Phosphammite

(NH4)2(PO3OH)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Pam
Discovered
1870
Also known as
  • Phosphammiet
  • Phosphammonit
  • Phosphammonite

Where it forms, where it's found

Geological setting

Guano deposit

Guano deposits

Type locality
Earles Find
  1. Lake Rason
  2. Laverton Shire
  3. Western Australia
  4. Australia

-28.7000°, 123.9333°

5recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
White
Streak
White
Tenacity
brittle
Fracture
Irregular/Uneven
Density
1.62 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 80 – 85° · 2V calc = 85°
Refractive index
1.508 – 1.53
Surface relief
Moderate
Principal indices
nα 1.508 · nβ 1.518 · nγ 1.530
Birefringence
0.022
Dispersion
none
Michel-Lévy diagramhighlighted lineδ = 0.0220
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]220 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation220 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 8.03 Å · b = 6.68 Å · c = 11.02 Å
Cell angles
β = 113.6 °
Ratio a:b:c
1 : 0.832 : 1.372
Z
4
Comment

AC 10:709 (1957)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen415.99963.996
48.46%
15PPhosphorusPhosphorus130.97430.974
23.46%
7NNitrogenNitrogen214.00728.014
21.21%
1HHydrogenHydrogen91.0089.072
6.87%
Total132.056100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Phosphammiet
  • Phosphammonit
  • Phosphammonite

In other languages

German
Phosphammit
Italian
Fosfammite

Classification

Strunz
10th ed.

8.AD.20

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.APhosphates, etc. without additional anions, without H2ODivision
  • 8.ADWith only large cationsGroup
  • 8.AD.20PhosphammiteSpecies
Dana
8th ed.

37.01.03.01

  • 37Anhydrous Acid Phosphates, Arsenates and VanadatesClass
  • 37.01MiscellaneousType
  • 37.01.03— unnamed intermediate level —Group
  • 37.01.03.01PhosphammiteSpecies
CIM

19.1.9

  • 19PhosphatesClass
  • 19.1Phosphates of the alkali metalsGroup
  • 19.1.9PhosphammiteSpecies

Group, growth & confusion

Often grow together
3 minerals

Literature, links & citation

Citations
  1. 1852Shepard, C.U. (1852) Species 6 Phosphammonite, (S.) Phosphate of ammonia. in A Treatise on Mineralogy, B.L. Hamlen (New Haven): 64-69.
  2. 1870Shepard, C.U. (1870) Notice of the Guanape Island guano. The Rural Carolinian: 1: 469-471.
  3. 1957Smith, J.P., Lehr, L.R., Brown, W.E. (1957) Crystallographic properties of diammonium phosphate. Acta Crystalographica: 10: 709.
  4. 1972Khan, A.A., Roux, J.P., James, W.J. (1972) The crystal structure of diammonium hydrogen phosphate, (NH4)2HPO4. Acta Crystallographica: B28: 2065-2069.
  5. 1973Bridge, P. J. (1973) Urea, a new mineral, and neotype phosphammite from Western Australia. Mineralogical Magazine, 39 (303) 346-348 doi:10.1180/minmag.1973.039.303.11 DOI: 10.1180/minmag.1973.039.303.11
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Phosphammite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/phosphammite-3197},
  note      = {Accessed 2026-05-11}
}