Rhabdophane-(Ce)

Ce(PO4) · H2O
IMA status
  • Approved
IMA symbol
Rha-Ce
Discovered
1878
Also known as
  • Llallagualita
  • Llallayualit
  • Llallayualita
  • +2 more

Where it forms, where it's found

Geological setting

Vein copper ore deposit.

An uncommon late-stage mineral in almost all of its occurrences: nepheline syenite pegmatites, polymetallic veins, also rarely from granite pegmatites, has been found in limonite beds

Type locality
Fowey Consols (incl. Wheal Treasure
  1. Wheal Fortune
  2. Wheal Chance)
  3. Tywardreath and Par
  4. Cornwall
  5. England
  6. UK

50.3700°, -4.6958°

84recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Greasy
Transparency
Translucent
Colour
Brown · pale pink · yellowish-white · pale gray · fibers may be colourless in transmitted light.

May be stained by iron oxides

Streak
Colorless when pure
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven · Sub-Conchoidal
Density
3.77 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.654 – 1.744
Surface relief
High
Principal indices
nω 1.654 – 1.700 · nε 1.703 – 1.744
Birefringence
0.050
Pleochroism
Visible

Colorless, E tan to light brown

Extinction
Parallel
Michel-Lévy diagramhighlighted lineδ = 0.0500
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]500 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation500 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#89
Cell parameters
a = 7.037(1) Å · c = 6.429(1) Å
Morphology

Occurs as incrustations, botryoidal, globular, or stalactitic forms with radial-fibrous structure. Short rod-like simple hexagonal crystals.

Comment

Space group and cell from Kolitsch (2021). Originally assumed to have space group P6222, with a = 7.07(2) and c = 19.06(5) Å.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
58CeCeriumCerium1140.116140.116
55.36%
8OOxygenOxygen515.99979.995
31.60%
15PPhosphorusPhosphorus130.97430.974
12.24%
1HHydrogenHydrogen21.0082.016
0.80%
Total253.101100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Llallagualita
  • Llallayualit
  • Llallayualita
  • Llallayualite
  • Rhabdophaan-(Ce)

In other languages

German
Rhabdophan-(Ce)
Italian
Rabdofane- · Rhabdophane-(Ce)

Classification

Strunz
10th ed.

8.CJ.45

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CJWith only large cationsGroup
  • 8.CJ.45Rhabdophane-(Ce)Species
Dana
8th ed.

40.04.07.01

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.04(AB)5(XO4)2·xH2OType
  • 40.04.07Rhabdophane GroupGroup
  • 40.04.07.01Rhabdophane-(Ce)Species
CIM

19.9.6

  • 19PhosphatesClass
  • 19.9Phosphates of rare earths and ScGroup
  • 19.9.6Rhabdophane-(Ce)Species

Group, growth & confusion

In the same group
6 members

Literature, links & citation

Citations
  1. 1878Lettsom, W.G. (1878) Rabdophan. Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 3: 191-191 (as Rhabdophane).
  2. 1878Lecoq d Boisbaudran (1878) Comptes rendu de l’Académie des sciences de Paris: 86: 1028 (as Rhabdophane).
  3. 1880Bertrand, E. (1880) Du type cristallin auquel on doit rapporter le Rhabdophane, d'après les propriétés optiques que présentent les corps cristallisés affectant la forme sphérolitique. Bulletin de la Société française de Minéralogie: 3: 58-62.
  4. 1882Hartley, W.N. (1882) The analysis of rhabdophane, a new British mineral. Journal of the Chemical Society, 41, 210-220.
  5. 1882Lettsom, W.G. (1882) Proceedings of the Crystallological Society, London: 105 (as Rhabdophane).
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Rhabdophane-(Ce) — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/rhabdophane-ce-3397},
  note      = {Accessed 2026-05-11}
}