Frondelite

(Mn2+0.5Fe3+0.5)2Fe3+3(PO4)3(OH)5
IMA status
  • Approved
  • Grandfathered
IMA symbol
Fnd
Discovered
1949
Also known as
  • Frondeliet

Where it forms, where it's found

Geological setting

Granitic pegmatite.

Granitic pegmatites.

Type locality
Sapucaia mine
  1. Sapucaia do Norte
  2. Galiléia
  3. Minas Gerais
  4. Brazil

-18.9008°, -41.4844°

56recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Dark brown · ocher-yellow · red-brown · greenish black · greenish brown · black · rarely orange

Colour zoning lengthwise common, manifests as concentric banding in radial aggregates.

Streak
Green (unoxidized), brown (oxidized)
Tenacity
brittle
Cleavage
Very Good

On (100), excellent; on (010), good; on (001), fair.

Fracture
Irregular/Uneven · Splintery · Fibrous
Density
3.453 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 45°
Refractive index
1.86 – 1.893
Surface relief
Very high
Principal indices
nα 1.860 · nβ 1.880 · nγ 1.893
Birefringence
0.033
Pleochroism
Visible

X = Light yellow-brown Y = Orange-brown Z = Orange-brown

Dispersion
r > v strong
Extinction
Parallel
UV response
Not Fluorescent in UV
Notes

Much so-called frondelite is Fe2+>Mn2+ and therefore is rockbridgeite.

Michel-Lévy diagramhighlighted lineδ = 0.0330
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]330 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation330 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#39
Cell parameters
a = 13.810 Å · b = 16.968 Å · c = 5.182 Å
Ratio a:b:c
1 : 1.229 : 0.375
Z
4
Morphology

Euhedral crystals rare. Crystals exhibit (100), (010), (110), and (101). Typically fibrous, elongated along [001]; radiating, in crusts, botyroidal and drusy masses.

Type-locality form

Crusts and as botryoidal and drusy masses, showing in cross section a radiating fibrous structure.

Comment

B22<f>1</f>2

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1715.999271.983
41.96%
26FeIronIron455.845223.380
34.46%
15PPhosphorusPhosphorus330.97492.922
14.33%
25MnManganeseManganese154.93854.938
8.47%
1HHydrogenHydrogen51.0085.040
0.78%
Total648.263100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Frondeliet

In other languages

French
frondélite
German
Frondelit
Italian
Frondelite

Classification

Strunz
10th ed.

8.BC.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BCWith only medium-sized cations, (OH, etc.):RO4 > 1:1 and < 2:1Group
  • 8.BC.10FrondeliteSpecies
Dana
8th ed.

41.09.02.02

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.09(AB)5(XO4)3ZqType
  • 41.09.02Rockbridgeite GroupGroup
  • 41.09.02.02FrondeliteSpecies
CIM

19.12.15

  • 19PhosphatesClass
  • 19.12Phosphates of MnGroup
  • 19.12.15FrondeliteSpecies

Group, growth & confusion

Often grow together
2 minerals
Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1949Lindberg, Marie Louise (1949) Frondelite and the frondelite-rockbridgeite series. American Mineralogist, 34 (7-8) 541-549
  2. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  3. 1960Lindberg, M.L. (1960) Crystal habit of frondelite, Sapucaia pegmatite mine, Minas Gerais, Brazil. U.S.G.S. Professional Paper 400B: 429–430.
  4. 2005(2005) Frondelite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2013Frost, Ray L., Xi, Yunfei, Scholz, Ricardo, Belotti, Fernanda M., Beganovic, Martina (2013) SEM–EDX, Raman and infrared spectroscopic characterization of the phosphate mineral frondelite (Mn2+)(Fe3+)4(PO4)3(OH)5. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 110. 7-13 doi:10.1016/j.saa.2013.02.008DOI: 10.1016/j.saa.2013.02.008
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Frondelite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/frondelite-1614},
  note      = {Accessed 2026-05-11}
}