Triphylite

LiFe2+(PO4)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Trp
Discovered
1834
Also known as
  • Lithio-Ferro-Triphylite
  • Perowskyn
  • Tetraphylin
  • +1 more

Where it forms, where it's found

Geological setting

Granite pegmatite.

Complex zoned granitic pegmatites.

Type locality
Hühnerkobel Mine (Hennenkobel Mine)
  1. Rabenstein
  2. Zwiesel
  3. Regen District
  4. Lower Bavaria
  5. Bavaria
  6. Germany

49.0517°, 13.1697°

280recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Brown-green · light green-gray · may appear blue-gray · colourless to pale yellow in transmitted light.

Blue shades may be due to vivianite inclusions.

Streak
Colorless to grayish white.
Tenacity
brittle
Cleavage
Very Good

On (001) nearly perfect; on (010) good; on (011) poor.

Fracture
Irregular/Uneven
Density
3.42 g/cm³

Optical

Optical type
Biaxial (+/-) · 2V measured = 90°
Refractive index
1.6849 – 1.72
Surface relief
High
Principal indices
nα 1.689 – 1.705 · nβ 1.6849 – 1.710 · nγ 1.685 – 1.720
Birefringence
0.008
Pleochroism
Non-pleochroic
Dispersion
r > v or r < v
Extinction
Parallel, may rarely be optically (+), oxidation greatly increases RI, e.g. α 1.790 β 1.805 γ 1.820 biref 0.030 2V = 85°; Mg reduces RI (Am Min 28:90 (1943)).
UV response
Not fluorescent.
Notes

Oxidation greatly changes optical properties. Triphylite may look black or contain blue vivianite alteration along cleavages. Sometimes masses are rimmed by blue tourmaline. Variation of optic orientation and optic nature across composition: X = c; Y = b; Z = a, B(neutral) with 2V° near 90° for end-member/near end-member triphylite, decreasing to B(-) with 2V° near 0° at composition roughly Lhp18Trp82; X = c, and sensibly U(-) at composition roughly Lhp19Trp81; X = c; Y = a; Z = b, B(-) with 2V° near 0° at composition roughly Lhp20Trp80, increasing to B(neutral) with 2V° near 90° at composition roughly Lhp25Trp75; with further compositional change towards lithiophilite, optical sign switches to B(+) and 2V° decreases to near 0° at composition roughly Lhp39Trp61; Z = b, and sensibly U(+) at composition roughly Lhp40Trp60; X = a; Y = c; Z = b, B(+) with 2V° near 0° at composition roughly Lhp41Trp59, increasing to B(+) with 2V° near 29° at composition roughly Lhp50Trp50 (the nomenclature boundary between triphylite and lithiophilite); see <m>lithiophilite</m> for further optic orientation changes on the Mn-rich side of the nomenclature boundary.

Michel-Lévy diagramhighlighted lineδ = 0.0080
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]80 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation80 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#70
Cell parameters
a = 6.0285(6) Å · b = 10.3586(9) Å · c = 4.7031(3) Å
Ratio a:b:c
1 : 1.718 : 0.780
Z
4
Morphology

Crystals rare; commonly coarse with uneven surfaces; stout prismatic [100]. Massive, rarely granular. May exist in pods over 1 meter across. Commonly replaced by siderite with accompanying secondary phosphate species.

Epitaxy

As coarsely laminated intergrowths with Graftonite, both phases mutually oriented with Graftonite (010) [100] parallel to Triphylite (102) [010].

Comment

Pmnb, AC B (1976) 32:2761 structure

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen415.99963.996
40.57%
26FeIronIron155.84555.845
35.40%
15PPhosphorusPhosphorus130.97430.974
19.63%
3LiLithiumLithium16.9406.940
4.40%
Total157.755100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Mn
  • Mg
  • Ca

Synonyms

  • Lithio-Ferro-Triphylite
  • Perowskyn
  • Tetraphylin
  • Triphylita

In other languages

French
Triphylite
German
Triphylin
Spanish
Trifilita
Italian
trifilite
Japanese
トリフィライト
Chinese
磷铁锂矿
Simplified Chinese
磷铁锂矿
Traditional Chinese
磷鐵鋰礦
Arabic
تريفيليت

Classification

Strunz
10th ed.

8.AB.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.APhosphates, etc. without additional anions, without H2ODivision
  • 8.ABWith medium-sized cationsGroup
  • 8.AB.10TriphyliteSpecies
Dana
8th ed.

38.01.01.01

  • 38Anhydrous Normal Phosphates, Arsenates, and VanadatesClass
  • 38.01ABXO4Type
  • 38.01.01Triphylite GroupGroup
  • 38.01.01.01TriphyliteSpecies
CIM

19.1.13

  • 19PhosphatesClass
  • 19.1Phosphates of the alkali metalsGroup
  • 19.1.13TriphyliteSpecies

Group, growth & confusion

In the same group
6 members
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1834Fuchs, J.N. (1834) Ueber ein neues Mineral (Triphylin). Journal für Praktische Chemie, Leipzig: 3: 98-104. (as Triphylin)
  2. 1834Fuchs, J.N. (1834) Ueber ein neues Mineral (Triphylin). Journal für Praktische Chemie, Leipzig: 3: 98-104.
  3. 1835Fuchs (1835) Journal für praktische Chemie, Leipzig: 5: 319 (as Triphylin).
  4. 1835Nordenskiöld (1835) Annalen der Physik, Halle, Leipzig: 36: 473 (as Perowskyn).
  5. 1836Berzelius (1836) Jahresber.: 15: 211 (as Tetraphylin).
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Triphylite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/triphylite-4020},
  note      = {Accessed 2026-05-11}
}