Rockbridgeite

(Fe2+0.5Fe3+0.5)2Fe3+3(PO4)3(OH)5
IMA status
  • Approved
  • Grandfathered
IMA symbol
Rkb
Discovered
1949
Also known as
  • Kobokobite
  • Rockbridgeiet

Where it forms, where it's found

Geological setting

granite pegmatite

Also rarely found in limonite iron ore deposits.

Type locality
Midvale Mine
  1. South Mountain
  2. Midvale
  3. Rockbridge County
  4. Virginia
  5. USA

37.8333°, -79.2833°

189recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5 – 4.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent · Opaque
Colour
Dark green · olive-green · brown · yellow-brown · greenish black · black

Commonly exhibits colour banding. May be bronze-brown or reddish brown when oxidized.

Streak
Gray green, pale brown
Tenacity
brittle
Cleavage
Very Good

On (100), excellent; on (010), good; on (001), fair.

Fracture
Irregular/Uneven
Density
3.45 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 45°
Refractive index
1.873 – 1.897
Surface relief
Very high
Principal indices
nα 1.873 – 1.875 · nβ 1.880 · nγ 1.895 – 1.897
Birefringence
0.022
Pleochroism
Visible

X = Light brown to light yellow-brown Y = Bluish green Z = Dark bluish green

Dispersion
r < v, or r>v very strong
UV response
Not fluorescent in UV
Michel-Lévy diagramhighlighted lineδ = 0.0220
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]220 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation220 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 13.783 Å · b = 16.805 Å · c = 5.172 Å
Ratio a:b:c
1 : 1.219 : 0.375
Z
4
Morphology

Euhedral crystals rare. Typically fibrous, elongated along [001]; compact radiating in crusts, botryoidal and drusy masses.

Comment

Bbmm

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
26FeIronIron555.845279.225
43.01%
8OOxygenOxygen1715.999271.983
41.90%
15PPhosphorusPhosphorus330.97492.922
14.31%
1HHydrogenHydrogen51.0085.040
0.78%
Total649.170100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Kobokobite
  • Rockbridgeiet

In other languages

German
Kobokobit · Rockbridgeit
Spanish
Rockbridgeita
Italian
Rockbridgeite

Classification

Strunz
10th ed.

8.BC.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BCWith only medium-sized cations, (OH, etc.):RO4 > 1:1 and < 2:1Group
  • 8.BC.10RockbridgeiteSpecies
Dana
8th ed.

41.09.02.01

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.09(AB)5(XO4)3ZqType
  • 41.09.02Rockbridgeite GroupGroup
  • 41.09.02.01RockbridgeiteSpecies
CIM

19.12.16

  • 19PhosphatesClass
  • 19.12Phosphates of MnGroup
  • 19.12.16RockbridgeiteSpecies

Group, growth & confusion

Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1880Massie (1880) Chemical News and Journal of Industrial Science, London: 42: 181.
  2. 1880Massie, F.A. (1880) On the composition of dufrenite from Rockbridgeite Co., Va. Chemical News and Journal of Industrial Science, London: 42: 181.
  3. 1881Campbell, J.L. (1881) On dufrenite from Rockbridgeite Co., Va. American Journal of Science: 22: 65–67.
  4. 1949Frondel, Clifford (1949) The dufrenite problem. American Mineralogist, 34 (7-8) 513-540
  5. 1949Lindberg, Marie Louise (1949) Frondelite and the frondelite-rockbridgeite series. American Mineralogist, 34 (7-8) 541-549
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Rockbridgeite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/rockbridgeite-3433},
  note      = {Accessed 2026-05-11}
}