Anhydrite

Ca(SO4)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Anh
Discovered
1804
Also known as
  • Anchydrit
  • Anhydrita
  • Anhydrous Gypsum
  • +22 more

History

The name tells you what is missing. Anhydrite comes from the Greek anhydros — without water — and that absence is the whole point. It is calcium sulfate with no water built into its crystals, the dry counterpart of gypsum, which carries water in its structure.

A first specimen turned up in 1794, in a salt mine near Hall in Tirol, in the Austrian Alps. The mineral was not named, though, until 1804. In that year the German geologist Abraham Gottlob Werner gave it the name anhydrite, chosen precisely to set it apart from gypsum. Werner saw that the two minerals were close cousins — both calcium sulfate — but that one had taken on water and one had not.

That difference is not just a label. Left in contact with water, anhydrite slowly absorbs it and turns into gypsum, swelling as it does so. The change can be undone by heat, driving the water back off above about 200 °C. The mineral was even made artificially this way, crystallised from salty solutions kept warm.

Anhydrite also lent its name to an industrial recipe. Between 1930 and 1976, three plants in Britain — and others in Germany, France, Austria, and Poland — ran the so-called anhydrite process, baking the mineral in a kiln to make sulfuric acid and cement at the same time. One relic survives as a carved relief of an anhydrite kiln, cut from a block of the mineral itself for a sulphuric acid company.

The water-swapping habit took a destructive turn later. In the German town of Staufen im Breisgau, a 2007 geothermal drilling project let underground water reach a buried layer of anhydrite. As pockets of it converted to gypsum and expanded, the ground heaved unevenly and cracked buildings across the old town.

Industrial & practical applications

Pour a level floor and you may be standing on anhydrite. Ground to a powder and mixed with water, it sets back into a hard mass — the reverse of the slow weathering it undergoes in the ground. That single trick makes it a useful building material rather than a museum curiosity.

The largest use today is in flooring. Anhydrite is the binder in self-levelling floor screeds — the liquid layer poured over a sub-floor to smooth and flatten it before tiles or boards go down. Builders favour it for its better fluidity for self-levelling, its dimensional stability, and a high mechanical strength once cured. It also conducts heat well, which suits it to floors with heating pipes buried inside.

It plays a quieter part in cement. Added to the mix, anhydrite acts as a set time controller — slowing or tuning how fast the cement hardens — while also raising mechanical strength and curbing shrinkage as the concrete dries. It is also added to plasters and cement as a drying agent, drawing in stray moisture.

Anhydrite is calcium sulfate, so it carries two things plants want: calcium and sulfur. Crushed and spread on fields, it feeds both as fertilising elements, and it can double as a cheap mineral filler in fertiliser blends.

Two further uses turn on its chemistry. It is mixed into aerated building blocks, where it reacts with aluminium powder to release the gas that froths the block full of bubbles. And it is used to neutralise polluted soil, locking up contaminants so they spread no further.

Where it forms, where it's found

Geological setting

Sedimentary evaporite deposits, cap rock of salt domes.

Type locality
Salt mine
  1. Hall valley
  2. Absam
  3. Innsbruck-Land District
  4. Tyrol
  5. Austria

47.3252°, 11.4764°

1,735recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789103 – 3.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous · greasy
Transparency
Transparent · Translucent
Colour
Colourless · bluish · blue-grey · violet · burgundy-red · white · rose-pink · brownish · reddish · grey · dark grey · colourless in transmitted light
Streak
White, off-white, greyish
Tenacity
brittle
Cleavage
Perfect

On (010) perfect; on (100) nearly perfect; on (001) good to imperfect.

Fracture
Irregular/Uneven · Splintery
Density
2.98 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 36 – 45° · 2V calc = 44°
Refractive index
1.567 – 1.618
Surface relief
Moderate
Principal indices
nα 1.567 – 1.574 · nβ 1.574 – 1.579 · nγ 1.609 – 1.618
Pleochroism
Visible

Violet coloured material: X = colourless to very light yellow or rose; Y = light violet or rose; Z = violet.

Dispersion
Strong, r < v.
Extinction
X = b; Y = a; Z = c.
UV response
Can show fluorescence under LW and/or SW. For example: bluish white response to SW: https://www.mindat.org/photo-1254482.html
Notes

Absorption: Z > Y > X.

Michel-Lévy diagramhighlighted lineδ = 0.0430
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]430 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation430 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 6.245(1) Å · b = 6.995(2) Å · c = 6.993(2) Å
Ratio a:b:c
1 : 1.120 : 1.120
Z
4
Morphology

Crystals equant, or nearly so, with large pinacoidal faces. Also thick tabular on (010), (100), or (001); commonly elongated on [100], [010] or [001]. Massive. Fine granular to scaly; fibrous (either parallel, radiated or plumose) and frequently curved. Contorted concretionary forms (bowel stone).

Twinning

1.) On (011) as contact twins and polysynthetic lamellae (may be produced by heating or pressure); 2.) On (120) as contact twins, rare.

Comment

Space Group: Amma

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen415.99963.996
47.01%
20CaCalciumCalcium140.07840.078
29.44%
16SSulfurSulfur132.06032.060
23.55%
Total136.134100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Sr
  • Ba
  • H2O

Synonyms

  • Anchydrit
  • Anhydrita
  • Anhydrous Gypsum
  • Anhydrous Sulfate of Lime
  • Anidrit
  • Bardiglione
  • Chaux sulfatée anhydre
  • Chaux sulfatée quartzifère
  • Cube Spar
  • Gekrösstein
  • Karstenit
  • Karstenite
  • Leuchtstein
  • Marmor Bardiglio di Bergamo
  • Metanhydrit
  • Muriacit
  • Muriacita
  • Muriacite
  • Muriazit
  • Salzsaurer Kalk
  • Siliceous Anhydrous Gypsum
  • Soude muriatée gypsifère
  • Würfelgips
  • Würfelgyps
  • Würfelspat

In other languages

French
7778-18-9 · Anhydrite · Chaux sulfatée anhydre · Chaux sulfatée quartzifère · Karsténite · Muriacite · Pierre de tripes · Soude muriatée gypsifère · Vulpinite
German
Anhydrit · Anhydritbinder · Anhydritspat · Anhydritstein · Gekrösstein · Karstenit
Spanish
anhidrita
Italian
anhydrite · anidrite
Portuguese
anidrita · Anidrite
Japanese
無水石膏 · 硬石膏
Chinese
硬石膏
Simplified Chinese
硬石膏
Traditional Chinese
硬石膏
Russian
ангидрит
Arabic
أنهيدريت

Classification

Strunz
10th ed.

7.AD.30

  • 7SulfatesClass
  • 7.ASulfates (selenates, etc.) without additional anions, without H2ODivision
  • 7.ADWith only large cationsGroup
  • 7.AD.30AnhydriteSpecies
Dana
8th ed.

28.03.02.01

  • 28Anhydrous Acid and Normal SulfatesClass
  • 28.03AXO4Type
  • 28.03.02— unnamed intermediate level —Group
  • 28.03.02.01AnhydriteSpecies
CIM

25.4.1

  • 25SulphatesClass
  • 25.4Sulphates of Ca, Sr and BaGroup
  • 25.4.1AnhydriteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. Newman, E.S. (1941): BEHAVIOR OF CALCIUM SULFATE AT HIGH TEMPERATURES. Journal of Research of the National Bureau of Standards, 27, 191-196. https://nvlpubs.nist.gov/nistpubs/jres/27/jresv27n2p191_A1b.pdf
  2. Langbein, R. (1979): Petrologische Aspekte der Anhydritbildung. Zeitschrift für geologische Wissenschaften, 7 (7), 913-926.
  3. 1794von Fichtel, J.E. (1794) Vom Lilalith. Mineralogische Aufsätze, Wien: 226-236. [as salzsaurer Kalk, Muriazit, schuppiger Gypsstein, footnote on p. 228 refering to Abbé Nicolaus Poda von Neuhaus].
  4. 1794Poda, A.N. (1794) Vom Lilalith. in: Mineralogische Aufsätze, Mathias Andreas Schmidt (Wein) 226-236.
  5. 1800Werner (1800). [as Würfelspath].
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Anhydrite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/anhydrite-234},
  note      = {Accessed 2026-05-11}
}