
Discovered
1845
Also known as
  • Archise
  • Capillary Pyrite
  • Capillary Pyrites
  • +8 more

History

The mineral that carries the name of crystallography's most famous notation system was first picked out of a Welsh coal mine. In 1845, the mineralogist Wilhelm Haidinger described a brassy, hair-thin sulfide found in the coal seams of Wales and named it millerite in honour of William Hallowes Miller.

Miller (1801–1880) was a Welsh-born professor at the University of Cambridge who had spent his career making crystals legible. In 1839 he published the notation that still bears his name — Miller indices, the small bracketed numbers that label every face and plane in a crystal. He had also written A Treatise on Crystallography, the textbook that put the system on its feet. Haidinger, dedicating a new species, picked the man who had given mineralogists the language to describe one.

The mineral also goes by two alternative names. It is called capillary pyrites — a reference to the fine hair-like needles in which it tends to grow — and nickel blende, marking it as a sulfide-of-nickel cousin to the better-known zinc blende.

Beyond the Welsh type locality, classic occurrences include Andreasberg in the Harz mountains of Germany, where the mineral forms as an alteration product of older nickel minerals, and Mount Vesuvius, where it appears as a sublimation product.

Industrial & practical applications

Millerite is a minor player in the world's nickel supply. Where it is locally concentrated, though, it makes an excellent ore. Pound for pound it carries a higher percentage of nickel than pentlandite — the sulfide that dominates global production. Several large nickel sulfide orebodies in Western Australia rely in part on it, among them Silver Swan, Mt Keith and Honeymoon Well. It also appears in the nickel laterite deposits of New Caledonia. Outside those settings it rarely accumulates in mineable concentrations.

For most of the world the mineral is sought as a specimen. Halls Gap in Lincoln County, Kentucky yields the radiating sprays of fine brassy needles that define the species in collections. The locality is the most common source of museum-quality material, with further sites in Wisconsin rounding out the regular collector circuit.

Where it forms, where it's found

Geological setting

A low-temperature mineral which occurs in sulfidic limestones and dolostones, and as a late-forming mineral in nickel sulfide deposits.

Type locality
Jáchymov
  1. Karlovy Vary District
  2. Karlovy Vary Region
  3. Czech Republic

50.3661°, 12.9233°

1,117recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103 – 3.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Metallic
Transparency
Opaque
Colour
Pale brass-yellow · with an iridescent tarnish · and greenish-grey.
Streak
Greenish black
Tenacity
brittle
Cleavage
Perfect

Perfect on (1011) and (0112).

Fracture
Irregular/Uneven
Density
5.3 g/cm³

Optical

Pleochroism
Weak

Weak in air stronger in oil Pale yellow-brown to bright yellow

Anisotropism
Strong
Tropism
Anisotropic
Reflectance R%
(26.4,30.0) 400, (29.8,34.0) 420, (35.6,38.8) 440, (41.0,42.1) 460, (45.1,44.8) 480, (48.4,46.9) 500, (51.5,48.4) 520, (53.9,49.8) 540, (55.5,50.8) 560, (57.0,51.8) 580, (58.3,51.6) 600, (59.2,53.3) 620, (59.9,53.8) 640, (60.4,54.2) 660, (60.5,54.4) 680, (60.5,54.3) 700
Luminescence
None
Reflected-light panel
50.2 %anisotropic · dual curve
Specimen sRGB 255, 180, 77
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Strong

Crystallography

Crystal system
Trigonal
Space group
#86
Cell parameters
a = 9.607 Å · c = 3.143 Å
Z
9
Morphology

Acicular crystals in radiating or jackstraw clusters; also massive.

Twinning

None reported.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
28NiNickelNickel158.69358.693
64.67%
16SSulfurSulfur132.06032.060
35.33%
Total90.753100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Co
  • Cu

Synonyms

  • Archise
  • Capillary Pyrite
  • Capillary Pyrites
  • Capillose
  • Gelbnickelkies
  • Haarkies
  • Hair Pyrites
  • Nickel Pyrite
  • Trichopyrit
  • Trichopyrita
  • Trichopyrite

In other languages

French
archise · harkise · millérite · nickel sulfuré · pyrite capillaire · pyrite de nickel · trichopyrite
German
Gelbnickelkies · Haarkies · Haarpyrit · Millerit · Nickelkies · Trichopyrit
Spanish
Millerita
Italian
Millerite
Japanese
針ニッケル鉱
Chinese
针镍 · 针镍矿
Russian
Миллерит
Arabic
ميلريت

Classification

Strunz
10th ed.

2.CC.20

  • 2Sulfides and SulfosaltsClass
  • 2.CMetal Sulfides, M: S = 1: 1 (and similar)Division
  • 2.CCWith Ni, Fe, Co, PGE, etc.Group
  • 2.CC.20MilleriteSpecies
Dana
8th ed.

02.08.16.01

  • 02SulfidesClass
  • 02.08AmXp, with m:p = 1:1Type
  • 02.08.16— unnamed intermediate level —Group
  • 02.08.16.01MilleriteSpecies
CIM

3.11.3

  • 3Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)Class
  • 3.11Sulphides etc. of NiGroup
  • 3.11.3MilleriteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1845Haidinger, W. (1845) Zweite Klasse: Geogenide. XIII. Ordnung. Kiese. IV. Eisenkies. Millerit., in Handbuch der Bestimmenden Mineralogie Bei Braumüller and Seidel Wien: 559-562.
  2. 1902Lohest, M. (1902) Présentation de millérite. Annales de la Société géologique de Belgique, 29, B142.
  3. 1904Palache, C., Wood, H.O. (1904) A crystallographic study of millerite. American Journal of Science: 18: 343-359.
  4. 1925Alsén, N. (1925) Röntgenographische Untersuchung der Kristallstrukturen von Magnetkies, Breithauptit, Pentlandit, Millerit und verwandten Verbindungen. Geologiska Föreningens i Stockholm Förhandlingar: 47: 19-72.
  5. 1943Stainier, X. (1943) L'origine de la millérite du Houiller. Annales de la Société géologique de Belgique: 66: B86
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Millerite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/millerite-2711},
  note      = {Accessed 2026-05-11}
}