Quadruphite

Na6Na2(CaNa)2Na2Ti2Na2Ti2(Si2O7)2(PO4)4O4F2
IMA status
  • Approved
IMA symbol
Qua
Discovered
1992
Also known as
  • Quadruphiet
  • Quadruphita

Where it forms, where it's found

Geological setting

Alkalic pegmatite.

Type locality
Alluaiv Mountain
  1. Lovozersky District
  2. Murmansk Oblast
  3. Russia

67.8645°, 34.5124°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Light brown
Streak
white
Tenacity
brittle
Cleavage
Perfect

Perfect (001) and less perfect (110) and (100).

Fracture
Step-Like
Density
3.12 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 62°
Refractive index
1.63 – 1.697
Surface relief
High
Principal indices
nα 1.630 · nβ 1.678 · nγ 1.697
Pleochroism
Visible

Colorless (X) to yellowish (Y, Z) with X < Y ~ Z.

Dispersion
r < v, strong
UV response
Not fluorescent
Michel-Lévy diagramhighlighted lineδ = 0.0670
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]670 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation670 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#1
Cell parameters
a = 5.415(2) Å · b = 7.081(3) Å · c = 20.34(1) Å
Cell angles
α = 86.85(4) ° · β = 94.40(4) ° · γ = 89.94(3) °
Ratio a:b:c
1 : 1.308 : 3.756
Z
1
Morphology

Flakes on (001).

Type-locality form

Flakes on (001), 1-2 mm thick and 3 mm across, grown epitaxially on lomonosovite and soboloveite.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3415.999543.966
38.53%
11NaSodiumSodium1422.990321.860
22.80%
22TiTitaniumTitanium447.867191.468
13.56%
15PPhosphorusPhosphorus430.974123.896
8.78%
14SiSiliconSilicon428.085112.340
7.96%
20CaCalciumCalcium240.07880.156
5.68%
9FFluorineFluorine218.99837.996
2.69%
Total1411.682100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Sr
  • Ba
  • Mn
  • Fe
  • Zr
  • Nb

Synonyms

  • Quadruphiet
  • Quadruphita

In other languages

German
IMA 1990-026 · Quadruphit
Italian
Quadrufite · Quadruphite · Quadruphite-VII · Quadruphite-VIII

Classification

Strunz
10th ed.

9.BE.45

  • 9SilicatesClass
  • 9.BSorosilicatesDivision
  • 9.BESi2O7 groups, with additional anions; cations in octahedral [6] and greater coordinationGroup
  • 9.BE.45QuadruphiteSpecies
Dana
8th ed.

56.04.01.03

  • 56Sorosilicates Si2o7 Groups, with Additional O, Oh, F and H2oClass
  • 56.04Si2O7 Groups and O, OH, F, and H2O with [Si2O7] with other cation groupsType
  • 56.04.01Lomonosovite groupGroup
  • 56.04.01.03QuadruphiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1987Sokolova, E.V., Egorov-Tismenko, Y.K., Khomyakov, A.P. (1987) Special features of the crystal structure of Na14CaMgTi4[Si2O7]2[PO4]O4F2 homologue of sulphohalite and lomonosovite structure types. Mineralogiceskij Zhurnal: 9: 28-35.
  2. 1992Khomyakov, A.P., Nechelyustov, G.N., Sokolova, E.A., Dorokhova, G.I. (1992) Quadruphite Na14CaMgTi4-[Si207]2[P04]404F2 and polyphite Na17Ca3Mg(Ti,Mn)4-[Si207]2[P04]602F6: New minerals of the lomonosovite group. Zapiski Vserossiskogo Mineralogicheskogo Obshchetstva, 121(1), 105-112 (in Russian).
  3. 1993Jambor, John L., Vanko, David A. (1993) New Mineral Names. American Mineralogist, 78 (11-12) 1314-1319
  4. 1997Mandarino, Joseph A. (1997) New Minerals 1990-1994. The Mineralogical Record Inc., Tuscon, Arizona. 220pp.
  5. 2001(2001) Quadruphite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Quadruphite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/quadruphite-3336},
  note      = {Accessed 2026-05-11}
}