Schüllerite

Ba2Ti2Na2Mg2(Si2O7)2O2F2
IMA status
  • Approved
IMA symbol
Shü
IMA approved
2010
Also known as
  • IMA2010-035
  • Schülleriet

Where it forms, where it's found

Geological setting

In miarolitic cavities of alkaline basalt.

Type locality
Löhley
  1. Üdersdorf
  2. Daun
  3. Vulkaneifel
  4. Rhineland-Palatinate
  5. Germany

50.1592°, 6.8114°

7recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
Brown
Streak
White
Tenacity
brittle
Cleavage
Perfect

on (001)

Density
3.974 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 40°
Refractive index
1.756 – 1.78
Surface relief
High
Principal indices
nα 1.756 · nβ 1.773 · nγ 1.780
Pleochroism
Visible

Brown to dark brown.

Dispersion
r < v, weak
Extinction
Z ∧ c = 20°; the angle between Y and the elongation direction of crystals is 38°.
Notes

Absorption: X > Y > Z.

Michel-Lévy diagramhighlighted lineδ = 0.0240
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]240 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation240 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 5.396(1) Å · b = 7.071(1) Å · c = 10.226(2) Å
Cell angles
α = 99.73(3) ° · β = 99.55(3) ° · γ = 90.09(3) °
Ratio a:b:c
1 : 1.310 : 1.895
Unit cell volume
379.1 ų
Z
1
Morphology

Flattened, fine lamellar to tabular crystals.

Type-locality form

Fine-lamellar to tabular crystals up to 0.5 x 1 x 2 mm in size and their clusters up to 2 mm across.

Comment

Originally reported in space group P1 (Rastsvetaeva et al., 2011).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
56BaBariumBarium2137.327274.654
31.52%
8OOxygenOxygen1615.999255.984
29.38%
14SiSiliconSilicon428.085112.340
12.89%
22TiTitaniumTitanium247.86795.734
10.99%
12MgMagnesiumMagnesium224.30548.610
5.58%
11NaSodiumSodium222.99045.980
5.28%
9FFluorineFluorine218.99837.996
4.36%
Total871.298100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • K
  • Sr
  • Al
  • Nb

Synonyms

  • IMA2010-035
  • Schülleriet

In other languages

German
IMA 2010-035 · Schüllerit
Italian
schüllerite

Classification

Strunz
10th ed.

9.BE.25

  • 9SilicatesClass
  • 9.BSorosilicatesDivision
  • 9.BESi2O7 groups, with additional anions; cations in octahedral [6] and greater coordinationGroup
  • 9.BE.25SchülleriteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 2010Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2010) New minerals and nomenclature modifications approved in 2010, CNMNC Newsletter No 5. Mineralogical Magazine, 74 (5) 859-862 doi:10.1180/s0026461x00056887 DOI: 10.1180/s0026461x00056887
  2. 2011Rastsvetaeva, R. K., Aksenov, S. M., Chukanov, N. V. (2011) Crystal structure of Schüllerite, a new mineral of the heterophyllosilicate family. Doklady Chemistry, 437 (2) 90-94 doi:10.1134/s0012500811040045DOI: 10.1134/s0012500811040045
  3. 2011Chukanov, N. V., Rastsvetaeva, R. K., Britvin, S. N., Virus, A. A., Belakovskiy, D. I., Pekov, I. V., Aksenov, S. M., Ternes, B. (2011) Schüllerite, Ba2Na(Mn,Ca)(Fe3+,Mg,Fe2+)2Ti2(Si2O7)2(O,F)4, a new mineral species from the Eifel volcanic district, Germany. Geology of Ore Deposits, 53 (8) 767-774 doi:10.1134/s1075701511080046DOI: 10.1134/s1075701511080046
  4. 2013Sokolova, Elena, Hawthorne, Frank C., Abdu, Yassir A. (2013) From structure topology to chemical composition. XV. Titanium silicates: revision of the crystal structure and chemical formula of schüllerite, Na2Ba2Mg2Ti2(Si2O7)2O2F2, from the Eifel volcanic region, Germany. The Canadian Mineralogist, 51 (5) 715-725 doi:10.3749/canmin.51.5.715 DOI: 10.3749/canmin.51.5.715
  5. 2014Rastsvetaeva, R. K., Aksenov, S. M., Chukanov, N. V., Lykova, I. S., Verin, I. A. (2014) Iron-rich schüllerite from Kahlenberg (Eifel, Germany): Crystal structure and relation to lamprophyllite-group minerals. Crystallography Reports, 59 (6) 867-873 doi:10.1134/s1063774514060248DOI: 10.1134/s1063774514060248
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Schüllerite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/schullerite-40293},
  note      = {Accessed 2026-05-11}
}