Rhodesite

KHCa2Si8O19 · 5H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Rod
Discovered
1957
Also known as
  • Rhodesiet

Where it forms, where it's found

Geological setting

kimberlite pipe

Kimberlite, altered silicic lavas

Type locality
Bultfontein Mine
  1. KEM JV Mine (Kimberley Ekapa Mining Joint Venture mine
  2. Kimberley Underground mine)
  3. Kimberley
  4. Sol Plaatje Local Municipality
  5. Frances Baard District Municipality
  6. Northern Cape
  7. South Africa

-28.7682°, 24.7921°

12recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
White
Cleavage
Distinct/Good

Good on (100)

Density
2.27 g/cm³

Optical

Optical type
Biaxial (+) · 2V calc = 68.1°
Refractive index
1.501 – 1.518
Surface relief
Moderate
Principal indices
nα 1.501 – 1.504 · nβ 1.506 – 1.508 · nγ 1.513 – 1.518
Dispersion
relatively strong
Michel-Lévy diagramhighlighted lineδ = 0.0130
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]130 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation130 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 23.60(18) Å · b = 6.57(2) Å · c = 7.03(2) Å
Ratio a:b:c
1 : 0.278 : 0.298
Z
2
Morphology

Matted silky fibers, flattened rosettes, irregular segregations, crusts.

Comment

Space Group: Pmam:

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2415.999383.976
51.96%
14SiSiliconSilicon828.085224.680
30.40%
20CaCalciumCalcium240.07880.156
10.85%
19KPotassiumPotassium139.09839.098
5.29%
1HHydrogenHydrogen111.00811.088
1.50%
Total738.998100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Al
  • Fe
  • Mg
  • Na

Synonyms

  • Rhodesiet

In other languages

German
Rhodesit
Italian
rhodesite
Chinese
水矽鹼鈣石

Classification

Strunz
10th ed.

9.EB.05

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.EBDouble nets with 4- and 6-membered ringsGroup
  • 9.EB.05RhodesiteSpecies
Dana
8th ed.

72.05.01.01

  • 72Phyllosilicates Two-dimensional Infinite Sheets with Other Than Six-membered RingsClass
  • 72.05Two-Dimensional Infinite Sheets with Other Than Six-Membered Rings with corrugated and complex layersType
  • 72.05.01Rhodesite groupGroup
  • 72.05.01.01RhodesiteSpecies
CIM

14.6.7

  • 14Silicates not Containing AluminumClass
  • 14.6Silicates of Ca with alkali or Mg or bothGroup
  • 14.6.7RhodesiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1957Mountain, E. D. (1957) Rhodesite, a new mineral from the Bultfontein mine, Kimberley. Mineralogical Magazine and Journal of the Mineralogical Society, 31 (239). 607-610 doi:10.1180/minmag.1957.31.239.01DOI: 10.1180/minmag.1957.31.239.01
  2. 1957Gard, J. A., Taylor, H. F. W., Chalmers, R. A. (1957) An investigation of two new minerals: rhodesite and mountainite. Mineralogical Magazine and Journal of the Mineralogical Society, 31 (239). 611-623 doi:10.1180/minmag.1957.31.239.02DOI: 10.1180/minmag.1957.31.239.02
  3. 1969Sheppard, Richard A., Gude 3rd, Arthur J. (1969) Rhodesite from Trinity County, California. American Mineralogist, 54 (1-2). 251-255
  4. 1992Liebau, F., Hesse, K.-F. (1992) Crystal structure of rhodesite, HK1-xNax+2yCa2-y{lB,3,22∞}[Si8O19]·(6-z)H2O, from three localities and its relation to other silicates with dreier double layers. Zeitschrift für Kristallographie - Crystalline Materials, 199 (14) 25 doi:10.1524/zkri.1992.199.14.25 DOI: 10.1524/zkri.1992.199.14.25
  5. 2001(2001) Rhodesite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Rhodesite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/rhodesite-3403},
  note      = {Accessed 2026-05-11}
}