Chalcosiderite

CuFe3+6(PO4)4(OH)8 · 4H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Csd
Discovered
1814
Also known as
  • Chalcosideriet
  • Chalcosiderit
  • Chalcosiderita

Where it forms, where it's found

Geological setting

Oxidized zone of some hydrothermal deposits.

Type locality
Phoenix United Mine
  1. Minions
  2. Linkinhorne
  3. Cornwall
  4. England
  5. UK

50.5240°, -4.4504°

75recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent
Colour
Dark green to apple-green
Streak
pale green to greenish to white
Tenacity
brittle
Cleavage
Perfect

On (001), perfect, on (010), good.

Density
3.22 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 22° · 2V calc = 48°
Refractive index
1.775 – 1.844
Surface relief
Very high
Principal indices
nα 1.775 · nβ 1.840 · nγ 1.844
Birefringence
0.069
Pleochroism
Weak

X= Colourless Z= Pale green

Dispersion
relatively strong r > v
UV response
Not fluorescent
Michel-Lévy diagramhighlighted lineδ = 0.0690
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]690 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation690 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 7.653(4) Å · b = 7.873(4) Å · c = 10.19 Å
Cell angles
α = 67.57(2) ° · β = 69.17(2) ° · γ = 64.93(2) °
Ratio a:b:c
1 : 1.029 : 1.332
Z
1
Morphology

Crystals short prismatic [001], with large (001), (010), (110), and (111). Commonly in sheafs, crusts.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2815.999447.972
45.41%
26FeIronIron655.845335.070
33.96%
15PPhosphorusPhosphorus430.974123.896
12.56%
29CuCopperCopper163.54663.546
6.44%
1HHydrogenHydrogen161.00816.128
1.63%
Total986.612100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Al

Synonyms

  • Chalcosideriet
  • Chalcosiderit
  • Chalcosiderita

In other languages

German
Chalkosiderit
Spanish
Calcosiderita
Italian
Calcosiderite · Chalcosiderite

Classification

Strunz
10th ed.

8.DD.15

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DDWith only medium-sized cations, (OH, etc.):RO4= 2:1Group
  • 8.DD.15ChalcosideriteSpecies
Dana
8th ed.

42.09.03.04

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.09(AB)7(XO4)4Zq·xH2OType
  • 42.09.03Turquoise GroupGroup
  • 42.09.03.04ChalcosideriteSpecies
CIM

19.2.13

  • 19PhosphatesClass
  • 19.2Phosphates of CuGroup
  • 19.2.13ChalcosideriteSpecies

Group, growth & confusion

In the same group
4 members
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1814Ullmann, J., Ch. (1814) Systematisch-tabellarische Uebersicht der mineralogisch einfachen Fossilien, (Kapitel 95 – Chalkosiderit), Krieger´sche Buchhandlung Cassel und Marburg, 323-325.
  2. 1875Maskelyne, N.S. (1875) On andrewsite and chalkosiderite. Journal of the Chemical Society, London: 28: 586-591.
  3. 1912Schaller, W.T. (1912) Crystallized turquoise from Virginia. American Journal of Science, 33, 35-40.
  4. 1912Schaller (1912) Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig, 50, 120.
  5. 1921Larsen, E.S. (1921) The microscopic determination of the nonopaque minerals. U.S. Geological Survey Bulletin, 671, 5-294.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Chalcosiderite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/chalcosiderite-945},
  note      = {Accessed 2026-05-11}
}