Where it forms, where it's found
- Geological setting
Granite pegmatite.
Complex zoned granitic pegmatites.
- Type locality
- Hühnerkobel Mine (Hennenkobel Mine)
- Rabenstein
- Zwiesel
- Regen District
- Lower Bavaria
- Bavaria
- Germany
49.0517°, 13.1697°
Physical
- Hardness
- 1Talc
- 2Gypsum
- 3Calcite
- 4Fluorite
- 5Apatite
- 6Orthoclase
- 7Quartz
- 8Topaz
- 9Corundum
- 10Diamond
- Transparency
- Translucent
- Colour
- Brown-green · light green-gray · may appear blue-gray · colourless to pale yellow in transmitted light.
Blue shades may be due to vivianite inclusions.
- Streak
- Colorless to grayish white.
- Tenacity
- brittle
- Cleavage
- Very Good
On (001) nearly perfect; on (010) good; on (011) poor.
- Fracture
- Irregular/Uneven
- Density
- 3.42 g/cm³
Optical
- Optical type
- Biaxial (+/-) · 2V measured = 90°
- Refractive index
- 1.6849 – 1.72
- Surface relief
- High
- Principal indices
- nα 1.689 – 1.705 · nβ 1.6849 – 1.710 · nγ 1.685 – 1.720
- Birefringence
- 0.008
- Pleochroism
- Non-pleochroic
- Dispersion
- r > v or r < v
- Extinction
- Parallel, may rarely be optically (+), oxidation greatly increases RI, e.g. α 1.790 β 1.805 γ 1.820 biref 0.030 2V = 85°; Mg reduces RI (Am Min 28:90 (1943)).
- UV response
- Not fluorescent.
- Notes
Oxidation greatly changes optical properties. Triphylite may look black or contain blue vivianite alteration along cleavages. Sometimes masses are rimmed by blue tourmaline. Variation of optic orientation and optic nature across composition: X = c; Y = b; Z = a, B(neutral) with 2V° near 90° for end-member/near end-member triphylite, decreasing to B(-) with 2V° near 0° at composition roughly Lhp18Trp82; X = c, and sensibly U(-) at composition roughly Lhp19Trp81; X = c; Y = a; Z = b, B(-) with 2V° near 0° at composition roughly Lhp20Trp80, increasing to B(neutral) with 2V° near 90° at composition roughly Lhp25Trp75; with further compositional change towards lithiophilite, optical sign switches to B(+) and 2V° decreases to near 0° at composition roughly Lhp39Trp61; Z = b, and sensibly U(+) at composition roughly Lhp40Trp60; X = a; Y = c; Z = b, B(+) with 2V° near 0° at composition roughly Lhp41Trp59, increasing to B(+) with 2V° near 29° at composition roughly Lhp50Trp50 (the nomenclature boundary between triphylite and lithiophilite); see <m>lithiophilite</m> for further optic orientation changes on the Mn-rich side of the nomenclature boundary.
Crystallography
- Space group
- #70
- Cell parameters
- a = 6.0285(6) Å · b = 10.3586(9) Å · c = 4.7031(3) Å
- Ratio a:b:c
- 1 : 1.718 : 0.780
- Z
- 4
- Morphology
Crystals rare; commonly coarse with uneven surfaces; stout prismatic [100]. Massive, rarely granular. May exist in pods over 1 meter across. Commonly replaced by siderite with accompanying secondary phosphate species.
- Epitaxy
As coarsely laminated intergrowths with Graftonite, both phases mutually oriented with Graftonite (010) [100] parallel to Triphylite (102) [010].
- Comment
Pmnb, AC B (1976) 32:2761 structure
Chemical composition
- Impurities
- Mn
- Mg
- Ca
Synonyms
- Lithio-Ferro-Triphylite
- Perowskyn
- Tetraphylin
- Triphylita
In other languages
- French
- Triphylite
- German
- Triphylin
- Spanish
- Trifilita
- Italian
- trifilite
- Japanese
- トリフィライト
- Chinese
- 磷铁锂矿
- Simplified Chinese
- 磷铁锂矿
- Traditional Chinese
- 磷鐵鋰礦
- Arabic
- تريفيليت
Classification
8.AB.10
- 8Phosphates, Arsenates, VanadatesClass
- 8.APhosphates, etc. without additional anions, without H2ODivision
- 8.ABWith medium-sized cationsGroup
- 8.AB.10TriphyliteSpecies
38.01.01.01
- 38Anhydrous Normal Phosphates, Arsenates, and VanadatesClass
- 38.01ABXO4Type
- 38.01.01Triphylite GroupGroup
- 38.01.01.01TriphyliteSpecies
19.1.13
- 19PhosphatesClass
- 19.1Phosphates of the alkali metalsGroup
- 19.1.13TriphyliteSpecies
Group, growth & confusion
AlbiteNa(AlSi3O8)Mineral—
Alluaudite◻NaMnFe3+2(PO4)3Mineral—
AmblygoniteLiAl(PO4)FMineral—
BerauniteFe3+6(PO4)4O(OH)4 · 6H2OMineral—
GraftoniteFe2+Fe2+2(PO4)2Mineral—
HureauliteMn2+5(PO3OH)2(PO4)2 · 4H2OMineral—
JohnsomervilleiteNa3CaFe2+11(PO4)9Mineral—
LudlamiteFe2+3(PO4)2 · 4H2OMineral—
MontebrasiteLiAl(PO4)(OH)Mineral—
MontgomeryiteCa4MgAl4(PO4)6(OH)4 · 12H2OMineral—
Literature, links & citation
- 1834Fuchs, J.N. (1834) Ueber ein neues Mineral (Triphylin). Journal für Praktische Chemie, Leipzig: 3: 98-104. (as Triphylin)
- 1834Fuchs, J.N. (1834) Ueber ein neues Mineral (Triphylin). Journal für Praktische Chemie, Leipzig: 3: 98-104.
- 1835Fuchs (1835) Journal für praktische Chemie, Leipzig: 5: 319 (as Triphylin).
- 1835Nordenskiöld (1835) Annalen der Physik, Halle, Leipzig: 36: 473 (as Perowskyn).
- 1836Berzelius (1836) Jahresber.: 15: 211 (as Tetraphylin).
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Triphylite — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/triphylite-4020},
note = {Accessed 2026-05-11}
}


