Heterosite

Fe3+(PO4)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Het
Discovered
1825
Also known as
  • Ferripurpurite
  • Heteposite
  • Hetepozit
  • +8 more

Where it forms, where it's found

Geological setting

Granite pegmatite.

Secondary mineral in complex granitic pegmatites replacing triphylite.

Type locality
Les Hureaux
  1. Saint-Sylvestre
  2. Limoges
  3. Haute-Vienne
  4. Nouvelle-Aquitaine
  5. France
164recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104 – 4.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Untreated mineral is usually Purple Black · also Deep rose to reddish purple · especially when treated in a strong acid solution.

Dark brown to brown-black. Uncommonly naturally bright purple. Most bright purple heterosite is artificially induced by acid etching.

Streak
Pale purple
Tenacity
brittle
Cleavage
Distinct/Good

On (100), good; on (010) imperfect. Cleavage surfaces curved or crinkled at times.

Fracture
Irregular/Uneven
Density
3.40 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 37°
Refractive index
1.861 – 1.911
Surface relief
Very high
Principal indices
nα 1.861 · nβ 1.891 · nγ 1.911
Birefringence
0.050
Pleochroism
Strong

X = Greenish gray, gray to rose-red Y, Z = Deep blood-red to purplish red Z = Deep blood-red to purplish red

Dispersion
r > v very strong
UV response
Not Fluorescent
Notes

Optic axis sections may exhibit anomalous green interference colours.

Michel-Lévy diagramhighlighted lineδ = 0.0500
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]500 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation500 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#70
Cell parameters
a = 5.83(1) Å · b = 9.79(1) Å · c = 4.769(5) Å
Ratio a:b:c
1 : 1.679 : 0.818
Z
4
Morphology

Cleavable blocky masses

Comment

Pmnb

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen415.99963.996
42.43%
26FeIronIron155.84555.845
37.03%
15PPhosphorusPhosphorus130.97430.974
20.54%
Total150.815100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Mn

Synonyms

  • Ferripurpurite
  • Heteposite
  • Hetepozit
  • Heterozite
  • Melanchlor
  • Na-heterosite
  • Neopurpurite
  • Pseudotriplit
  • Pseudotriplite
  • Purpurite (of Graton and Schaller)
  • Soda-Heterosite

In other languages

French
Ferripurpurite · Hétérosite · Hétérozite · Na-heterosite · Néopurpurite · Pseudotriplite
German
Heterosit
Spanish
Heterosita
Italian
eterosite · Heterosite

Classification

Strunz
10th ed.

8.AB.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.APhosphates, etc. without additional anions, without H2ODivision
  • 8.ABWith medium-sized cationsGroup
  • 8.AB.10HeterositeSpecies
Dana
8th ed.

38.04.01.01

  • 38Anhydrous Normal Phosphates, Arsenates, and VanadatesClass
  • 38.04AXO4Type
  • 38.04.01— unnamed intermediate level —Group
  • 38.04.01.01HeterositeSpecies
CIM

19.12.10

  • 19PhosphatesClass
  • 19.12Phosphates of MnGroup
  • 19.12.10HeterositeSpecies

Group, growth & confusion

In the same group
6 members
Often grow together
3 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1825Alluaud in: Vauquelin (1825) Annales de chimie et de physique, Paris: 30: 294 (as Heteposite).
  2. 1826Alluaud, F. (1826) Notices sur l'hétérosite, l'hureaulite (fer et manganèse phosphatés), et sur quelques autres minéraux du département de la Haute-Vienne. Annales des Sciences Naturelles, 8, 334-354. (p. 346; as Heterosite and Heterozite).
  3. 1839Fuchs (1839) Journal für praktische Chemie, Leipzig: 17: 160 (as Melanchlor).
  4. 1845Blum, J.R. (1845) Lehrbuch der Mineralogie, 2nd. Edition: 537 (as Pseudotriplite).
  5. 1905Graton, L.C., Schaller, W.T. (1905) Purpurite, a new mineral. American Journal of Science, 4th. Series: 20: 146-151.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Heterosite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/heterosite-1887},
  note      = {Accessed 2026-05-11}
}