Polyhalite

K2Ca2Mg(SO4)4 · 2H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Plhl
Discovered
1818
Also known as
  • Ischelit
  • Ischelite
  • Mamanit
  • +9 more

Where it forms, where it's found

Geological setting

Evaporite deposit.

Oceanic salt deposits; rarely as a volcanic product.

Type locality
Bad Ischler Salzberg
  1. Perneck
  2. Bad Ischl
  3. Gmunden District
  4. Upper Austria
  5. Austria

47.6667°, 13.6333°

92recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5 – 3.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colourless · white · pink · red · grey · colourless in transmitted light.

Salmon-pink to brick-red due to iron oxide inclusions.

Streak
White
Cleavage
Perfect

(101), perfect

Density
2.78 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 60 – 62° · 2V calc = 60 – 80°
Refractive index
1.546 – 1.567
Surface relief
Moderate
Principal indices
nα 1.546 – 1.548 · nβ 1.558 – 1.562 · nγ 1.567
Dispersion
none
Michel-Lévy diagramhighlighted lineδ = 0.0200
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]200 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation200 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Cell parameters
a = 6.975(3) Å · b = 6.984(3) Å · c = 8.899(3) Å
Cell angles
α = 104.01(3) ° · β = 101.19(3) ° · γ = 114.10(6) °
Ratio a:b:c
1 : 1.001 : 1.276
Unit cell volume
362.3 ų
Z
1
Morphology

Crystals small and rare; tabular (010) or elongated [001] and exhibiting numerous forms. Commonly massive, fibrous to foliated.

Twinning

On (010) and (100), very common and often polysynthetic.

Parting
On (010) (foliated varities).
Type-locality form

Compact fibrous.

Comment

Cell parameters from Bindi (2005).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1815.999287.982
47.77%
16SSulfurSulfur432.060128.240
21.27%
20CaCalciumCalcium240.07880.156
13.29%
19KPotassiumPotassium239.09878.196
12.97%
12MgMagnesiumMagnesium124.30524.305
4.03%
1HHydrogenHydrogen41.0084.032
0.67%
Total602.911100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Ischelit
  • Ischelite
  • Mamanit
  • Mamanita
  • Mamanite
  • Polygalit
  • Polygalite
  • Polyhaliet
  • Polyhalita
  • Polyhallit
  • Polyhallita
  • Polyhallite

In other languages

French
Polyhalite
German
Polyhalit
Spanish
Polihalita
Italian
Polialite · Polihalite · Polyhalite
Japanese
ポリハライト · 雑鹵石
Chinese
杂卤石
Simplified Chinese
杂卤石
Traditional Chinese
雜滷石
Russian
Полигалит
Arabic
بوليهاليت

Classification

Strunz
10th ed.

7.CC.65

  • 7SulfatesClass
  • 7.CSulfates (selenates, etc.) without additional anions, with H2ODivision
  • 7.CCWith medium-sized and large cationsGroup
  • 7.CC.65PolyhaliteSpecies
Dana
8th ed.

29.04.05.01

  • 29Hydrated Acid and Normal SulfatesClass
  • 29.04AmBn(XO4)p·xH2O, with (m+n):p < 3:2 and > 1:1Type
  • 29.04.05— unnamed intermediate level —Group
  • 29.04.05.01PolyhaliteSpecies
CIM

25.4.10

  • 25SulphatesClass
  • 25.4Sulphates of Ca, Sr and BaGroup
  • 25.4.10PolyhaliteSpecies

Group, growth & confusion

Often grow together
4 minerals

Literature, links & citation

Citations
  1. Tschermaks Mineralogische und Petrographische Mitteilungen: 14: 75-86.
  2. 1817Stromeyer, F. (1817) Ein neu entdecktes Metall und Analyse eines neuen Minerals. Journal für Chemie und Physik: 21: 297-306.
  3. 1817Sowerby, James (1817) TAB. CXLVII CALX Polyhalites. Polyhalite. In Exotic Mineralogy: or, coloured figures of foreign minerals: as a supplement to British Mineralogy. Vol. 2. Benjamin Meredith. p.101-102.
  4. 1818Stromeyer, F. (1818) Kön. Ges. Wiss. Göttingen, Gel. Anz., Teil 3, 2081.
  5. 1819Stromeyer, F. (1819) Chemische Untersuchung der natürlichen Boraxsäure, des Eisenpecherzes, des Picro-Pharmacoliths und des Polyhalits, eines neuen fossilen-Salzes. Annalen der Physik: 61: 177-189.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Polyhalite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/polyhalite-3259},
  note      = {Accessed 2026-05-11}
}