Plimerite

Zn2Fe3+3(PO4)3(OH)4(H2O)
IMA status
  • Approved
IMA symbol
Pme
IMA approved
2008
Also known as
  • IMA2008-013
  • Plimeriet
  • Zink-Rockbridgeit

Where it forms, where it's found

Geological setting

Oxidation zone of a sulfide deposit.

Type locality
Block 14 opencut
  1. Broken Hill
  2. Broken Hill district
  3. Yancowinna Co.
  4. New South Wales
  5. Australia

-31.9591°, 141.4751°

11recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Pale-green to dark-olive-green · almost black
Streak
Pale-greyish-green
Tenacity
brittle
Cleavage
Very Good

excellent cleavage parallel to (100) and (010) and distinct cleavage parallel to (001)

Fracture
Irregular/Uneven
Density
3.67 g/cm³

Optical

Optical type
Biaxial (-) · 2V calc = 63°
Refractive index
1.756 – 1.767
Surface relief
High
Principal indices
nα 1.756 · nβ 1.764 · nγ 1.767
Pleochroism
Visible

X = pale-greenish-brown, Y = pale-brown, Z = pale-bluish-green

Notes

Absorption Z > X > Y; optical orientation XYZ = cab

Michel-Lévy diagramhighlighted lineδ = 0.0110
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]110 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation110 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 13.865(3) Å · b = 16.798(3) Å · c = 5.151(1) Å
Ratio a:b:c
1 : 1.212 : 0.372
Unit cell volume
1187 ų
Z
4
Morphology

Elongated along [001] and the principal form observed is (100) with minor (010) and (001).

Twinning

none observed

Type-locality form

Acicular and bladed crystals up to 0.5 mm long and as hemispherical aggregates of radiating acicular crystals up to 3 mm.

Comment

SG Bbmm (non-standard setting of Cmcm)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1715.999271.983
40.64%
26FeIronIron355.845167.535
25.03%
30ZnZincZinc265.380130.760
19.54%
15PPhosphorusPhosphorus330.97492.922
13.89%
1HHydrogenHydrogen61.0086.048
0.90%
Total669.248100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2008-013
  • Plimeriet
  • Zink-Rockbridgeit

In other languages

German
IMA 2008-013 · Plimerit
Spanish
Plimerita
Italian
plimerite

Classification

Strunz
10th ed.

8.BC.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BCWith only medium-sized cations, (OH, etc.):RO4 > 1:1 and < 2:1Group
  • 8.BC.10PlimeriteSpecies
Dana
8th ed.

41.09.02.03

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.09(AB)5(XO4)3ZqType
  • 41.09.02Rockbridgeite GroupGroup
  • 41.09.02.03PlimeriteSpecies

Group, growth & confusion

Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1958Fisher, D. Jerome (1958) Pegmatite phosphates and their problems. American Mineralogist, 43 (3-4) 181-207
  2. 2009Elliott, P., Kolitsch, U., Giester, G., Libowitzky, E., McCammon, C., Pring, A., Birch, W. D., Brugger, J. (2009) Description and crystal structure of a new mineral – plimerite, ZnFe3+4(PO4)3(OH)5 – the Zn-analogue of rockbridgeite and frondelite, from Broken Hill, New South Wales, Australia. Mineralogical Magazine, 73 (1) 131-148 doi:10.1180/minmag.2009.073.1.131 DOI: 10.1180/minmag.2009.073.1.131
  3. 2010Piilonen, P. C., Poirier, G. (2010) New Mineral Names. American Mineralogist, 95 (1) 204-208 doi:10.2138/am.2010.553DOI: 10.2138/am.2010.553
  4. 2011Sejkora, J., Plášil, J., Filip, J. (2011) Plimerite from Krásno near Horní Slavkov ore district, Czech Republic. Journal of GEOsciences, 56 (2) 215-229
  5. 2011(2011) Plimerite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Plimerite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/plimerite-36041},
  note      = {Accessed 2026-05-11}
}