Natrophilite

NaMn2+(PO4)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Ntp
Discovered
1890
Also known as
  • Natrophiliet

Where it forms, where it's found

Geological setting

Granite pegmatite.

Type locality
Fillow Quarry
  1. Branchville
  2. Redding
  3. Fairfield County
  4. Connecticut
  5. USA

41.2678°, -73.4392°

8recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104.5 – 5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Deep yellow to light yellow
Streak
White
Tenacity
brittle
Cleavage
Distinct/Good

On (001), good; on (010), indistinct; on (021) poor.

Fracture
Irregular/Uneven
Density
3.41 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 70 – 80° · 2V calc = 58°
Refractive index
1.671 – 1.684
Surface relief
High
Principal indices
nα 1.671 · nβ 1.674 · nγ 1.684
Birefringence
0.013
Pleochroism
Non-pleochroic
Dispersion
r < v, relatively strong
Extinction
XYZ = abc
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0130
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]130 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation130 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
Pmna
Cell parameters
a = 6.31 Å · b = 10.517 Å · c = 4.98 Å
Ratio a:b:c
1 : 1.667 : 0.789
Morphology

Crystals unknown; usually as small (1 mm) grains of as thin fracture (1 mm wide) fillings.

Type-locality form

Embedded grains.

Comment

Incomplete structure analysis, Am Min (1972) 57:1333

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen415.99963.996
37.01%
25MnManganeseManganese154.93854.938
31.78%
15PPhosphorusPhosphorus130.97430.974
17.91%
11NaSodiumSodium122.99022.990
13.30%
Total172.898100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Natrophiliet

In other languages

French
natrophilite
German
Natrophilit
Spanish
Natrofilita
Italian
natrofilite
Arabic
ناتروفيليت

Classification

Strunz
10th ed.

8.AB.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.APhosphates, etc. without additional anions, without H2ODivision
  • 8.ABWith medium-sized cationsGroup
  • 8.AB.10NatrophiliteSpecies
Dana
8th ed.

38.01.01.03

  • 38Anhydrous Normal Phosphates, Arsenates, and VanadatesClass
  • 38.01ABXO4Type
  • 38.01.01Triphylite GroupGroup
  • 38.01.01.03NatrophiliteSpecies
CIM

19.12.3

  • 19PhosphatesClass
  • 19.12Phosphates of MnGroup
  • 19.12.3NatrophiliteSpecies

Group, growth & confusion

In the same group
6 members

Literature, links & citation

Citations
  1. 1890Brush, G.J., Dana, E.S., Wells, H.L. (1890). On the mineral locality at Branchville, Connecticut: Fifth paper. American Journal of Science, 39, 201-216 (205).
  2. 1921Larsen, Esper S. (1921) The microscopic determination of the nonopaque minerals. Bulletin 679. US Geological Survey doi:10.3133/b679 DOI: 10.3133/b679
  3. 1943Byström, A. (1943). The structure of natrophilite, NaMn(PO4). Arkiv för Kemi, Mineralogi och Geologi, Stockholm, 17B(4), 1-4.
  4. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  5. 1965Fisher, D. Jerome (1965) Natrophilite. American Mineralogist, 50 (7-8) 1096-1097
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Natrophilite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/natrophilite-2861},
  note      = {Accessed 2026-05-11}
}