Grayite

(Th,Pb,Ca)(PO4) · H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Gry
Discovered
1957
Also known as
  • Grayiet

Where it forms, where it's found

Geological setting

Originally in a lithia-rich granite pegmatite.

Has been found in granite pegmatite (Maine).

Type locality
Gooddays Mine (Good Days Mine)
  1. Mutoko parish (Mtoko)
  2. Mutoko District (Mtoko District)
  3. Mashonaland East
  4. Zimbabwe

-17.4000°, 32.5000°

18recorded occurrences
Source · OpenStreetMap

Radioactivity

Physical

Transparency
Translucent
Colour
Dark reddish brown · rarely tannish yellow
Fracture
Conchoidal
Density
6.41 g/cm³

Optical

Optical type
Uniaxial
Refractive index
1.66 – 1.69
Surface relief
High
Principal indices
nω 1.66 · nε 1.69
Birefringence
moderate (~0.03)
UV response
Specimens from Havey #2 Quarry, Topsham, Maine fluoresce yellow in SW UV.
Michel-Lévy diagramhighlighted lineδ = 0.0300
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]300 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation300 nm
Order1st order
XPL colour

Crystallography

Crystal system
Hexagonal
Space group
#119
Cell parameters
a = 6.957 Å · c = 6.396 Å
Z
3

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
90ThThoriumThorium1232.038232.038
39.17%
82PbLeadLead1207.200207.200
34.98%
8OOxygenOxygen515.99979.995
13.51%
20CaCalciumCalcium140.07840.078
6.77%
15PPhosphorusPhosphorus130.97430.974
5.23%
1HHydrogenHydrogen21.0082.016
0.34%
Total592.301100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Grayiet

In other languages

French
Grayite
German
Grayit
Italian
Grayite

Classification

Strunz
10th ed.

8.CJ.45

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CJWith only large cationsGroup
  • 8.CJ.45GrayiteSpecies
Dana
8th ed.

40.04.07.04

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.04(AB)5(XO4)2·xH2OType
  • 40.04.07Rhabdophane GroupGroup
  • 40.04.07.04GrayiteSpecies
CIM

19.10.8

  • 19PhosphatesClass
  • 19.10Phosphates of Pb, Th, V and BiGroup
  • 19.10.8GrayiteSpecies

Group, growth & confusion

Often grow together
2 minerals

Literature, links & citation

Citations
  1. Kol'skii Filial, Materialy Mineral. Kol'skii Poluostrova: l: 91-101. (in Russian)
  2. 1957Bowie, S.H.U. (1957) Summary of progress of the Geological Survey of Great Britian and the Museum of Practical Geology for the year 1956. Atomic Energy Division. Geological Survey of Great Britain 1957: 66-67.
  3. 1959Chronique mines outre-mer et recherche minere: 279 (1959).
  4. 1959Semenov, E.I. (1959) Minerals of the rhabdophane group in alkalic massives. Akad. Nauk SSR,
  5. 1961Dooley and Hathaway (1961) United States Geological Survey Professional Paper 424-C.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Grayite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/grayite-1743},
  note      = {Accessed 2026-05-11}
}