Natrotitanite

(Na0.5Y0.5)TiO(SiO4)
IMA status
  • Approved
IMA symbol
Nttn
IMA approved
2011
Also known as
  • IMA2011-033
  • Natrotitaniet

Where it forms, where it's found

Geological setting

In a rare-element deposit, which is spatially related to two small oval outcrops of alkaline granite.

Type locality
Verkhnee Espe Massif (Verkhnee Espe deposit)
  1. Akzhaylyautas Mts (Akzhailyautas Mts
  2. Akjaylautas Mts
  3. Akzhalautas Mts)
  4. Tarbagatai Range
  5. Abai Region
  6. Kazakhstan

48.1000°, 81.4500°

1recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Transparent · Translucent
Colour
Milky white to yellowish grey
Streak
White
Tenacity
brittle
Cleavage
None Observed
Density
3.833 g/cm³

Optical

Optical type
Biaxial
Refractive index
1.904 – 2.03
Surface relief
Very high
Principal indices
nα 1.904 · nγ 2.030
UV response
It shows pale orange cathodoluminescence but does not fluoresce under ultraviolet light.
Michel-Lévy diagramhighlighted lineδ = 0.1260
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1260 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1260 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/c
Cell parameters
a = 6.5691(2) Å · b = 8.6869(3) Å · c = 7.0924(2) Å
Cell angles
β = 114.1269(4) °
Ratio a:b:c
1 : 1.322 : 1.080
Unit cell volume
369.4 ų
Z
4
Type-locality form

Star-shaped aggregates of small short prisms of yellow or yellowish white (Na,Y,REE)-bearing titanite rimmed by thin (~2 µm) rims of natrotitanite are embedded in yttrium-bearing fluorite and replace narsarsukite.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen515.99979.995
37.75%
22TiTitaniumTitanium147.86747.867
22.59%
39YYttriumYttrium0.588.90644.453
20.98%
14SiSiliconSilicon128.08528.085
13.25%
11NaSodiumSodium0.522.99011.495
5.43%
Total211.895100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2011-033
  • Natrotitaniet

In other languages

German
IMA 2011-033 · Natrotitanit
Spanish
Natrotitanita
Italian
natrotitanite

Classification

Strunz
10th ed.

9.AG.15

  • 9SilicatesClass
  • 9.ANesosilicatesDivision
  • 9.AGNesosilicates with additional anions; cations in > [6] +- [6] coordinationGroup
  • 9.AG.15NatrotitaniteSpecies

Group, growth & confusion

In the same group
4 members

Literature, links & citation

Citations
  1. 2011Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2011) New minerals and nomenclature modifications approved in 2011, CNMNC Newsletter No. 10. Mineralogical Magazine, 75 (5) 2549-2561 doi:10.1180/minmag.2011.075.5.2549 DOI: 10.1180/minmag.2011.075.5.2549
  2. 2012Stepanov, A. V., Bekenova, G. K., Levin, V. L., Hawthorne, F. C. (2012) Natrotitanite, ideally (Na0.5Y0.5)Ti(SiO4)O, a new mineral from the Verkhnee Espe deposit, Akjailyautas mountains, Eastern Kazakhstan district, Kazakhstan: description and crystal structure. Mineralogical Magazine, 76 (1) 37-44 doi:10.1180/minmag.2012.076.1.37 DOI: 10.1180/minmag.2012.076.1.37
  3. 2014(2014) Natrotitanite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Natrotitanite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/natrotitanite-42452},
  note      = {Accessed 2026-05-11}
}